Structural characterization of copper (II) tetradecanoate with 2,2′-bipyridine and 4,4′-bipyridine to study magnetic properties
This paper presents synthesis, structural characterization and spintronic applications of copper (II) tetradecanoate derived magnetic complexes. The complexes were prepared by a chemical reaction between [Cu2(CH3(CH2)12COO)4](EtOH)2 and 2,2′-bipyridine-4,4′-bipyridine ligands respectively. The compl...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2018-03-01
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| Series: | Journal of Saudi Chemical Society |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S1319610317300959 |
| _version_ | 1819260173036814336 |
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| author | Noha Said Bedowr Rosiyah Binti Yahya Nesrain Farhan |
| author_facet | Noha Said Bedowr Rosiyah Binti Yahya Nesrain Farhan |
| author_sort | Noha Said Bedowr |
| collection | DOAJ |
| description | This paper presents synthesis, structural characterization and spintronic applications of copper (II) tetradecanoate derived magnetic complexes. The complexes were prepared by a chemical reaction between [Cu2(CH3(CH2)12COO)4](EtOH)2 and 2,2′-bipyridine-4,4′-bipyridine ligands respectively. The complexes were further reacted between the product of the first reaction and 4,4′-bipyridine-2,2′-bipyridine respectively. The structural characterization techniques included elemental analysis, Fourier transformed infrared spectroscopy (FTIR), Ultra-violet–Visible (UV–Vis) spectroscopy, polarized optical microscopy, magnetic moment and thermogravimetric analysis. The structural and characterization results suggested that the synthesized complexes were binuclear and mononuclear covalent complexes of copper(II) with structural formulas [Cu2(η2-(OOCR)4](4,4′-bpy)2H2O] and [Cu(η1-(OOCR)2(2,2′-bpy) (4,4′-bpy)] respectively. |
| first_indexed | 2024-12-23T19:21:41Z |
| format | Article |
| id | doaj.art-5cbb34373eb34ffbaef52bd7e544122f |
| institution | Directory Open Access Journal |
| issn | 1319-6103 |
| language | English |
| last_indexed | 2024-12-23T19:21:41Z |
| publishDate | 2018-03-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Journal of Saudi Chemical Society |
| spelling | doaj.art-5cbb34373eb34ffbaef52bd7e544122f2022-12-21T17:34:08ZengElsevierJournal of Saudi Chemical Society1319-61032018-03-0122325526010.1016/j.jscs.2017.08.003Structural characterization of copper (II) tetradecanoate with 2,2′-bipyridine and 4,4′-bipyridine to study magnetic propertiesNoha Said Bedowr0Rosiyah Binti Yahya1Nesrain Farhan2In Organic Lap, Department of Chemistry, Faculty of Science, University of Malaya, 50603 Kuala Lumpur, MalaysiaIn Organic Lap, Department of Chemistry, Faculty of Science, University of Malaya, 50603 Kuala Lumpur, MalaysiaIn Organic Lap, Department of Chemistry, Faculty of Science, University of Malaya, 50603 Kuala Lumpur, MalaysiaThis paper presents synthesis, structural characterization and spintronic applications of copper (II) tetradecanoate derived magnetic complexes. The complexes were prepared by a chemical reaction between [Cu2(CH3(CH2)12COO)4](EtOH)2 and 2,2′-bipyridine-4,4′-bipyridine ligands respectively. The complexes were further reacted between the product of the first reaction and 4,4′-bipyridine-2,2′-bipyridine respectively. The structural characterization techniques included elemental analysis, Fourier transformed infrared spectroscopy (FTIR), Ultra-violet–Visible (UV–Vis) spectroscopy, polarized optical microscopy, magnetic moment and thermogravimetric analysis. The structural and characterization results suggested that the synthesized complexes were binuclear and mononuclear covalent complexes of copper(II) with structural formulas [Cu2(η2-(OOCR)4](4,4′-bpy)2H2O] and [Cu(η1-(OOCR)2(2,2′-bpy) (4,4′-bpy)] respectively.http://www.sciencedirect.com/science/article/pii/S1319610317300959Cu(II) tetradecanoate2,2-Bipyridine4,4-Bipyridine |
| spellingShingle | Noha Said Bedowr Rosiyah Binti Yahya Nesrain Farhan Structural characterization of copper (II) tetradecanoate with 2,2′-bipyridine and 4,4′-bipyridine to study magnetic properties Journal of Saudi Chemical Society Cu(II) tetradecanoate 2,2-Bipyridine 4,4-Bipyridine |
| title | Structural characterization of copper (II) tetradecanoate with 2,2′-bipyridine and 4,4′-bipyridine to study magnetic properties |
| title_full | Structural characterization of copper (II) tetradecanoate with 2,2′-bipyridine and 4,4′-bipyridine to study magnetic properties |
| title_fullStr | Structural characterization of copper (II) tetradecanoate with 2,2′-bipyridine and 4,4′-bipyridine to study magnetic properties |
| title_full_unstemmed | Structural characterization of copper (II) tetradecanoate with 2,2′-bipyridine and 4,4′-bipyridine to study magnetic properties |
| title_short | Structural characterization of copper (II) tetradecanoate with 2,2′-bipyridine and 4,4′-bipyridine to study magnetic properties |
| title_sort | structural characterization of copper ii tetradecanoate with 2 2 bipyridine and 4 4 bipyridine to study magnetic properties |
| topic | Cu(II) tetradecanoate 2,2-Bipyridine 4,4-Bipyridine |
| url | http://www.sciencedirect.com/science/article/pii/S1319610317300959 |
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