A Comparative Study on the Degradation of Alkali-Activated Slag/Fly Ash and Cement-Based Mortars in Phosphoric Acid

This study compares the degradation behavior of the alkali-activated slag/fly ash (AASF) and ordinary Portland cement (OPC) mortars exposed to phosphoric acid with different pH values. The experimental results show that AASF mortars exhibit better resistance than OPC mortars against surface damage,...

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Main Authors: Jie Ren, Lihai Zhang, Yingcan Zhu, Zhenming Li, Rackel San Nicolas
Format: Article
Language:English
Published: Frontiers Media S.A. 2022-03-01
Series:Frontiers in Materials
Subjects:
Online Access:https://www.frontiersin.org/articles/10.3389/fmats.2022.845349/full
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author Jie Ren
Jie Ren
Lihai Zhang
Yingcan Zhu
Zhenming Li
Rackel San Nicolas
author_facet Jie Ren
Jie Ren
Lihai Zhang
Yingcan Zhu
Zhenming Li
Rackel San Nicolas
author_sort Jie Ren
collection DOAJ
description This study compares the degradation behavior of the alkali-activated slag/fly ash (AASF) and ordinary Portland cement (OPC) mortars exposed to phosphoric acid with different pH values. The experimental results show that AASF mortars exhibit better resistance than OPC mortars against surface damage, although both systems get white deposits on the surface in phosphoric acid with a relatively high pH level. AASF mortars obtained lower mass loss than OPC mortars in phosphoric acid with pH at 2 and 3. The strength reduction in AASF mortars after immersion in phosphoric acid is more significant than that in OPC mortars. However, total degradation depth of AASF was smaller than that of OPC regardless of the pH of the acid solutions. Based on the experimental data, linear relationships were identified between the slope of degradation depth–mass loss curves and the Al/Si and Ca/Si ratios of the binders. This may indicate a new way to assess the degradation behavior of AASF and OPC based on their chemical compositions.
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spelling doaj.art-5d4487a3a89e433185fc048c661150cb2022-12-21T18:42:11ZengFrontiers Media S.A.Frontiers in Materials2296-80162022-03-01910.3389/fmats.2022.845349845349A Comparative Study on the Degradation of Alkali-Activated Slag/Fly Ash and Cement-Based Mortars in Phosphoric AcidJie Ren0Jie Ren1Lihai Zhang2Yingcan Zhu3Zhenming Li4Rackel San Nicolas5Department of Infrastructure Engineering, the University of Melbourne, Parkville, VIC, AustraliaDepartment of Civil, Environment, and Architectural Engineering, University of Colorado Boulder, Boulder, CO, United StatesDepartment of Infrastructure Engineering, the University of Melbourne, Parkville, VIC, AustraliaCentre for Sustainable Agricultural Systems, University of Southern Queensland, Toowoomba, QLD, AustraliaDepartment of Materials and Environment, Faculty of Civil Engineering and Geoscience, Delft University of Technology, Delft, NetherlandsDepartment of Infrastructure Engineering, the University of Melbourne, Parkville, VIC, AustraliaThis study compares the degradation behavior of the alkali-activated slag/fly ash (AASF) and ordinary Portland cement (OPC) mortars exposed to phosphoric acid with different pH values. The experimental results show that AASF mortars exhibit better resistance than OPC mortars against surface damage, although both systems get white deposits on the surface in phosphoric acid with a relatively high pH level. AASF mortars obtained lower mass loss than OPC mortars in phosphoric acid with pH at 2 and 3. The strength reduction in AASF mortars after immersion in phosphoric acid is more significant than that in OPC mortars. However, total degradation depth of AASF was smaller than that of OPC regardless of the pH of the acid solutions. Based on the experimental data, linear relationships were identified between the slope of degradation depth–mass loss curves and the Al/Si and Ca/Si ratios of the binders. This may indicate a new way to assess the degradation behavior of AASF and OPC based on their chemical compositions.https://www.frontiersin.org/articles/10.3389/fmats.2022.845349/fullalkali-activated materialsPortland cementphosphoric aciddegradationstrength
spellingShingle Jie Ren
Jie Ren
Lihai Zhang
Yingcan Zhu
Zhenming Li
Rackel San Nicolas
A Comparative Study on the Degradation of Alkali-Activated Slag/Fly Ash and Cement-Based Mortars in Phosphoric Acid
Frontiers in Materials
alkali-activated materials
Portland cement
phosphoric acid
degradation
strength
title A Comparative Study on the Degradation of Alkali-Activated Slag/Fly Ash and Cement-Based Mortars in Phosphoric Acid
title_full A Comparative Study on the Degradation of Alkali-Activated Slag/Fly Ash and Cement-Based Mortars in Phosphoric Acid
title_fullStr A Comparative Study on the Degradation of Alkali-Activated Slag/Fly Ash and Cement-Based Mortars in Phosphoric Acid
title_full_unstemmed A Comparative Study on the Degradation of Alkali-Activated Slag/Fly Ash and Cement-Based Mortars in Phosphoric Acid
title_short A Comparative Study on the Degradation of Alkali-Activated Slag/Fly Ash and Cement-Based Mortars in Phosphoric Acid
title_sort comparative study on the degradation of alkali activated slag fly ash and cement based mortars in phosphoric acid
topic alkali-activated materials
Portland cement
phosphoric acid
degradation
strength
url https://www.frontiersin.org/articles/10.3389/fmats.2022.845349/full
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