Poly[pentaaquatetrakis(μ2-nicotinato-κ2N:O)(perchlorato-κO)lanthanum(III)disilver(I)]
In the title complex, [Ag2La(C6H4NO2)4(ClO4)(H2O)5]n, the LaIII atom, lying on a twofold rotation axis, is eight-coordinated by four O atoms from four nicotinate (nic) ligands and four water molecules in a distorted square-antiprismatic coordination geometry. The AgI atom is coordinated in an almost...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809026130 |
| _version_ | 1818887092892073984 |
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| author | Wen-Dong Song Chao-Hua Zhang Biao Guan |
| author_facet | Wen-Dong Song Chao-Hua Zhang Biao Guan |
| author_sort | Wen-Dong Song |
| collection | DOAJ |
| description | In the title complex, [Ag2La(C6H4NO2)4(ClO4)(H2O)5]n, the LaIII atom, lying on a twofold rotation axis, is eight-coordinated by four O atoms from four nicotinate (nic) ligands and four water molecules in a distorted square-antiprismatic coordination geometry. The AgI atom is coordinated in an almost linear fashion by two pyridyl N atoms of two nic ligands. The linear coordination is augmented by weak interactions with one O atom from a half-occupied ClO4− anion and a water molecule lying on a twofold axis. Two Ag(nic)2 units connect two La atoms, forming a cyclic unit. These units are further extended into an infinite zigzag chain. The chains are bridged by the disordered perchlorate ions via weak Ag—O [2.678 (2) Å] interactions. O—H...O hydrogen bonds, weak Ag...Ag [3.3340 (15) Å] interactions and π–π interactions between the pyridyl rings [centroid–centroid distance = 3.656 (2) Å] lead to a three-dimensional network. |
| first_indexed | 2024-12-19T16:31:44Z |
| format | Article |
| id | doaj.art-5cb961bfff9544e1af4ceb0704fc4320 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T16:31:44Z |
| publishDate | 2009-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-5cb961bfff9544e1af4ceb0704fc43202022-12-21T20:14:10ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-08-01658m896m89710.1107/S1600536809026130Poly[pentaaquatetrakis(μ2-nicotinato-κ2N:O)(perchlorato-κO)lanthanum(III)disilver(I)]Wen-Dong SongChao-Hua ZhangBiao GuanIn the title complex, [Ag2La(C6H4NO2)4(ClO4)(H2O)5]n, the LaIII atom, lying on a twofold rotation axis, is eight-coordinated by four O atoms from four nicotinate (nic) ligands and four water molecules in a distorted square-antiprismatic coordination geometry. The AgI atom is coordinated in an almost linear fashion by two pyridyl N atoms of two nic ligands. The linear coordination is augmented by weak interactions with one O atom from a half-occupied ClO4− anion and a water molecule lying on a twofold axis. Two Ag(nic)2 units connect two La atoms, forming a cyclic unit. These units are further extended into an infinite zigzag chain. The chains are bridged by the disordered perchlorate ions via weak Ag—O [2.678 (2) Å] interactions. O—H...O hydrogen bonds, weak Ag...Ag [3.3340 (15) Å] interactions and π–π interactions between the pyridyl rings [centroid–centroid distance = 3.656 (2) Å] lead to a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536809026130 |
| spellingShingle | Wen-Dong Song Chao-Hua Zhang Biao Guan Poly[pentaaquatetrakis(μ2-nicotinato-κ2N:O)(perchlorato-κO)lanthanum(III)disilver(I)] Acta Crystallographica Section E |
| title | Poly[pentaaquatetrakis(μ2-nicotinato-κ2N:O)(perchlorato-κO)lanthanum(III)disilver(I)] |
| title_full | Poly[pentaaquatetrakis(μ2-nicotinato-κ2N:O)(perchlorato-κO)lanthanum(III)disilver(I)] |
| title_fullStr | Poly[pentaaquatetrakis(μ2-nicotinato-κ2N:O)(perchlorato-κO)lanthanum(III)disilver(I)] |
| title_full_unstemmed | Poly[pentaaquatetrakis(μ2-nicotinato-κ2N:O)(perchlorato-κO)lanthanum(III)disilver(I)] |
| title_short | Poly[pentaaquatetrakis(μ2-nicotinato-κ2N:O)(perchlorato-κO)lanthanum(III)disilver(I)] |
| title_sort | poly pentaaquatetrakis amp 956 2 nicotinato amp 954 2n o perchlorato amp 954 o lanthanum iii disilver i |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809026130 |
| work_keys_str_mv | AT wendongsong polypentaaquatetrakisamp9562nicotinatoamp9542noperchloratoamp954olanthanumiiidisilveri AT chaohuazhang polypentaaquatetrakisamp9562nicotinatoamp9542noperchloratoamp954olanthanumiiidisilveri AT biaoguan polypentaaquatetrakisamp9562nicotinatoamp9542noperchloratoamp954olanthanumiiidisilveri |