{μ-2,2′-(Ethane-1,2-diyl)bis[4,6-bis(trimethylsilyl)-1,3-dihydrocyclopenta[c]pyrrol-5-one]}bis[tricarbonyliron(0)]
The binuclear title compound, [Fe2(C28H48N2O2Si4)(CO)6], consists of two central iron(0) atoms, each of them surrounded by a cyclopentadienone moiety and three carbonyl ligands in a three-legged piano-stool shape. Furthermore, the bis(cyclopentadienone) ligand acts as a bridge between the two metal...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2023-04-01
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| Series: | IUCrData |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314623003462 |
| _version_ | 1797832833998258176 |
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| author | Hilario D. Huerta-Zerón Anke Spannenberg Matthias Beller Henrik Junge |
| author_facet | Hilario D. Huerta-Zerón Anke Spannenberg Matthias Beller Henrik Junge |
| author_sort | Hilario D. Huerta-Zerón |
| collection | DOAJ |
| description | The binuclear title compound, [Fe2(C28H48N2O2Si4)(CO)6], consists of two central iron(0) atoms, each of them surrounded by a cyclopentadienone moiety and three carbonyl ligands in a three-legged piano-stool shape. Furthermore, the bis(cyclopentadienone) ligand acts as a bridge between the two metal atoms. |
| first_indexed | 2024-04-09T14:15:10Z |
| format | Article |
| id | doaj.art-5c1b0b68aa5f48298dc1a3ab33e4fb5e |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-04-09T14:15:10Z |
| publishDate | 2023-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-5c1b0b68aa5f48298dc1a3ab33e4fb5e2023-05-05T14:05:03ZengInternational Union of CrystallographyIUCrData2414-31462023-04-0184x23034610.1107/S2414314623003462bh4073{μ-2,2′-(Ethane-1,2-diyl)bis[4,6-bis(trimethylsilyl)-1,3-dihydrocyclopenta[c]pyrrol-5-one]}bis[tricarbonyliron(0)]Hilario D. Huerta-Zerón0Anke Spannenberg1Matthias Beller2Henrik Junge3Leibniz-Institut für Katalyse e. V., Albert-Einstein-Strasse 29a, 18059 Rostock, GermanyLeibniz-Institut für Katalyse e. V., Albert-Einstein-Strasse 29a, 18059 Rostock, GermanyLeibniz-Institut für Katalyse e. V., Albert-Einstein-Strasse 29a, 18059 Rostock, GermanyLeibniz-Institut für Katalyse e. V., Albert-Einstein-Strasse 29a, 18059 Rostock, GermanyThe binuclear title compound, [Fe2(C28H48N2O2Si4)(CO)6], consists of two central iron(0) atoms, each of them surrounded by a cyclopentadienone moiety and three carbonyl ligands in a three-legged piano-stool shape. Furthermore, the bis(cyclopentadienone) ligand acts as a bridge between the two metal atoms.http://scripts.iucr.org/cgi-bin/paper?S2414314623003462crystal structureiron carbonyl complexcyclopentadienone ligandbinuclear complex |
| spellingShingle | Hilario D. Huerta-Zerón Anke Spannenberg Matthias Beller Henrik Junge {μ-2,2′-(Ethane-1,2-diyl)bis[4,6-bis(trimethylsilyl)-1,3-dihydrocyclopenta[c]pyrrol-5-one]}bis[tricarbonyliron(0)] IUCrData crystal structure iron carbonyl complex cyclopentadienone ligand binuclear complex |
| title | {μ-2,2′-(Ethane-1,2-diyl)bis[4,6-bis(trimethylsilyl)-1,3-dihydrocyclopenta[c]pyrrol-5-one]}bis[tricarbonyliron(0)] |
| title_full | {μ-2,2′-(Ethane-1,2-diyl)bis[4,6-bis(trimethylsilyl)-1,3-dihydrocyclopenta[c]pyrrol-5-one]}bis[tricarbonyliron(0)] |
| title_fullStr | {μ-2,2′-(Ethane-1,2-diyl)bis[4,6-bis(trimethylsilyl)-1,3-dihydrocyclopenta[c]pyrrol-5-one]}bis[tricarbonyliron(0)] |
| title_full_unstemmed | {μ-2,2′-(Ethane-1,2-diyl)bis[4,6-bis(trimethylsilyl)-1,3-dihydrocyclopenta[c]pyrrol-5-one]}bis[tricarbonyliron(0)] |
| title_short | {μ-2,2′-(Ethane-1,2-diyl)bis[4,6-bis(trimethylsilyl)-1,3-dihydrocyclopenta[c]pyrrol-5-one]}bis[tricarbonyliron(0)] |
| title_sort | μ 2 2 ethane 1 2 diyl bis 4 6 bis trimethylsilyl 1 3 dihydrocyclopenta c pyrrol 5 one bis tricarbonyliron 0 |
| topic | crystal structure iron carbonyl complex cyclopentadienone ligand binuclear complex |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314623003462 |
| work_keys_str_mv | AT hilariodhuertazeron m22ethane12diylbis46bistrimethylsilyl13dihydrocyclopentacpyrrol5onebistricarbonyliron0 AT ankespannenberg m22ethane12diylbis46bistrimethylsilyl13dihydrocyclopentacpyrrol5onebistricarbonyliron0 AT matthiasbeller m22ethane12diylbis46bistrimethylsilyl13dihydrocyclopentacpyrrol5onebistricarbonyliron0 AT henrikjunge m22ethane12diylbis46bistrimethylsilyl13dihydrocyclopentacpyrrol5onebistricarbonyliron0 |