Enhanced breakdown strength of the BaTiO3/polypropylene nanocomposite film based on the biaxial stretching process

Abstract The significant progresses of polymer‐based nanocomposites with improved dielectric performances are urgently calling for an effect way to realise commercial production. Up to now, the biaxial stretching technology is still a powerful method to produce the high‐performance dielectric films...

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Main Authors: Ming‐Sheng Zheng, Wei‐Wei Lu, Xing Yang, Zhi‐Min Dang
Format: Article
Language:English
Published: Wiley 2023-09-01
Series:IET Nanodielectrics
Subjects:
Online Access:https://doi.org/10.1049/nde2.12046
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author Ming‐Sheng Zheng
Wei‐Wei Lu
Xing Yang
Zhi‐Min Dang
author_facet Ming‐Sheng Zheng
Wei‐Wei Lu
Xing Yang
Zhi‐Min Dang
author_sort Ming‐Sheng Zheng
collection DOAJ
description Abstract The significant progresses of polymer‐based nanocomposites with improved dielectric performances are urgently calling for an effect way to realise commercial production. Up to now, the biaxial stretching technology is still a powerful method to produce the high‐performance dielectric films applied in the film capacitors due to its full‐blown applications. In this work, a classical composite system of BaTiO3/polypropylene was applied to reveal the connection between the microstructure changes and dielectric properties of the corresponding nanocomposite films in the biaxial stretching process. The permittivity of BT‐30 wt% nanocomposite reached 2.8 at 103 Hz after stretching, and its breakdown strength reached 340 MV/m. In addition, the breakdown strength of BT‐10 wt% nanocomposite could even be promoted to 452 MV/m, which was 1.3 times higher than that before stretching. The microstructure test demonstrated that the rearrangement of nanofillers, high crystallinity and the oriented polypropylene crystals were advantageous to the improvement of breakdown strength for the stretched nanocomposite films. Therefore, the application of biaxial stretching technology into the preparation of nanocomposite dielectric film is an enormous potential way for the energy storage film capacitors.
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spelling doaj.art-5d03759baab9479c8d4e7fe427de10622023-09-22T04:17:13ZengWileyIET Nanodielectrics2514-32552023-09-016315916410.1049/nde2.12046Enhanced breakdown strength of the BaTiO3/polypropylene nanocomposite film based on the biaxial stretching processMing‐Sheng Zheng0Wei‐Wei Lu1Xing Yang2Zhi‐Min Dang3School of Chemistry and Biological Engineering University of Science & Technology Beijing Beijing ChinaSchool of Chemistry and Chemical Engineering Xi'an University of Science & Technology Xi'an ChinaSchool of Chemistry and Biological Engineering University of Science & Technology Beijing Beijing ChinaDepartment of Electrical Engineering State Key Laboratory of Power System Tsinghua University Beijing ChinaAbstract The significant progresses of polymer‐based nanocomposites with improved dielectric performances are urgently calling for an effect way to realise commercial production. Up to now, the biaxial stretching technology is still a powerful method to produce the high‐performance dielectric films applied in the film capacitors due to its full‐blown applications. In this work, a classical composite system of BaTiO3/polypropylene was applied to reveal the connection between the microstructure changes and dielectric properties of the corresponding nanocomposite films in the biaxial stretching process. The permittivity of BT‐30 wt% nanocomposite reached 2.8 at 103 Hz after stretching, and its breakdown strength reached 340 MV/m. In addition, the breakdown strength of BT‐10 wt% nanocomposite could even be promoted to 452 MV/m, which was 1.3 times higher than that before stretching. The microstructure test demonstrated that the rearrangement of nanofillers, high crystallinity and the oriented polypropylene crystals were advantageous to the improvement of breakdown strength for the stretched nanocomposite films. Therefore, the application of biaxial stretching technology into the preparation of nanocomposite dielectric film is an enormous potential way for the energy storage film capacitors.https://doi.org/10.1049/nde2.12046dielectric thin filmselectric breakdownnanocompositespermittivity
spellingShingle Ming‐Sheng Zheng
Wei‐Wei Lu
Xing Yang
Zhi‐Min Dang
Enhanced breakdown strength of the BaTiO3/polypropylene nanocomposite film based on the biaxial stretching process
IET Nanodielectrics
dielectric thin films
electric breakdown
nanocomposites
permittivity
title Enhanced breakdown strength of the BaTiO3/polypropylene nanocomposite film based on the biaxial stretching process
title_full Enhanced breakdown strength of the BaTiO3/polypropylene nanocomposite film based on the biaxial stretching process
title_fullStr Enhanced breakdown strength of the BaTiO3/polypropylene nanocomposite film based on the biaxial stretching process
title_full_unstemmed Enhanced breakdown strength of the BaTiO3/polypropylene nanocomposite film based on the biaxial stretching process
title_short Enhanced breakdown strength of the BaTiO3/polypropylene nanocomposite film based on the biaxial stretching process
title_sort enhanced breakdown strength of the batio3 polypropylene nanocomposite film based on the biaxial stretching process
topic dielectric thin films
electric breakdown
nanocomposites
permittivity
url https://doi.org/10.1049/nde2.12046
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AT weiweilu enhancedbreakdownstrengthofthebatio3polypropylenenanocompositefilmbasedonthebiaxialstretchingprocess
AT xingyang enhancedbreakdownstrengthofthebatio3polypropylenenanocompositefilmbasedonthebiaxialstretchingprocess
AT zhimindang enhancedbreakdownstrengthofthebatio3polypropylenenanocompositefilmbasedonthebiaxialstretchingprocess