Effects of initial wettability and different surfactant-silica nanoparticles flooding scenarios on oil-recovery from carbonate rocks
Initial wettability of rock surfaces plays a crucial role in displacement efficiency during core flooding experiments. In this study, linear alkylbenzene sulfonic acid (LABSA) and silica nanoparticles (NPs) were utilized as enhanced oil recovery (EOR) agents to improve oil recovery from carbonate ro...
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| Format: | Article |
| Language: | English |
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KeAi Communications Co., Ltd.
2022-12-01
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| Series: | Petroleum |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2405656121000249 |
| _version_ | 1797960194818310144 |
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| author | Amin Rezaei Amin Khodabakhshi Amir Esmaeili Mehdi Razavifar |
| author_facet | Amin Rezaei Amin Khodabakhshi Amir Esmaeili Mehdi Razavifar |
| author_sort | Amin Rezaei |
| collection | DOAJ |
| description | Initial wettability of rock surfaces plays a crucial role in displacement efficiency during core flooding experiments. In this study, linear alkylbenzene sulfonic acid (LABSA) and silica nanoparticles (NPs) were utilized as enhanced oil recovery (EOR) agents to improve oil recovery from carbonate rock samples. Prior to the core flooding experiments, effects of the presence of LABSA and SiO2 NPs on oil-water interfacial tension (IFT), wettability alteration, and surfactant adsorption on the rock surfaces were evaluated. The results of IFT/contact angle measurements showed that by adding 0.03 wt% LABSA, the IFT, and contact angle reduced from the initial values of 36.9 mN/m and 115.6° ± 0.2° to 8.3 mN/m and 100.3° ± 0.4°, respectively. Furthermore, incorporating SiO2 NPs (0.1 wt%) into the system causes a further decrease in IFT value (dropped to 2.2 mN/m), along with a substantial reduction in contact angle (final contact angle after 6 h soaking into the solution was measured as 64.8° ± 0.3°). In addition, surfactant loss due to the adsorption on the rock surfaces decreased up to 35% in the presence of SiO2 NPs (0.1 wt%). Moreover, various core flooding scenarios in carbonate plugs with different initial wettability conditions were conducted, and the performance of the EOR agents in enhancing oil recovery from oil-wet and water-wet core samples in the secondary and tertiary mode of flooding was evaluated. The outcomes revealed that the injection of a combination of chemicals, containing LABSA (0.03 wt %) and SiO2 (0.1 wt%) in the secondary mode leads to the highest ultimate oil recovery from sister carbonate core samples. |
| first_indexed | 2024-04-11T00:42:29Z |
| format | Article |
| id | doaj.art-5bdd7e1f9f99443ab3abcde2724a8fc8 |
| institution | Directory Open Access Journal |
| issn | 2405-6561 |
| language | English |
| last_indexed | 2024-04-11T00:42:29Z |
| publishDate | 2022-12-01 |
| publisher | KeAi Communications Co., Ltd. |
| record_format | Article |
| series | Petroleum |
| spelling | doaj.art-5bdd7e1f9f99443ab3abcde2724a8fc82023-01-06T04:17:24ZengKeAi Communications Co., Ltd.Petroleum2405-65612022-12-0184499508Effects of initial wettability and different surfactant-silica nanoparticles flooding scenarios on oil-recovery from carbonate rocksAmin Rezaei0Amin Khodabakhshi1Amir Esmaeili2Mehdi Razavifar3Abdal Industrial Projects Management Company (MAPSA), Pardis Technology Park, Pardis, Tehran, Iran; Corresponding author.Department of Chemical Engineering, Faculty of Engineering, Mahshahr Branch, Islamic Azad University, Mahshar, IranDepartment of Petroleum Engineering, Amirkabir University of Technology (Tehran Polytechnic), Tehran, IranEnhanced Oil Recovery (EOR) Research Centre, IOR/EOR Research Institute, Shiraz University, Shiraz, IranInitial wettability of rock surfaces plays a crucial role in displacement efficiency during core flooding experiments. In this study, linear alkylbenzene sulfonic acid (LABSA) and silica nanoparticles (NPs) were utilized as enhanced oil recovery (EOR) agents to improve oil recovery from carbonate rock samples. Prior to the core flooding experiments, effects of the presence of LABSA and SiO2 NPs on oil-water interfacial tension (IFT), wettability alteration, and surfactant adsorption on the rock surfaces were evaluated. The results of IFT/contact angle measurements showed that by adding 0.03 wt% LABSA, the IFT, and contact angle reduced from the initial values of 36.9 mN/m and 115.6° ± 0.2° to 8.3 mN/m and 100.3° ± 0.4°, respectively. Furthermore, incorporating SiO2 NPs (0.1 wt%) into the system causes a further decrease in IFT value (dropped to 2.2 mN/m), along with a substantial reduction in contact angle (final contact angle after 6 h soaking into the solution was measured as 64.8° ± 0.3°). In addition, surfactant loss due to the adsorption on the rock surfaces decreased up to 35% in the presence of SiO2 NPs (0.1 wt%). Moreover, various core flooding scenarios in carbonate plugs with different initial wettability conditions were conducted, and the performance of the EOR agents in enhancing oil recovery from oil-wet and water-wet core samples in the secondary and tertiary mode of flooding was evaluated. The outcomes revealed that the injection of a combination of chemicals, containing LABSA (0.03 wt %) and SiO2 (0.1 wt%) in the secondary mode leads to the highest ultimate oil recovery from sister carbonate core samples.http://www.sciencedirect.com/science/article/pii/S2405656121000249LABSAEnhanced oil recoverySilica nanoparticlesIFTContact angleAdsorption |
| spellingShingle | Amin Rezaei Amin Khodabakhshi Amir Esmaeili Mehdi Razavifar Effects of initial wettability and different surfactant-silica nanoparticles flooding scenarios on oil-recovery from carbonate rocks Petroleum LABSA Enhanced oil recovery Silica nanoparticles IFT Contact angle Adsorption |
| title | Effects of initial wettability and different surfactant-silica nanoparticles flooding scenarios on oil-recovery from carbonate rocks |
| title_full | Effects of initial wettability and different surfactant-silica nanoparticles flooding scenarios on oil-recovery from carbonate rocks |
| title_fullStr | Effects of initial wettability and different surfactant-silica nanoparticles flooding scenarios on oil-recovery from carbonate rocks |
| title_full_unstemmed | Effects of initial wettability and different surfactant-silica nanoparticles flooding scenarios on oil-recovery from carbonate rocks |
| title_short | Effects of initial wettability and different surfactant-silica nanoparticles flooding scenarios on oil-recovery from carbonate rocks |
| title_sort | effects of initial wettability and different surfactant silica nanoparticles flooding scenarios on oil recovery from carbonate rocks |
| topic | LABSA Enhanced oil recovery Silica nanoparticles IFT Contact angle Adsorption |
| url | http://www.sciencedirect.com/science/article/pii/S2405656121000249 |
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