A New Perspective on the Applicability of Diffuse Reflectance Spectroscopy for Determining the Hematite Content of Fe-Rich Soils in the Tropical Margins of China
Hematite and goethite are widely occurring chromogenic iron oxides in soils and sediments that are sensitive to climatic dry/wet shifts. However, only by accurately quantifying the content or ratio of hematite and goethite can they be applied reliably to palaeoclimate reconstruction. Compared to the...
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2024-02-01
|
| Series: | Minerals |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2075-163X/14/3/242 |
| _version_ | 1797239926408871936 |
|---|---|
| author | Jiawei Li Bin Lü Tianyuan Chen Xin Liu Jinmeng Tang Hui Yan |
| author_facet | Jiawei Li Bin Lü Tianyuan Chen Xin Liu Jinmeng Tang Hui Yan |
| author_sort | Jiawei Li |
| collection | DOAJ |
| description | Hematite and goethite are widely occurring chromogenic iron oxides in soils and sediments that are sensitive to climatic dry/wet shifts. However, only by accurately quantifying the content or ratio of hematite and goethite can they be applied reliably to palaeoclimate reconstruction. Compared to the Loess Plateau of China, hematite in the soils of southern China has not been sufficiently studied. We used diffuse reflectance spectroscopy (abbreviation DRS, including the first-derivative curves and the second-derivative curves of the Kubelka–Munk remission functions), combined with ignition at 950 °C, and X-ray fluorescence (XRF) to quantify the hematite content of four tropical-margin iron-rich soil profiles with different matrix compositions in the Leizhou Peninsula, China. We also examined the application of hematite quantification parameters in soils with different matrix compositions under the same climatic conditions. Our main findings are as follows: (i) DRS first-derivative curves can reflect the presence of goethite and hematite in soils, and their relative contents can be compared within the same profile. (ii) The second-derivative curve of the Kubelka–Munk remission functions can reflect the relative proportions of goethite and hematite and provide information about the degree of Al substitution. (iii) Combined with calibration equations, soil redness can reliably quantify the hematite content, but it is necessary to consider the effect of mucilage envelopes in the process of hematite formation. Additionally, we summarize various methods used for quantifying hematite, and the influence of soil matrix compositions, with the aim of providing a reference for hematite quantification elsewhere. We also propose a new indicator (ΔHm<sub>Red</sub>/Hm<sub>Red</sub>) to help detect iron hydroxide/iron oxide changes in soils. |
| first_indexed | 2024-04-24T17:59:18Z |
| format | Article |
| id | doaj.art-5ce28687b0474c7cb7431f032f402de9 |
| institution | Directory Open Access Journal |
| issn | 2075-163X |
| language | English |
| last_indexed | 2024-04-24T17:59:18Z |
| publishDate | 2024-02-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Minerals |
| spelling | doaj.art-5ce28687b0474c7cb7431f032f402de92024-03-27T13:56:11ZengMDPI AGMinerals2075-163X2024-02-0114324210.3390/min14030242A New Perspective on the Applicability of Diffuse Reflectance Spectroscopy for Determining the Hematite Content of Fe-Rich Soils in the Tropical Margins of ChinaJiawei Li0Bin Lü1Tianyuan Chen2Xin Liu3Jinmeng Tang4Hui Yan5Key Laboratory for Humid Subtropical Eco-Geographical Processes of the Ministry of Education, Fujian Normal University, Fuzhou 350117, ChinaKey Laboratory for Humid Subtropical Eco-Geographical Processes of the Ministry of Education, Fujian Normal University, Fuzhou 350117, ChinaKey Laboratory for Humid Subtropical Eco-Geographical Processes of the Ministry of Education, Fujian Normal University, Fuzhou 350117, ChinaMinistry of Education Key Laboratory of Western China’s Environmental Systems, College of Earth and Environmental Sciences, Lanzhou University, Lanzhou 730000, ChinaMinistry of Education Key Laboratory of Western China’s Environmental Systems, College of Earth and Environmental Sciences, Lanzhou University, Lanzhou 730000, ChinaKey Laboratory for Humid Subtropical Eco-Geographical Processes of the Ministry of Education, Fujian Normal University, Fuzhou 350117, ChinaHematite and goethite are widely occurring chromogenic iron oxides in soils and sediments that are sensitive to climatic dry/wet shifts. However, only by accurately quantifying the content or ratio of hematite and goethite can they be applied reliably to palaeoclimate reconstruction. Compared to the Loess Plateau of China, hematite in the soils of southern China has not been sufficiently studied. We used diffuse reflectance spectroscopy (abbreviation DRS, including the first-derivative curves