2-(4-Bromophenyl)-5,7-dimethyl-3-methylsulfanyl-1-benzofuran
The title compound, C17H15BrOS, was prepared by the Lewis acid-catalysed reaction of 2,4-dimethylphenol with 4′-bromo-2-chloro-2-(methylsulfanyl)acetophenone. The 4-bromophenyl ring is rotated slightly out of the benzofuran plane, making a dihedral angle of 8.4 (1)°. The...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536807063052 |
| _version_ | 1798024404025737216 |
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| author | Hong Dae Choi Pil Ja Seo Byeng Wha Son Uk Lee |
| author_facet | Hong Dae Choi Pil Ja Seo Byeng Wha Son Uk Lee |
| author_sort | Hong Dae Choi |
| collection | DOAJ |
| description | The title compound, C17H15BrOS, was prepared by the Lewis acid-catalysed reaction of 2,4-dimethylphenol with 4′-bromo-2-chloro-2-(methylsulfanyl)acetophenone. The 4-bromophenyl ring is rotated slightly out of the benzofuran plane, making a dihedral angle of 8.4 (1)°. The crystal structure is stabilized by a CH2—H...π interaction between the 5-methyl group and the benzene ring of the benzofuran system. |
| first_indexed | 2024-04-11T18:01:52Z |
| format | Article |
| id | doaj.art-5d2d03f07f9a4c138aad2ad190af6625 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T18:01:52Z |
| publishDate | 2008-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-5d2d03f07f9a4c138aad2ad190af66252022-12-22T04:10:27ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-01-01641o148o14810.1107/S16005368070630522-(4-Bromophenyl)-5,7-dimethyl-3-methylsulfanyl-1-benzofuranHong Dae ChoiPil Ja SeoByeng Wha SonUk LeeThe title compound, C17H15BrOS, was prepared by the Lewis acid-catalysed reaction of 2,4-dimethylphenol with 4′-bromo-2-chloro-2-(methylsulfanyl)acetophenone. The 4-bromophenyl ring is rotated slightly out of the benzofuran plane, making a dihedral angle of 8.4 (1)°. The crystal structure is stabilized by a CH2—H...π interaction between the 5-methyl group and the benzene ring of the benzofuran system.http://scripts.iucr.org/cgi-bin/paper?S1600536807063052 |
| spellingShingle | Hong Dae Choi Pil Ja Seo Byeng Wha Son Uk Lee 2-(4-Bromophenyl)-5,7-dimethyl-3-methylsulfanyl-1-benzofuran Acta Crystallographica Section E |
| title | 2-(4-Bromophenyl)-5,7-dimethyl-3-methylsulfanyl-1-benzofuran |
| title_full | 2-(4-Bromophenyl)-5,7-dimethyl-3-methylsulfanyl-1-benzofuran |
| title_fullStr | 2-(4-Bromophenyl)-5,7-dimethyl-3-methylsulfanyl-1-benzofuran |
| title_full_unstemmed | 2-(4-Bromophenyl)-5,7-dimethyl-3-methylsulfanyl-1-benzofuran |
| title_short | 2-(4-Bromophenyl)-5,7-dimethyl-3-methylsulfanyl-1-benzofuran |
| title_sort | 2 4 bromophenyl 5 7 dimethyl 3 methylsulfanyl 1 benzofuran |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536807063052 |
| work_keys_str_mv | AT hongdaechoi 24bromophenyl57dimethyl3methylsulfanyl1benzofuran AT piljaseo 24bromophenyl57dimethyl3methylsulfanyl1benzofuran AT byengwhason 24bromophenyl57dimethyl3methylsulfanyl1benzofuran AT uklee 24bromophenyl57dimethyl3methylsulfanyl1benzofuran |