Moisture Content and Mechanical Properties of Bio-Waste Pellets for Fuel and/or Water Remediation Applications

The current research is focused on the mutual comparison (mechanical properties, response to humidity) of agro-waste composite materials. The purpose of this work is directed at the valorization of agro-waste biomass products and to investigate their mechanical stability for transport or other appli...

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Main Authors: Yuriy A. Anisimov, Bernd G. K. Steiger, Duncan E. Cree, Lee D. Wilson
Format: Article
Language:English
Published: MDPI AG 2023-03-01
Series:Journal of Composites Science
Subjects:
Online Access:https://www.mdpi.com/2504-477X/7/3/100
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author Yuriy A. Anisimov
Bernd G. K. Steiger
Duncan E. Cree
Lee D. Wilson
author_facet Yuriy A. Anisimov
Bernd G. K. Steiger
Duncan E. Cree
Lee D. Wilson
author_sort Yuriy A. Anisimov
collection DOAJ
description The current research is focused on the mutual comparison (mechanical properties, response to humidity) of agro-waste composite materials. The purpose of this work is directed at the valorization of agro-waste biomass products and to investigate their mechanical stability for transport or other applications (in dry and wet states). Three different types of agro-waste (oat hull (Oh), torrefied wheat straw (S), and spent coffee grounds (SCG)) were blended with kaolinite (K) and chitosan (CHT) at variable weight ratios to yield ternary composites. Mechanical properties were represented by measuring hardness (in compression mode) and elastic modulus (under tension mode). Young’s (elastic) modulus was measured both for dried and hydrated samples. The pelletized materials were prepared in two forms: crosslinked (CL) with epichlorohydrin and non-crosslinked (NCL). The hardness of the Oh pellets was poor (75 N) and decreased by four times with greater agro-waste content, while crosslinking affected the hardness only slightly. S pellets had the highest level of hardness at 40% agro-waste content (160 N), with a concomitant decrease to 120 N upon crosslinking. SCG pellets had the least change in hardness for both CL and NCL specimens (105–120 N). The trends of Young’s modulus were similar to hardness. Hydration caused the elastic modulus to decrease ca. 100-fold. In general, S and SCG composites exhibit the greatest hardness and Young’s modulus compared to Oh composites (CL or NCL) in their dry state.
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spelling doaj.art-5cf8da76e7344201b7eb0dad084c72de2023-11-17T11:53:13ZengMDPI AGJournal of Composites Science2504-477X2023-03-017310010.3390/jcs7030100Moisture Content and Mechanical Properties of Bio-Waste Pellets for Fuel and/or Water Remediation ApplicationsYuriy A. Anisimov0Bernd G. K. Steiger1Duncan E. Cree2Lee D. Wilson3Department of Chemistry, University of Saskatchewan, Saskatoon, SK S7N 5C9, CanadaDepartment of Chemistry, University of Saskatchewan, Saskatoon, SK S7N 5C9, CanadaDepartment of Mechanical Engineering, University of Saskatchewan, Saskatoon, SK S7N 5A9, CanadaDepartment of Chemistry, University of Saskatchewan, Saskatoon, SK S7N 5C9, CanadaThe current research is focused on the mutual comparison (mechanical properties, response to humidity) of agro-waste composite materials. The purpose of this work is directed at the valorization of agro-waste biomass products and to investigate their mechanical stability for transport or other applications (in dry and wet states). Three different types of agro-waste (oat hull (Oh), torrefied wheat straw (S), and spent coffee grounds (SCG)) were blended with kaolinite (K) and chitosan (CHT) at variable weight ratios to yield ternary composites. Mechanical properties were represented by measuring hardness (in compression mode) and elastic modulus (under tension mode). Young’s (elastic) modulus was measured both for dried and hydrated samples. The pelletized materials were prepared in two forms: crosslinked (CL) with epichlorohydrin and non-crosslinked (NCL). The hardness of the Oh pellets was poor (75 N) and decreased by four times with greater agro-waste content, while crosslinking affected the hardness only slightly. S pellets had the highest level of hardness at 40% agro-waste content (160 N), with a concomitant decrease to 120 N upon crosslinking. SCG pellets had the least change in hardness for both CL and NCL specimens (105–120 N). The trends of Young’s modulus were similar to hardness. Hydration caused the elastic modulus to decrease ca. 100-fold. In general, S and SCG composites exhibit the greatest hardness and Young’s modulus compared to Oh composites (CL or NCL) in their dry state.https://www.mdpi.com/2504-477X/7/3/100densityYoung’s moduluschitosankaolinitepelletsternary composites
spellingShingle Yuriy A. Anisimov
Bernd G. K. Steiger
Duncan E. Cree
Lee D. Wilson
Moisture Content and Mechanical Properties of Bio-Waste Pellets for Fuel and/or Water Remediation Applications
Journal of Composites Science
density
Young’s modulus
chitosan
kaolinite
pellets
ternary composites
title Moisture Content and Mechanical Properties of Bio-Waste Pellets for Fuel and/or Water Remediation Applications
title_full Moisture Content and Mechanical Properties of Bio-Waste Pellets for Fuel and/or Water Remediation Applications
title_fullStr Moisture Content and Mechanical Properties of Bio-Waste Pellets for Fuel and/or Water Remediation Applications
title_full_unstemmed Moisture Content and Mechanical Properties of Bio-Waste Pellets for Fuel and/or Water Remediation Applications
title_short Moisture Content and Mechanical Properties of Bio-Waste Pellets for Fuel and/or Water Remediation Applications
title_sort moisture content and mechanical properties of bio waste pellets for fuel and or water remediation applications
topic density
Young’s modulus
chitosan
kaolinite
pellets
ternary composites
url https://www.mdpi.com/2504-477X/7/3/100
work_keys_str_mv AT yuriyaanisimov moisturecontentandmechanicalpropertiesofbiowastepelletsforfuelandorwaterremediationapplications
AT berndgksteiger moisturecontentandmechanicalpropertiesofbiowastepelletsforfuelandorwaterremediationapplications
AT duncanecree moisturecontentandmechanicalpropertiesofbiowastepelletsforfuelandorwaterremediationapplications
AT leedwilson moisturecontentandmechanicalpropertiesofbiowastepelletsforfuelandorwaterremediationapplications