Base-Free Synthesis of Furfurylamines from Biomass Furans Using Ru Pincer Complexes

Base-Free Synthesis of Furfurylamines from Biomass Furans Using Ru Pincer Complexes

We report the first example of employing homogeneous organometal-catalyzed transfer hydrogenation for the selective reductive amination of furfurals to furfurylamines. An efficient, chemoselective, and base-free method is described using Ru-MACHO-BH as catalyst and <i>i</i>PrOH as H dono...

Full description

Bibliographic Details
Main Authors:	Danielle Lobo Justo Pinheiro, Martin Nielsen
Format:	Article
Language:	English
Published:	MDPI AG 2021-04-01
Series:	Catalysts
Subjects:	transfer hydrogenation furfurals furfurylamine reductive amination Ru-MACHO
Online Access:	https://www.mdpi.com/2073-4344/11/5/558

Similar Items

Tunable synthesis of furfurylamines or β-amino alcohols via Ru-catalyzed N–H functionalization using biomass-derived polyols
by: Le Jia, et al.
Published: (2022-08-01)

Synthesis and Characterization of Benzoxazine Resin Based on Furfurylamine
by: Jing Wang, et al.
Published: (2022-11-01)

Efficient synthesis of furfurylamine from biomass via a hybrid strategy in an EaCl:Gly–water medium
by: Wei He, et al.
Published: (2023-03-01)

Significant Enhancement of 5-Hydroxymethylfural Productivity from <i>D</i>-Fructose with SG(SiO<sub>2</sub>) in Betaine:Glycerol–Water for Efficient Synthesis of Biobased 5-(Hydroxymethyl)furfurylamine
by: Daozhu Xu, et al.
Published: (2022-09-01)

Towards Thermally Reversible Networks Based on Furan-Functionalization of Jatropha Oil
by: Frita Yuliati, et al.
Published: (2020-08-01)

Benign Synthesis of Indoles from Anilines and Epoxides: New Application for Ruthenium Pincer Catalysts
by: Angèle Monney, et al.
Published: (2014-04-01)

Hydrogenation of Furfural to Furfuryl Alcohol over Ru Particles Supported on Mildly Oxidized Biochar
by: Raoof Bardestani, et al.
Published: (2020-08-01)

Recent Advances in the Efficient Synthesis of Useful Amines from Biomass-Based Furan Compounds and Their Derivatives over Heterogeneous Catalysts
by: Jia Zhang, et al.
Published: (2023-03-01)

Mechanistic Studies of Oxygen-Atom Transfer (OAT) in the Homogeneous Conversion of N<sub>2</sub>O by Ru Pincer Complexes
by: Guangchao Liang, et al.
Published: (2022-05-01)

Origin of the Increase in the Selectivity of Ru Catalysts with the Addition of Amines in the Presence of ZnSO<sub>4</sub> for the Selective Hydrogenation of Benzene to Cyclohexene
by: Haijie Sun, et al.
Published: (2024-03-01)

Effect of amine group on the hydrogenation of aromatic rings over Ru/MgO-Al2O3 catalysts
by: Li Zuo, et al.
Published: (2022-10-01)

Cyclopentadienone Iron Tricarbonyl Complexes-Catalyzed Hydrogen Transfer in Water
by: Daouda Ndiaye, et al.
Published: (2020-01-01)

Reductive Catalytic Fractionation of Spruce Wood over Ru/C Bifunctional Catalyst in the Medium of Ethanol and Molecular Hydrogen
by: Oxana P. Taran, et al.
Published: (2022-11-01)

Ionic [Ru] complex with recyclability by electro-adsorption for efficient catalytic transfer hydrogenation of aryl ketones
by: Yue Chuan-Jun, et al.
Published: (2017-12-01)

Recent Progress with Pincer Transition Metal Catalysts for Sustainability
by: Luca Piccirilli, et al.
Published: (2020-07-01)

Rhodium "PONOP" pincer complexes for amine-borane dehydrogenation
by: Spearing-Ewyn, EAK
Published: (2020)

Trimeric Ruthenium Cluster-Derived Ru Nanoparticles Dispersed in MIL-101(Cr) for Catalytic Transfer Hydrogenation
by: Kyung-Ryul Oh, et al.
Published: (2022-09-01)

Biosynthesis of Furfurylamines in Batch and Continuous Flow by Immobilized Amine Transaminases
by: Tobias Heinks, et al.
Published: (2023-05-01)