and the second-derivative curves of the Kubelka–Munk remission functions), combined with ignition at 950 °C, and X-ray fluorescence (XRF) to quantify the hematite content of four tropical-margin iron-rich soil profiles with different matrix compositions in the Leizhou Peninsula, China. We also examined the application of hematite quantification parameters in soils with different matrix compositions under the same climatic conditions. Our main findings are as follows: (i) DRS first-derivative curves can reflect the presence of goethite and hematite in soils, and their relative contents can be compared within the same profile. (ii) The second-derivative curve of the Kubelka–Munk remission functions can reflect the relative proportions of goethite and hematite and provide information about the degree of Al substitution. (iii) Combined with calibration equations, soil redness can reliably quantify the hematite content, but it is necessary to consider the effect of mucilage envelopes in the process of hematite formation. Additionally, we summarize various methods used for quantifying hematite, and the influence of soil matrix compositions, with the aim of providing a reference for hematite quantification elsewhere. We also propose a new indicator (ΔHm<sub>Red</sub>/Hm<sub>Red</sub>) to help detect iron hydroxide/iron oxide changes in soils.https://www.mdpi.com/2075-163X/14/3/242hematiteiron-rich soiltropical margindiffuse reflectance spectroscopy |
| spellingShingle | Jiawei Li Bin Lü Tianyuan Chen Xin Liu Jinmeng Tang Hui Yan A New Perspective on the Applicability of Diffuse Reflectance Spectroscopy for Determining the Hematite Content of Fe-Rich Soils in the Tropical Margins of China Minerals hematite iron-rich soil tropical margin diffuse reflectance spectroscopy |
| title | A New Perspective on the Applicability of Diffuse Reflectance Spectroscopy for Determining the Hematite Content of Fe-Rich Soils in the Tropical Margins of China |
| title_full | A New Perspective on the Applicability of Diffuse Reflectance Spectroscopy for Determining the Hematite Content of Fe-Rich Soils in the Tropical Margins of China |
| title_fullStr | A New Perspective on the Applicability of Diffuse Reflectance Spectroscopy for Determining the Hematite Content of Fe-Rich Soils in the Tropical Margins of China |
| title_full_unstemmed | A New Perspective on the Applicability of Diffuse Reflectance Spectroscopy for Determining the Hematite Content of Fe-Rich Soils in the Tropical Margins of China |
| title_short | A New Perspective on the Applicability of Diffuse Reflectance Spectroscopy for Determining the Hematite Content of Fe-Rich Soils in the Tropical Margins of China |
| title_sort | new perspective on the applicability of diffuse reflectance spectroscopy for determining the hematite content of fe rich soils in the tropical margins of china |
| topic | hematite iron-rich soil tropical margin diffuse reflectance spectroscopy |
| url | https://www.mdpi.com/2075-163X/14/3/242 |
| work_keys_str_mv | AT jiaweili anewperspectiveontheapplicabilityofdiffusereflectancespectroscopyfordeterminingthehematitecontentofferichsoilsinthetropicalmarginsofchina AT binlu anewperspectiveontheapplicabilityofdiffusereflectancespectroscopyfordeterminingthehematitecontentofferichsoilsinthetropicalmarginsofchina AT tianyuanchen anewperspectiveontheapplicabilityofdiffusereflectancespectroscopyfordeterminingthehematitecontentofferichsoilsinthetropicalmarginsofchina AT xinliu anewperspectiveontheapplicabilityofdiffusereflectancespectroscopyfordeterminingthehematitecontentofferichsoilsinthetropicalmarginsofchina AT jinmengtang anewperspectiveontheapplicabilityofdiffusereflectancespectroscopyfordeterminingthehematitecontentofferichsoilsinthetropicalmarginsofchina AT huiyan anewperspectiveontheapplicabilityofdiffusereflectancespectroscopyfordeterminingthehematitecontentofferichsoilsinthetropicalmarginsofchina AT jiaweili newperspectiveontheapplicabilityofdiffusereflectancespectroscopyfordeterminingthehematitecontentofferichsoilsinthetropicalmarginsofchina AT binlu newperspectiveontheapplicabilityofdiffusereflectancespectroscopyfordeterminingthehematitecontentofferichsoilsinthetropicalmarginsofchina AT tianyuanchen newperspectiveontheapplicabilityofdiffusereflectancespectroscopyfordeterminingthehematitecontentofferichsoilsinthetropicalmarginsofchina AT xinliu newperspectiveontheapplicabilityofdiffusereflectancespectroscopyfordeterminingthehematitecontentofferichsoilsinthetropicalmarginsofchina AT jinmengtang newperspectiveontheapplicabilityofdiffusereflectancespectroscopyfordeterminingthehematitecontentofferichsoilsinthetropicalmarginsofchina AT huiyan newperspectiveontheapplicabilityofdiffusereflectancespectroscopyfordeterminingthehematitecontentofferichsoilsinthetropicalmarginsofchina |