Dipotassium 1,3,4-thiadiazole-2,5-bis(thiolate) as a new S-donor for direct synthesis of symmetrical disulfides
Abstract In this research, a simple, efficient and novel protocol is eveloped for the direct synthesis of symmetrical disulfides using dipotassium 1,3,4-thiadiazole-2,5-bis(thiolate) as a new, low toxicity, inexpensive, stable solid and free of foul-smelling thiols for synthesize symmetric diaryl/di...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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Nature Portfolio
2022-09-01
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| Series: | Scientific Reports |
| Online Access: | https://doi.org/10.1038/s41598-022-20642-5 |
| _version_ | 1797998314185031680 |
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| author | Mohammad Soleiman-Beigi Mohammad Alikarami Homa Kohzadi Zahra Akbari |
| author_facet | Mohammad Soleiman-Beigi Mohammad Alikarami Homa Kohzadi Zahra Akbari |
| author_sort | Mohammad Soleiman-Beigi |
| collection | DOAJ |
| description | Abstract In this research, a simple, efficient and novel protocol is eveloped for the direct synthesis of symmetrical disulfides using dipotassium 1,3,4-thiadiazole-2,5-bis(thiolate) as a new, low toxicity, inexpensive, stable solid and free of foul-smelling thiols for synthesize symmetric diaryl/dialkyl disulfides from aryl and alkyl halides in presence of MOF-199 and CuO nanoparticles. Significantly, using this method results in obtaining a variety of symmetrical disulfides in moderate to excellent yields (up to 98%). |
| first_indexed | 2024-04-11T10:46:44Z |
| format | Article |
| id | doaj.art-5c139f6f2ea440cbb3f9c0e09fbef913 |
| institution | Directory Open Access Journal |
| issn | 2045-2322 |
| language | English |
| last_indexed | 2024-04-11T10:46:44Z |
| publishDate | 2022-09-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Scientific Reports |
| spelling | doaj.art-5c139f6f2ea440cbb3f9c0e09fbef9132022-12-22T04:29:01ZengNature PortfolioScientific Reports2045-23222022-09-011211810.1038/s41598-022-20642-5Dipotassium 1,3,4-thiadiazole-2,5-bis(thiolate) as a new S-donor for direct synthesis of symmetrical disulfidesMohammad Soleiman-Beigi0Mohammad Alikarami1Homa Kohzadi2Zahra Akbari3Department of Chemistry, Faculty of Science, Ilam UniversityDepartment of Chemistry, Ilam Branch, Islamic Azad UniversityDepartment of Chemistry, Faculty of Science, Ilam UniversityDepartment of Chemistry, Faculty of Science, Ilam UniversityAbstract In this research, a simple, efficient and novel protocol is eveloped for the direct synthesis of symmetrical disulfides using dipotassium 1,3,4-thiadiazole-2,5-bis(thiolate) as a new, low toxicity, inexpensive, stable solid and free of foul-smelling thiols for synthesize symmetric diaryl/dialkyl disulfides from aryl and alkyl halides in presence of MOF-199 and CuO nanoparticles. Significantly, using this method results in obtaining a variety of symmetrical disulfides in moderate to excellent yields (up to 98%).https://doi.org/10.1038/s41598-022-20642-5 |
| spellingShingle | Mohammad Soleiman-Beigi Mohammad Alikarami Homa Kohzadi Zahra Akbari Dipotassium 1,3,4-thiadiazole-2,5-bis(thiolate) as a new S-donor for direct synthesis of symmetrical disulfides Scientific Reports |
| title | Dipotassium 1,3,4-thiadiazole-2,5-bis(thiolate) as a new S-donor for direct synthesis of symmetrical disulfides |
| title_full | Dipotassium 1,3,4-thiadiazole-2,5-bis(thiolate) as a new S-donor for direct synthesis of symmetrical disulfides |
| title_fullStr | Dipotassium 1,3,4-thiadiazole-2,5-bis(thiolate) as a new S-donor for direct synthesis of symmetrical disulfides |
| title_full_unstemmed | Dipotassium 1,3,4-thiadiazole-2,5-bis(thiolate) as a new S-donor for direct synthesis of symmetrical disulfides |
| title_short | Dipotassium 1,3,4-thiadiazole-2,5-bis(thiolate) as a new S-donor for direct synthesis of symmetrical disulfides |
| title_sort | dipotassium 1 3 4 thiadiazole 2 5 bis thiolate as a new s donor for direct synthesis of symmetrical disulfides |
| url | https://doi.org/10.1038/s41598-022-20642-5 |
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