NANOSCALE BARIUM HYDROSILICATES: CHOOSING THE SYNTHESIS TECHNOLOGY

Cement concretes are the most used materials in modern civil engineering. Due to that such materials draw great attention both in the Russian Federation and abroad. The possibility to enhance the manufacturability and operational properties of concretes results in significant reduction of overall op...

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Main Authors: GRISHINA Anna Nikolaevna, KOROLEV Evgenij Valerjevich
Format: Article
Language:English
Published: OOO "CNT «NanoStroitelstvo» 2013-08-01
Series:Нанотехнологии в строительстве
Subjects:
Online Access:http://nanobuild.ru/en_EN/journal/Nanobuild-4-2013/111-119.pdf
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author GRISHINA Anna Nikolaevna
KOROLEV Evgenij Valerjevich
author_facet GRISHINA Anna Nikolaevna
KOROLEV Evgenij Valerjevich
author_sort GRISHINA Anna Nikolaevna
collection DOAJ
description Cement concretes are the most used materials in modern civil engineering. Due to that such materials draw great attention both in the Russian Federation and abroad. The possibility to enhance the manufacturability and operational properties of concretes results in significant reduction of overall operating costs. Many enhancement methods have been elaborated. Among them there is one based on introduction of calcium hydrosilicates into construction composition. The authors set up a hypothesis that similarity between properties and structures of different hydrosilicates (for example, alkaline earth metals and metals of the second group) will provide similar increased operational characteristics. The specialists of Research and Educational Center «Nanotechnology» are developing cement composites nanomodification methods which include introduction of nanodimensional barium hydrosilicates particles. The synthesis of barium hydrosilicates particles can be done with the use of many technologies, different by energy consumption or performing complexity. Taking into account both these factors, one can assume that low-temperature sol-gel synthesis from diluted water solutions is the proper technology. The present paper shows that this assumption is correct. The selection of certain technology is made by the means of multiobjective optimization, which is in turn is performed by the means of linear scalarization. This method, while not always giving the Pareto optimal solutions, can be easily implemented. The particle size distribution is taken into consideration during selection of objectives and weights. It is shown that selected technology allows manufacturing nanoparticles with median size about 30 nm.
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spelling doaj.art-5beb366ae8944e0dbde7ae7b59c674ea2022-12-21T19:40:42ZengOOO "CNT «NanoStroitelstvo»Нанотехнологии в строительстве2075-85452013-08-0154111119NANOSCALE BARIUM HYDROSILICATES: CHOOSING THE SYNTHESIS TECHNOLOGYGRISHINA Anna Nikolaevna0KOROLEV Evgenij Valerjevich1Ph.D. in Engineering, Research Officer of the Research and Educational Center «Nanotechnology», Moscow State University of Civil Engineering, Russian Federation; Yaroslavskoye hw.26, 129337, Moscow, Russian FederationDoctor of Engineering, Professor, Director of the Research and Educational Center «Nanotechnology», Moscow State University of Civil Engineering, Russian Federation; Yaroslavskoye hw.26, 129337, Moscow, Russian FederationCement concretes are the most used materials in modern civil engineering. Due to that such materials draw great attention both in the Russian Federation and abroad. The possibility to enhance the manufacturability and operational properties of concretes results in significant reduction of overall operating costs. Many enhancement methods have been elaborated. Among them there is one based on introduction of calcium hydrosilicates into construction composition. The authors set up a hypothesis that similarity between properties and structures of different hydrosilicates (for example, alkaline earth metals and metals of the second group) will provide similar increased operational characteristics. The specialists of Research and Educational Center «Nanotechnology» are developing cement composites nanomodification methods which include introduction of nanodimensional barium hydrosilicates particles. The synthesis of barium hydrosilicates particles can be done with the use of many technologies, different by energy consumption or performing complexity. Taking into account both these factors, one can assume that low-temperature sol-gel synthesis from diluted water solutions is the proper technology. The present paper shows that this assumption is correct. The selection of certain technology is made by the means of multiobjective optimization, which is in turn is performed by the means of linear scalarization. This method, while not always giving the Pareto optimal solutions, can be easily implemented. The particle size distribution is taken into consideration during selection of objectives and weights. It is shown that selected technology allows manufacturing nanoparticles with median size about 30 nm.http://nanobuild.ru/en_EN/journal/Nanobuild-4-2013/111-119.pdfsynthesis technologynanoparticlesbarium hydrosilicatesefficiency of technology
spellingShingle GRISHINA Anna Nikolaevna
KOROLEV Evgenij Valerjevich
NANOSCALE BARIUM HYDROSILICATES: CHOOSING THE SYNTHESIS TECHNOLOGY
Нанотехнологии в строительстве
synthesis technology
nanoparticles
barium hydrosilicates
efficiency of technology
title NANOSCALE BARIUM HYDROSILICATES: CHOOSING THE SYNTHESIS TECHNOLOGY
title_full NANOSCALE BARIUM HYDROSILICATES: CHOOSING THE SYNTHESIS TECHNOLOGY
title_fullStr NANOSCALE BARIUM HYDROSILICATES: CHOOSING THE SYNTHESIS TECHNOLOGY
title_full_unstemmed NANOSCALE BARIUM HYDROSILICATES: CHOOSING THE SYNTHESIS TECHNOLOGY
title_short NANOSCALE BARIUM HYDROSILICATES: CHOOSING THE SYNTHESIS TECHNOLOGY
title_sort nanoscale barium hydrosilicates choosing the synthesis technology
topic synthesis technology
nanoparticles
barium hydrosilicates
efficiency of technology
url http://nanobuild.ru/en_EN/journal/Nanobuild-4-2013/111-119.pdf
work_keys_str_mv AT grishinaannanikolaevna nanoscalebariumhydrosilicateschoosingthesynthesistechnology
AT korolevevgenijvalerjevich nanoscalebariumhydrosilicateschoosingthesynthesistechnology