μ-2-Aminoterephthalato-κ2O1:O4-bis[triphenyltin(IV)]

μ-2-Aminoterephthalato-κ2O1:O4-bis[triphenyltin(IV)]

The title compound, [Sn2(C6H5)6(C8H5NO4)], contains two triphenyltin groups bridged by a 2-aminoterephthalate ligand. The two SnIV centers have similar distorted tetrahedral coordination geometries. Each SnIV atom is bonded to three phenyl C atoms and one O atom from a carboxylate group. The other O...

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Bibliographic Details
Main Authors: Wenkuan Li, Handong Yin, Lei Dong, Jing Li, Qijun Zhang
Format: Article
Language:English
Published: International Union of Crystallography 2009-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809043554
Description
Summary:The title compound, [Sn2(C6H5)6(C8H5NO4)], contains two triphenyltin groups bridged by a 2-aminoterephthalate ligand. The two SnIV centers have similar distorted tetrahedral coordination geometries. Each SnIV atom is bonded to three phenyl C atoms and one O atom from a carboxylate group. The other O atom of the carboxylate group has a weak interaction with the Sn atom. The amino group is disordered over two sites, with site-occupancy factors of 0.779 (11) and 0.221 (11). Intramolecular N—H...O hydrogen bonds are observed.
ISSN:1600-5368

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