Synthesis and efficiency comparison of reed straw-based biochar as a mesoporous adsorbent for ionic dyes removal

The reed straw is assessed as a potential source of widely available renewable biomass for biochar production and compared with two other waste-based biomasses, namely fruit stones blend, and brewery spent grains. The biochars were activated via steam and CO2. While steam activation yielded 12 % car...

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Main Authors: Oleksii Tomin, Riku Vahala, Maryam R. Yazdani
Format: Article
Language:English
Published: Elsevier 2024-01-01
Series:Heliyon
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2405844024007539
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author Oleksii Tomin
Riku Vahala
Maryam R. Yazdani
author_facet Oleksii Tomin
Riku Vahala
Maryam R. Yazdani
author_sort Oleksii Tomin
collection DOAJ
description The reed straw is assessed as a potential source of widely available renewable biomass for biochar production and compared with two other waste-based biomasses, namely fruit stones blend, and brewery spent grains. The biochars were activated via steam and CO2. While steam activation yielded 12 % carbon from reed biomass, CO2 activation resulted in biomass degradation. The characterization of reed biochar showed a mesoporous structure and a high surface area of 514 m2/g. The adsorption tests displayed a decent adsorption capacity of biochar, with values of 92.6 mg/g for methylene violet dye and 35.7 mg/g for acid green dye. Only 1 g/L dosage of reed biochar was able to remove 99 % of the 50 mg/L methylene violet solution in 15 min and 60 % of the 50 mg/L acid green solution in 10 min. The obtained results demonstrate reed biomass as a suitable source for biochar production as well as reed-based biochar as a promising dye adsorbent.
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spelling doaj.art-5c86431281684ec6ba0c2388628af4082024-02-03T06:38:17ZengElsevierHeliyon2405-84402024-01-01102e24722Synthesis and efficiency comparison of reed straw-based biochar as a mesoporous adsorbent for ionic dyes removalOleksii Tomin0Riku Vahala1Maryam R. Yazdani2Department of Built Environment, School of Engineering, Aalto University, P.O. Box 15200, FI-00076, Aalto, Finland; Corresponding author.Department of Built Environment, School of Engineering, Aalto University, P.O. Box 15200, FI-00076, Aalto, FinlandDepartment of Mechanical Engineering, School of Engineering, Aalto University, P.O. Box 14400, FI-00076, Aalto, Finland; Corresponding author.The reed straw is assessed as a potential source of widely available renewable biomass for biochar production and compared with two other waste-based biomasses, namely fruit stones blend, and brewery spent grains. The biochars were activated via steam and CO2. While steam activation yielded 12 % carbon from reed biomass, CO2 activation resulted in biomass degradation. The characterization of reed biochar showed a mesoporous structure and a high surface area of 514 m2/g. The adsorption tests displayed a decent adsorption capacity of biochar, with values of 92.6 mg/g for methylene violet dye and 35.7 mg/g for acid green dye. Only 1 g/L dosage of reed biochar was able to remove 99 % of the 50 mg/L methylene violet solution in 15 min and 60 % of the 50 mg/L acid green solution in 10 min. The obtained results demonstrate reed biomass as a suitable source for biochar production as well as reed-based biochar as a promising dye adsorbent.http://www.sciencedirect.com/science/article/pii/S2405844024007539BiocharReed straw biomassWaste biomassSteam activationCO2 activationMesoporous adsorbent
spellingShingle Oleksii Tomin
Riku Vahala
Maryam R. Yazdani
Synthesis and efficiency comparison of reed straw-based biochar as a mesoporous adsorbent for ionic dyes removal
Heliyon
Biochar
Reed straw biomass
Waste biomass
Steam activation
CO2 activation
Mesoporous adsorbent
title Synthesis and efficiency comparison of reed straw-based biochar as a mesoporous adsorbent for ionic dyes removal
title_full Synthesis and efficiency comparison of reed straw-based biochar as a mesoporous adsorbent for ionic dyes removal
title_fullStr Synthesis and efficiency comparison of reed straw-based biochar as a mesoporous adsorbent for ionic dyes removal
title_full_unstemmed Synthesis and efficiency comparison of reed straw-based biochar as a mesoporous adsorbent for ionic dyes removal
title_short Synthesis and efficiency comparison of reed straw-based biochar as a mesoporous adsorbent for ionic dyes removal
title_sort synthesis and efficiency comparison of reed straw based biochar as a mesoporous adsorbent for ionic dyes removal
topic Biochar
Reed straw biomass
Waste biomass
Steam activation
CO2 activation
Mesoporous adsorbent
url http://www.sciencedirect.com/science/article/pii/S2405844024007539
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AT maryamryazdani synthesisandefficiencycomparisonofreedstrawbasedbiocharasamesoporousadsorbentforionicdyesremoval