rac-7,7′,9,9′-Tetraphenyl-9a,9a′-bi(7,8,9,9a-tetrahydro-6aH-pentaleno[1,2,3-ij]naphthalen-8-one)
The racemic title compound, C54H38O2, consists of two C-linked pentaleno[1,2,3-ij]naphthalenone moieties, the crowded aryl ring substitution on the cyclopentane rings forcing the two segments to assume a conformation which has pseudo-twofold rotational symmetry, with a dihedral angle between the nap...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812014146 |
| _version_ | 1818960304402333696 |
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| author | Junwei Ye Weitao Gong Yuan Lin Guiling Ning Xiangdong Zhang |
| author_facet | Junwei Ye Weitao Gong Yuan Lin Guiling Ning Xiangdong Zhang |
| author_sort | Junwei Ye |
| collection | DOAJ |
| description | The racemic title compound, C54H38O2, consists of two C-linked pentaleno[1,2,3-ij]naphthalenone moieties, the crowded aryl ring substitution on the cyclopentane rings forcing the two segments to assume a conformation which has pseudo-twofold rotational symmetry, with a dihedral angle between the naphthalene substituent groups of 55.30 (8)°. In each segment, the two phenyl rings have different conformational orientations, with inter-ring dihedral angles of 34.7 (2) and 49.63 (16)°. Each cyclopentane ring has the same relative configuration in its four chiral centres and together with the fused naphthalene ring assumes an overall chair-like conformation. |
| first_indexed | 2024-12-20T11:55:24Z |
| format | Article |
| id | doaj.art-5c9f190eb41246cfb2b20e572571dfc1 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:55:24Z |
| publishDate | 2012-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-5c9f190eb41246cfb2b20e572571dfc12022-12-21T19:41:40ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-05-01685o1329o132910.1107/S1600536812014146rac-7,7′,9,9′-Tetraphenyl-9a,9a′-bi(7,8,9,9a-tetrahydro-6aH-pentaleno[1,2,3-ij]naphthalen-8-one)Junwei YeWeitao GongYuan LinGuiling NingXiangdong ZhangThe racemic title compound, C54H38O2, consists of two C-linked pentaleno[1,2,3-ij]naphthalenone moieties, the crowded aryl ring substitution on the cyclopentane rings forcing the two segments to assume a conformation which has pseudo-twofold rotational symmetry, with a dihedral angle between the naphthalene substituent groups of 55.30 (8)°. In each segment, the two phenyl rings have different conformational orientations, with inter-ring dihedral angles of 34.7 (2) and 49.63 (16)°. Each cyclopentane ring has the same relative configuration in its four chiral centres and together with the fused naphthalene ring assumes an overall chair-like conformation.http://scripts.iucr.org/cgi-bin/paper?S1600536812014146 |
| spellingShingle | Junwei Ye Weitao Gong Yuan Lin Guiling Ning Xiangdong Zhang rac-7,7′,9,9′-Tetraphenyl-9a,9a′-bi(7,8,9,9a-tetrahydro-6aH-pentaleno[1,2,3-ij]naphthalen-8-one) Acta Crystallographica Section E |
| title | rac-7,7′,9,9′-Tetraphenyl-9a,9a′-bi(7,8,9,9a-tetrahydro-6aH-pentaleno[1,2,3-ij]naphthalen-8-one) |
| title_full | rac-7,7′,9,9′-Tetraphenyl-9a,9a′-bi(7,8,9,9a-tetrahydro-6aH-pentaleno[1,2,3-ij]naphthalen-8-one) |
| title_fullStr | rac-7,7′,9,9′-Tetraphenyl-9a,9a′-bi(7,8,9,9a-tetrahydro-6aH-pentaleno[1,2,3-ij]naphthalen-8-one) |
| title_full_unstemmed | rac-7,7′,9,9′-Tetraphenyl-9a,9a′-bi(7,8,9,9a-tetrahydro-6aH-pentaleno[1,2,3-ij]naphthalen-8-one) |
| title_short | rac-7,7′,9,9′-Tetraphenyl-9a,9a′-bi(7,8,9,9a-tetrahydro-6aH-pentaleno[1,2,3-ij]naphthalen-8-one) |
| title_sort | rac 7 7 amp 8242 9 9 amp 8242 tetraphenyl 9a 9a amp 8242 bi 7 8 9 9a tetrahydro 6ah pentaleno 1 2 3 ij naphthalen 8 one |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812014146 |
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