CoCuMgAl-Mixed-Oxide-Based Catalysts with Fine-Tunable Composition for the Hydrogenation of Furan Compounds
by: Liudmila N. Stepanova, et al.
Published: (2024-02-01)

Search for double β-decays of 96Ru and 104Ru with high purity Ge γ-spectrometry
by: P. Belli, et al.
Published: (2010-12-01)

Ru–W Pair Sites Enabling the Ensemble Catalysis for Efficient Hydrogen Evolution
by: Weilong Ma, et al.
Published: (2023-09-01)

PDDA-Montmorillonite Composites Loaded with Ru Nanoparticles: Synthesis, Characterization, and Catalytic Properties in Hydrogenation of 2-Butanone
by: Ewa M. Serwicka, et al.
Published: (2018-08-01)

Hydrogenation of Furfural as Model Reaction of Bio-Oil Stabilization under Mild Conditions Using Multiwalled Carbon Nanotube (MWNT)-Supported Pt Catalysts
by: Wang, Chuan, et al.
Published: (2016)

Highly Efficient Kinetic Resolution of Aryl-Alkenyl Alcohols by Ru-Catalyzed Hydrogen Transfer
by: Yipeng You, et al.
Published: (2021-12-01)

Chitin-Derived Nanocatalysts for Reductive Amination Reactions
by: Daniele Polidoro, et al.
Published: (2023-01-01)

Ru/Attapulgite as an Efficient and Low-Cost Ammonia Decomposition Catalyst
by: Qingfeng Teng, et al.
Published: (2024-03-01)

High Performance and Sustainable Copper-Modified Hydroxyapatite Catalysts for Catalytic Transfer Hydrogenation of Furfural
by: Balla Putrakumar, et al.
Published: (2020-09-01)

General Construction of Amine via Reduction of N=<i>X</i> (<i>X</i> = C, O, H) Bonds Mediated by Supported Nickel Boride Nanoclusters
by: Da Ke, et al.
Published: (2022-08-01)

Chemobiocatalytic transformation of biomass-derived D-xylose into furfuryl alcohol in a sustainable reaction system
by: Linsong Yang, et al.
Published: (2023-11-01)

Synthesis and Characterization of Ru‐Loaded Anodized Aluminum Oxide for Hydrogenation Catalysis
by: Annelies Vandekerkhove, et al.
Published: (2019-04-01)

Hydrolytic Dehydrogenation of Ammonia Borane Attained by Ru-Based Catalysts: An Auspicious Option to Produce Hydrogen from a Solid Hydrogen Carrier Molecule
by: Miriam Navlani-García, et al.
Published: (2021-04-01)

Dendrimer-Stabilized Ru Nanoparticles Immobilized in Organo-Silica Materials for Hydrogenation of Phenols
by: Eduard Karakhanov, et al.
Published: (2017-03-01)

Value-Added Bio-Chemicals Commodities from Catalytic Conversion of Biomass Derived Furan-Compounds
by: Aitziber Iriondo, et al.
Published: (2020-08-01)

Conversion of Phenol and Lignin as Components of Renewable Raw Materials on Pt and Ru-Supported Catalysts
by: Aleksey E. Koklin, et al.
Published: (2022-02-01)

Ruthenium(II) half-sandwich complexes containing N-substituted 5-nitrobenzimidazole: Synthesis, structures and catalytic transfer hydrogenation of ketones
by: İsmail Özdemir, et al.
Published: (2019-03-01)

Ultrasonic in-situ reduction preparation of SBA-15 loaded ultrafine RuCo alloy catalysts for efficient hydrogen storage of various LOHCs
by: Taiyi Liu, et al.
Published: (2024-05-01)

Novel Routes in Transformation of Lignocellulosic Biomass to Furan Platform Chemicals: From Pretreatment to Enzyme Catalysis
by: Grigorios Dedes, et al.
Published: (2020-07-01)

Selectively nucleotide‐derived RuP on N,P‐codoped carbon with engineered mesopores for energy‐efficient hydrogen production assisted by hydrazine oxidation
by: Xiya Guan, et al.
Published: (2024-02-01)

Synthesis of Pd/Ru Bimetallic Nanoparticles by Escherichia coli and Potential as a Catalyst for Upgrading 5-Hydroxymethyl Furfural Into Liquid Fuel Precursors
by: Jaime Gomez-Bolivar, et al.
Published: (2019-06-01)

A novel and highly efficient Zr-containing catalyst supported by biomass-derived sodium carboxymethyl cellulose for hydrogenation of furfural
by: Jianxiu Hao, et al.
Published: (2022-07-01)