Laser-Induced Ion Formation and Electron Emission from a Nanostructured Gold Surface at Laser Fluence below the Threshold for Plasma Formation
The laser formation of positive and negative ions on a nanostructured metal surface is observed at laser fluence below the plasma formation threshold. The laser radiation energy dependences of the yield of positive and negative Au ions and charged clusters as well as electrons from the laser-induced...
| Main Authors: | , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2023-02-01
|
| Series: | Nanomaterials |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2079-4991/13/3/600 |
| _version_ | 1827759691941281792 |
|---|---|
| author | Andrey Pento Ilya Kuzmin Viacheslav Kozlovskiy Lei Li Polina Laptinskaya Yaroslav Simanovsky Boris Sartakov Sergey Nikiforov |
| author_facet | Andrey Pento Ilya Kuzmin Viacheslav Kozlovskiy Lei Li Polina Laptinskaya Yaroslav Simanovsky Boris Sartakov Sergey Nikiforov |
| author_sort | Andrey Pento |
| collection | DOAJ |
| description | The laser formation of positive and negative ions on a nanostructured metal surface is observed at laser fluence below the plasma formation threshold. The laser radiation energy dependences of the yield of positive and negative Au ions and charged clusters as well as electrons from the laser-induced nanostructures on the surface of gold are obtained at laser fluence below the plasma formation threshold using a pulsed laser with a wavelength of 355 nm and a pulse duration of 0.37 ns. It is shown that the ratio of the signals of positive and negative ions is constant over the entire range of the laser radiation energies, while the ion signal dependence on the laser radiation energy is described by a power function with an exponent of 9. The role of gold nanoparticles with a size of less than 5 nm in the formation of Au ions and charged Au clusters is discussed. |
| first_indexed | 2024-03-11T09:31:19Z |
| format | Article |
| id | doaj.art-5cf672daf2ee45ea9ffa13316999242e |
| institution | Directory Open Access Journal |
| issn | 2079-4991 |
| language | English |
| last_indexed | 2024-03-11T09:31:19Z |
| publishDate | 2023-02-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Nanomaterials |
| spelling | doaj.art-5cf672daf2ee45ea9ffa13316999242e2023-11-16T17:37:08ZengMDPI AGNanomaterials2079-49912023-02-0113360010.3390/nano13030600Laser-Induced Ion Formation and Electron Emission from a Nanostructured Gold Surface at Laser Fluence below the Threshold for Plasma FormationAndrey Pento0Ilya Kuzmin1Viacheslav Kozlovskiy2Lei Li3Polina Laptinskaya4Yaroslav Simanovsky5Boris Sartakov6Sergey Nikiforov7Prokhorov General Physics Institute of the Russian Academy of Sciences, 119991 Moscow, RussiaVernadsky Institute of Geochemistry and Analytical Chemistry of the Russian Academy of Sciences, 119991 Moscow, RussiaChernogolovka Branch of the N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Chernogolovka, 142432 Moscow Region, RussiaInstitute of Mass Spectrometry and Atmospheric Environment, Jinan University, Guangzhou 510632, ChinaProkhorov General Physics Institute of the Russian Academy of Sciences, 119991 Moscow, RussiaProkhorov General Physics Institute of the Russian Academy of Sciences, 119991 Moscow, RussiaProkhorov General Physics Institute of the Russian Academy of Sciences, 119991 Moscow, RussiaProkhorov General Physics Institute of the Russian Academy of Sciences, 119991 Moscow, RussiaThe laser formation of positive and negative ions on a nanostructured metal surface is observed at laser fluence below the plasma formation threshold. The laser radiation energy dependences of the yield of positive and negative Au ions and charged clusters as well as electrons from the laser-induced nanostructures on the surface of gold are obtained at laser fluence below the plasma formation threshold using a pulsed laser with a wavelength of 355 nm and a pulse duration of 0.37 ns. It is shown that the ratio of the signals of positive and negative ions is constant over the entire range of the laser radiation energies, while the ion signal dependence on the laser radiation energy is described by a power function with an exponent of 9. The role of gold nanoparticles with a size of less than 5 nm in the formation of Au ions and charged Au clusters is discussed.https://www.mdpi.com/2079-4991/13/3/600gold nanoparticleslaser mass spectrometrylaser-induced nanostructures |
| spellingShingle | Andrey Pento Ilya Kuzmin Viacheslav Kozlovskiy Lei Li Polina Laptinskaya Yaroslav Simanovsky Boris Sartakov Sergey Nikiforov Laser-Induced Ion Formation and Electron Emission from a Nanostructured Gold Surface at Laser Fluence below the Threshold for Plasma Formation Nanomaterials gold nanoparticles laser mass spectrometry laser-induced nanostructures |
| title | Laser-Induced Ion Formation and Electron Emission from a Nanostructured Gold Surface at Laser Fluence below the Threshold for Plasma Formation |
| title_full | Laser-Induced Ion Formation and Electron Emission from a Nanostructured Gold Surface at Laser Fluence below the Threshold for Plasma Formation |
| title_fullStr | Laser-Induced Ion Formation and Electron Emission from a Nanostructured Gold Surface at Laser Fluence below the Threshold for Plasma Formation |
| title_full_unstemmed | Laser-Induced Ion Formation and Electron Emission from a Nanostructured Gold Surface at Laser Fluence below the Threshold for Plasma Formation |
| title_short | Laser-Induced Ion Formation and Electron Emission from a Nanostructured Gold Surface at Laser Fluence below the Threshold for Plasma Formation |
| title_sort | laser induced ion formation and electron emission from a nanostructured gold surface at laser fluence below the threshold for plasma formation |
| topic | gold nanoparticles laser mass spectrometry laser-induced nanostructures |
| url | https://www.mdpi.com/2079-4991/13/3/600 |
| work_keys_str_mv | AT andreypento laserinducedionformationandelectronemissionfromananostructuredgoldsurfaceatlaserfluencebelowthethresholdforplasmaformation AT ilyakuzmin laserinducedionformationandelectronemissionfromananostructuredgoldsurfaceatlaserfluencebelowthethresholdforplasmaformation AT viacheslavkozlovskiy laserinducedionformationandelectronemissionfromananostructuredgoldsurfaceatlaserfluencebelowthethresholdforplasmaformation AT leili laserinducedionformationandelectronemissionfromananostructuredgoldsurfaceatlaserfluencebelowthethresholdforplasmaformation AT polinalaptinskaya laserinducedionformationandelectronemissionfromananostructuredgoldsurfaceatlaserfluencebelowthethresholdforplasmaformation AT yaroslavsimanovsky laserinducedionformationandelectronemissionfromananostructuredgoldsurfaceatlaserfluencebelowthethresholdforplasmaformation AT borissartakov laserinducedionformationandelectronemissionfromananostructuredgoldsurfaceatlaserfluencebelowthethresholdforplasmaformation AT sergeynikiforov laserinducedionformationandelectronemissionfromananostructuredgoldsurfaceatlaserfluencebelowthethresholdforplasmaformation |