Surface-Treated Recycling Fibers from Wind Turbine Blades as Reinforcement for Waste Phosphogypsum

An attempt at the treatment of the waste fiber (WF) from the wind turbine blade (WTB) was made through the modifier of dopamine hydrochloride and the compound modifier of dopamine hydrochloride and 2,5-dihydroxy terephthalic acid or 3,4-dihydroxy cinnamic acid or 3,4-dihydroxy benzonitrile, correspo...

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Main Authors: Lilin Yang, Weilin Zhao, Daobei Wang, Yang Liu, Dongzhi Wang, Na Cui
Format: Article
Language:English
Published: MDPI AG 2022-12-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/27/24/8668
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author Lilin Yang
Weilin Zhao
Daobei Wang
Yang Liu
Dongzhi Wang
Na Cui
author_facet Lilin Yang
Weilin Zhao
Daobei Wang
Yang Liu
Dongzhi Wang
Na Cui
author_sort Lilin Yang
collection DOAJ
description An attempt at the treatment of the waste fiber (WF) from the wind turbine blade (WTB) was made through the modifier of dopamine hydrochloride and the compound modifier of dopamine hydrochloride and 2,5-dihydroxy terephthalic acid or 3,4-dihydroxy cinnamic acid or 3,4-dihydroxy benzonitrile, corresponding to obtain four modified waste fibers (MWF1, MWF2, MWF3, and MWF4). The MWFs samples’ microstructure properties were characterized using SEM, EDS, XPS, FTIR analyses, and water contact angle tests. The results revealed that all the MWF surfaces were wrapped by a distinct coating layer and had different elemental compositions and chemical groups, demonstrating the significant effect of the four modifications on the WF surfaces. The hydroxyl, amino, or nitrile groups were grafted onto the WF surfaces causing improvement of the hydrophilicity and reactivity. Furthermore, all the MWFs as the reinforced materials were incorporated into the industrial waste phosphogypsum (PG) to manufacture the phosphorous-building gypsum composites (PBGC). The effects on the micro-morphology and mechanical properties of the PBGC were evaluated. The results also show the improvement in flexural and compressive strength with the addition of MWFs into the PBGC, due to the enhancement of the compactness between the MWF and phosphogypsum matrix. In particular, the effects of three compound modifiers on the flexural and compressive strength are more significant. The highest flexural and compressive strength was contributed by the PBGC-MWF4 with 2% dosage using a compound modifier of dopamine hydrochloride and 3,4-dihydroxy benzonitrile, which were enhanced 61.04% and 25.97% compared with the PBG.
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spelling doaj.art-5c7b409716574f369b50151d458b16a72023-11-24T16:55:23ZengMDPI AGMolecules1420-30492022-12-012724866810.3390/molecules27248668Surface-Treated Recycling Fibers from Wind Turbine Blades as Reinforcement for Waste PhosphogypsumLilin Yang0Weilin Zhao1Daobei Wang2Yang Liu3Dongzhi Wang4Na Cui5School of Materials Science and Engineering, University of Jinan, Jinan 250000, ChinaSchool of Materials Science and Engineering, University of Jinan, Jinan 250000, ChinaSchool of Materials Science and Engineering, University of Jinan, Jinan 250000, ChinaSchool of Materials Science and Engineering, University of Jinan, Jinan 250000, ChinaSchool of Materials Science and Engineering, University of Jinan, Jinan 250000, ChinaSchool of Civil Engineering and Architecture, University of Jinan, Jinan 250000, ChinaAn attempt at the treatment of the waste fiber (WF) from the wind turbine blade (WTB) was made through the modifier of dopamine hydrochloride and the compound modifier of dopamine hydrochloride and 2,5-dihydroxy terephthalic acid or 3,4-dihydroxy cinnamic acid or 3,4-dihydroxy benzonitrile, corresponding to obtain four modified waste fibers (MWF1, MWF2, MWF3, and MWF4). The MWFs samples’ microstructure properties were characterized using SEM, EDS, XPS, FTIR analyses, and water contact angle tests. The results revealed that all the MWF surfaces were wrapped by a distinct coating layer and had different elemental compositions and chemical groups, demonstrating the significant effect of the four modifications on the WF surfaces. The hydroxyl, amino, or nitrile groups were grafted onto the WF surfaces causing improvement of the hydrophilicity and reactivity. Furthermore, all the MWFs as the reinforced materials were incorporated into the industrial waste phosphogypsum (PG) to manufacture the phosphorous-building gypsum composites (PBGC). The effects on the micro-morphology and mechanical properties of the PBGC were evaluated. The results also show the improvement in flexural and compressive strength with the addition of MWFs into the PBGC, due to the enhancement of the compactness between the MWF and phosphogypsum matrix. In particular, the effects of three compound modifiers on the flexural and compressive strength are more significant. The highest flexural and compressive strength was contributed by the PBGC-MWF4 with 2% dosage using a compound modifier of dopamine hydrochloride and 3,4-dihydroxy benzonitrile, which were enhanced 61.04% and 25.97% compared with the PBG.https://www.mdpi.com/1420-3049/27/24/8668waste fiberwind turbine bladephosphogypsumsurface treatment
spellingShingle Lilin Yang
Weilin Zhao
Daobei Wang
Yang Liu
Dongzhi Wang
Na Cui
Surface-Treated Recycling Fibers from Wind Turbine Blades as Reinforcement for Waste Phosphogypsum
Molecules
waste fiber
wind turbine blade
phosphogypsum
surface treatment
title Surface-Treated Recycling Fibers from Wind Turbine Blades as Reinforcement for Waste Phosphogypsum
title_full Surface-Treated Recycling Fibers from Wind Turbine Blades as Reinforcement for Waste Phosphogypsum
title_fullStr Surface-Treated Recycling Fibers from Wind Turbine Blades as Reinforcement for Waste Phosphogypsum
title_full_unstemmed Surface-Treated Recycling Fibers from Wind Turbine Blades as Reinforcement for Waste Phosphogypsum
title_short Surface-Treated Recycling Fibers from Wind Turbine Blades as Reinforcement for Waste Phosphogypsum
title_sort surface treated recycling fibers from wind turbine blades as reinforcement for waste phosphogypsum
topic waste fiber
wind turbine blade
phosphogypsum
surface treatment
url https://www.mdpi.com/1420-3049/27/24/8668
work_keys_str_mv AT lilinyang surfacetreatedrecyclingfibersfromwindturbinebladesasreinforcementforwastephosphogypsum
AT weilinzhao surfacetreatedrecyclingfibersfromwindturbinebladesasreinforcementforwastephosphogypsum
AT daobeiwang surfacetreatedrecyclingfibersfromwindturbinebladesasreinforcementforwastephosphogypsum
AT yangliu surfacetreatedrecyclingfibersfromwindturbinebladesasreinforcementforwastephosphogypsum
AT dongzhiwang surfacetreatedrecyclingfibersfromwindturbinebladesasreinforcementforwastephosphogypsum
AT nacui surfacetreatedrecyclingfibersfromwindturbinebladesasreinforcementforwastephosphogypsum