Crystal structure of (E)-diethyl 2-[(1-phenylsulfonyl-1H-indol-3-yl)methylidene]succinate
In the title compound, C23H23NO6S, the phenyl ring is perpendicular [dihedral angle = 89.34 (9)°] to the indole ring system. In the molecule, the ethoxy groups are each disordered over two sets of sites with occupancy ratios of 0.671 (6):0.329 (6) and 0.75 (3):0.25 (3). The molecular conformation is...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2015-12-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989015023075 |
| _version_ | 1798031001318850560 |
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| author | M. Umadevi Potharaju Raju R. Yamuna Arasambattu K. Mohanakrishnan G. Chakkaravarthi |
| author_facet | M. Umadevi Potharaju Raju R. Yamuna Arasambattu K. Mohanakrishnan G. Chakkaravarthi |
| author_sort | M. Umadevi |
| collection | DOAJ |
| description | In the title compound, C23H23NO6S, the phenyl ring is perpendicular [dihedral angle = 89.34 (9)°] to the indole ring system. In the molecule, the ethoxy groups are each disordered over two sets of sites with occupancy ratios of 0.671 (6):0.329 (6) and 0.75 (3):0.25 (3). The molecular conformation is consolidated by a weak C—H...O interaction, which generates an S(6) graph–set motif. The packing of the molecules in the crystal structure features weak C—H...π interactions. |
| first_indexed | 2024-04-11T19:50:15Z |
| format | Article |
| id | doaj.art-5be76cc24c0a44ae91607824b4e8f9bf |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-04-11T19:50:15Z |
| publishDate | 2015-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-5be76cc24c0a44ae91607824b4e8f9bf2022-12-22T04:06:20ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-12-017112o1029o103010.1107/S2056989015023075rk2433Crystal structure of (E)-diethyl 2-[(1-phenylsulfonyl-1H-indol-3-yl)methylidene]succinateM. Umadevi0Potharaju Raju1R. Yamuna2Arasambattu K. Mohanakrishnan3G. Chakkaravarthi4Research and Development Centre, Bharathiar University, Coimbatore 641 046, IndiaDepartment of Organic Chemistry, University of Madras, Guindy Campus, Chennai 600 025, IndiaDepartment of Sciences, Chemistry and Materials Research Lab, Amrita Vishwa Vidyapeetham University, Ettimadai, Coimbatore 641 112, IndiaDepartment of Organic Chemistry, University of Madras, Guindy Campus, Chennai 600 025, IndiaDepartment of Physics, CPCL Polytechnic College, Chennai 600 068, IndiaIn the title compound, C23H23NO6S, the phenyl ring is perpendicular [dihedral angle = 89.34 (9)°] to the indole ring system. In the molecule, the ethoxy groups are each disordered over two sets of sites with occupancy ratios of 0.671 (6):0.329 (6) and 0.75 (3):0.25 (3). The molecular conformation is consolidated by a weak C—H...O interaction, which generates an S(6) graph–set motif. The packing of the molecules in the crystal structure features weak C—H...π interactions.http://scripts.iucr.org/cgi-bin/paper?S2056989015023075crystal structureindole derivativehydrogen bonding |
| spellingShingle | M. Umadevi Potharaju Raju R. Yamuna Arasambattu K. Mohanakrishnan G. Chakkaravarthi Crystal structure of (E)-diethyl 2-[(1-phenylsulfonyl-1H-indol-3-yl)methylidene]succinate Acta Crystallographica Section E: Crystallographic Communications crystal structure indole derivative hydrogen bonding |
| title | Crystal structure of (E)-diethyl 2-[(1-phenylsulfonyl-1H-indol-3-yl)methylidene]succinate |
| title_full | Crystal structure of (E)-diethyl 2-[(1-phenylsulfonyl-1H-indol-3-yl)methylidene]succinate |
| title_fullStr | Crystal structure of (E)-diethyl 2-[(1-phenylsulfonyl-1H-indol-3-yl)methylidene]succinate |
| title_full_unstemmed | Crystal structure of (E)-diethyl 2-[(1-phenylsulfonyl-1H-indol-3-yl)methylidene]succinate |
| title_short | Crystal structure of (E)-diethyl 2-[(1-phenylsulfonyl-1H-indol-3-yl)methylidene]succinate |
| title_sort | crystal structure of e diethyl 2 1 phenylsulfonyl 1h indol 3 yl methylidene succinate |
| topic | crystal structure indole derivative hydrogen bonding |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989015023075 |
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