Octacarbonyldi-μ2-hydrido-[μ3-(1,3,5-trimethylphenyl)phosphinidene](triphenylphosphane)-triangulo-triruthenium
In the crystal structure of the title compound, [Ru3(C9H11P)H2(C18H15P)(CO)8], the triangular Ru3 unit is capped with one mesitylphosphinidene ligand. In the trigonal–pyramidal Ru3P core, one RuII atom is coordinated by a triphenylphosphane ligand in a terminal fashion. Two hydride lig...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812039499 |
| _version_ | 1798025833866067968 |
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| author | Taeko Kakizawa |
| author_facet | Taeko Kakizawa |
| author_sort | Taeko Kakizawa |
| collection | DOAJ |
| description | In the crystal structure of the title compound, [Ru3(C9H11P)H2(C18H15P)(CO)8], the triangular Ru3 unit is capped with one mesitylphosphinidene ligand. In the trigonal–pyramidal Ru3P core, one RuII atom is coordinated by a triphenylphosphane ligand in a terminal fashion. Two hydride ligands bridge over two Ru—Ru bonds. These Ru—Ru bonds [2.9400 (4) and 2.9432 (4) Å] are slightly longer than the nonhydride-bridged Ru—Ru bond [2.8146 (4) Å]. The terminal triphenylphosphane ligand coordinates to the RuII atom, which is involved in two hydride bridges. |
| first_indexed | 2024-04-11T18:26:23Z |
| format | Article |
| id | doaj.art-5c3fc1b7a7aa43b6956d2f7e9bfa5dc0 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T18:26:23Z |
| publishDate | 2012-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-5c3fc1b7a7aa43b6956d2f7e9bfa5dc02022-12-22T04:09:37ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-10-016810m1293m129310.1107/S1600536812039499Octacarbonyldi-μ2-hydrido-[μ3-(1,3,5-trimethylphenyl)phosphinidene](triphenylphosphane)-triangulo-trirutheniumTaeko KakizawaIn the crystal structure of the title compound, [Ru3(C9H11P)H2(C18H15P)(CO)8], the triangular Ru3 unit is capped with one mesitylphosphinidene ligand. In the trigonal–pyramidal Ru3P core, one RuII atom is coordinated by a triphenylphosphane ligand in a terminal fashion. Two hydride ligands bridge over two Ru—Ru bonds. These Ru—Ru bonds [2.9400 (4) and 2.9432 (4) Å] are slightly longer than the nonhydride-bridged Ru—Ru bond [2.8146 (4) Å]. The terminal triphenylphosphane ligand coordinates to the RuII atom, which is involved in two hydride bridges.http://scripts.iucr.org/cgi-bin/paper?S1600536812039499 |
| spellingShingle | Taeko Kakizawa Octacarbonyldi-μ2-hydrido-[μ3-(1,3,5-trimethylphenyl)phosphinidene](triphenylphosphane)-triangulo-triruthenium Acta Crystallographica Section E |
| title | Octacarbonyldi-μ2-hydrido-[μ3-(1,3,5-trimethylphenyl)phosphinidene](triphenylphosphane)-triangulo-triruthenium |
| title_full | Octacarbonyldi-μ2-hydrido-[μ3-(1,3,5-trimethylphenyl)phosphinidene](triphenylphosphane)-triangulo-triruthenium |
| title_fullStr | Octacarbonyldi-μ2-hydrido-[μ3-(1,3,5-trimethylphenyl)phosphinidene](triphenylphosphane)-triangulo-triruthenium |
| title_full_unstemmed | Octacarbonyldi-μ2-hydrido-[μ3-(1,3,5-trimethylphenyl)phosphinidene](triphenylphosphane)-triangulo-triruthenium |
| title_short | Octacarbonyldi-μ2-hydrido-[μ3-(1,3,5-trimethylphenyl)phosphinidene](triphenylphosphane)-triangulo-triruthenium |
| title_sort | octacarbonyldi amp 956 2 hydrido amp 956 3 1 3 5 trimethylphenyl phosphinidene triphenylphosphane triangulo triruthenium |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812039499 |
| work_keys_str_mv | AT taekokakizawa octacarbonyldiamp9562hydridoamp9563135trimethylphenylphosphinidenetriphenylphosphanetriangulotriruthenium |