(2,9-Dimethyl-1,10-phenanthroline)(4-hydroxypyridine-2,6-dicarboxylato)copper(II) trihydrate
In the title complex, [Cu(C7H3NO5)(C14H12N2)]·3H2O, there are two independent neutral molecules of the Cu complex along with six molecules of water of hydration in the asymmetric unit. The CuII atoms in each complex adopt a distorted square-pyramidal coordination geometry being pentacoo...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-07-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809021588 |
| _version_ | 1819280158879645696 |
|---|---|
| author | Janet Soleimannejad Hossein Aghabozorg Faranak Manteghi Shokoh Najafi |
| author_facet | Janet Soleimannejad Hossein Aghabozorg Faranak Manteghi Shokoh Najafi |
| author_sort | Janet Soleimannejad |
| collection | DOAJ |
| description | In the title complex, [Cu(C7H3NO5)(C14H12N2)]·3H2O, there are two independent neutral molecules of the Cu complex along with six molecules of water of hydration in the asymmetric unit. The CuII atoms in each complex adopt a distorted square-pyramidal coordination geometry being pentacoordinated by one N and two O atoms of 4-hydroxypyridine-2,6-dicarboxylate anions and two N atoms of 2,9-dimethyl-1,10-phenanthroline (dmp) molecules. In the crystal structure, there are O—H...O and C—H...O hydrogen bonds and five π–π stacking interactions with centroid–centroid distances in the range 3.620 (1)–3.712 (1) Å. In addition, a C—H...π interaction between a heterocyclic ring of dmp is observed to reinforce the crystal cohesion. |
| first_indexed | 2024-12-24T00:39:21Z |
| format | Article |
| id | doaj.art-5bd4ad17574d45838fe396aca369baee |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:39:21Z |
| publishDate | 2009-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-5bd4ad17574d45838fe396aca369baee2022-12-21T17:24:00ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-07-01657m761m76210.1107/S1600536809021588(2,9-Dimethyl-1,10-phenanthroline)(4-hydroxypyridine-2,6-dicarboxylato)copper(II) trihydrateJanet SoleimannejadHossein AghabozorgFaranak ManteghiShokoh NajafiIn the title complex, [Cu(C7H3NO5)(C14H12N2)]·3H2O, there are two independent neutral molecules of the Cu complex along with six molecules of water of hydration in the asymmetric unit. The CuII atoms in each complex adopt a distorted square-pyramidal coordination geometry being pentacoordinated by one N and two O atoms of 4-hydroxypyridine-2,6-dicarboxylate anions and two N atoms of 2,9-dimethyl-1,10-phenanthroline (dmp) molecules. In the crystal structure, there are O—H...O and C—H...O hydrogen bonds and five π–π stacking interactions with centroid–centroid distances in the range 3.620 (1)–3.712 (1) Å. In addition, a C—H...π interaction between a heterocyclic ring of dmp is observed to reinforce the crystal cohesion.http://scripts.iucr.org/cgi-bin/paper?S1600536809021588 |
| spellingShingle | Janet Soleimannejad Hossein Aghabozorg Faranak Manteghi Shokoh Najafi (2,9-Dimethyl-1,10-phenanthroline)(4-hydroxypyridine-2,6-dicarboxylato)copper(II) trihydrate Acta Crystallographica Section E |
| title | (2,9-Dimethyl-1,10-phenanthroline)(4-hydroxypyridine-2,6-dicarboxylato)copper(II) trihydrate |
| title_full | (2,9-Dimethyl-1,10-phenanthroline)(4-hydroxypyridine-2,6-dicarboxylato)copper(II) trihydrate |
| title_fullStr | (2,9-Dimethyl-1,10-phenanthroline)(4-hydroxypyridine-2,6-dicarboxylato)copper(II) trihydrate |
| title_full_unstemmed | (2,9-Dimethyl-1,10-phenanthroline)(4-hydroxypyridine-2,6-dicarboxylato)copper(II) trihydrate |
| title_short | (2,9-Dimethyl-1,10-phenanthroline)(4-hydroxypyridine-2,6-dicarboxylato)copper(II) trihydrate |
| title_sort | 2 9 dimethyl 1 10 phenanthroline 4 hydroxypyridine 2 6 dicarboxylato copper ii trihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809021588 |
| work_keys_str_mv | AT janetsoleimannejad 29dimethyl110phenanthroline4hydroxypyridine26dicarboxylatocopperiitrihydrate AT hosseinaghabozorg 29dimethyl110phenanthroline4hydroxypyridine26dicarboxylatocopperiitrihydrate AT faranakmanteghi 29dimethyl110phenanthroline4hydroxypyridine26dicarboxylatocopperiitrihydrate AT shokohnajafi 29dimethyl110phenanthroline4hydroxypyridine26dicarboxylatocopperiitrihydrate |