A comparative study for treatment of white liquor by different applications of Fenton process

In this paper, the treatability of white liquor by conventional (CFP), modified (MFP) and electro-Fenton oxidation processes (EFP) was investigated depending on the COD parameter. Based on the experimental results, up to 62.4%, 58.4% and 54.9% COD removals by the CFP, MFP and EFP were achieved, resp...

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Main Authors: Mehmet Faik Sevimli, Elif Deliktaş, Serkan Şahinkaya, Dünyamin Güçlü
Format: Article
Language:English
Published: Elsevier 2014-12-01
Series:Arabian Journal of Chemistry
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1878535212003061
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author Mehmet Faik Sevimli
Elif Deliktaş
Serkan Şahinkaya
Dünyamin Güçlü
author_facet Mehmet Faik Sevimli
Elif Deliktaş
Serkan Şahinkaya
Dünyamin Güçlü
author_sort Mehmet Faik Sevimli
collection DOAJ
description In this paper, the treatability of white liquor by conventional (CFP), modified (MFP) and electro-Fenton oxidation processes (EFP) was investigated depending on the COD parameter. Based on the experimental results, up to 62.4%, 58.4% and 54.9% COD removals by the CFP, MFP and EFP were achieved, respectively. It was observed that adjustment of initial pH to acidic values is not required in the CFP. The optimal operational conditions were found to be [Fe2+] = 500 mg/L, [H2O2] = 1000 mg/L at pH 7.3 (original pH) in the CFP, [Fe0] = 1250 mg/L, [H2O2] = 1000 mg/L at pH 3 in the MFP, and I = 1.0 A, [H2O2] = 1500 mg/L at pH 3 in the EFP, respectively. As a result, the CFP has been determined as a more efficient alternative treatment method.
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spelling doaj.art-5d46a7b2335246658704bb72859c820b2022-12-22T01:08:57ZengElsevierArabian Journal of Chemistry1878-53522014-12-01761116112310.1016/j.arabjc.2012.12.015A comparative study for treatment of white liquor by different applications of Fenton processMehmet Faik Sevimli0Elif Deliktaş1Serkan Şahinkaya2Dünyamin Güçlü3Department of Environmental Engineering, Selçuk University Campus, 42075 Konya, TurkeyDepartment of Environmental Engineering, Selçuk University Campus, 42075 Konya, TurkeyDepartment of Environmental Engineering, Nevşehir University Campus, 50300 Nevşehir, TurkeyDepartment of Environmental Engineering, Selçuk University Campus, 42075 Konya, TurkeyIn this paper, the treatability of white liquor by conventional (CFP), modified (MFP) and electro-Fenton oxidation processes (EFP) was investigated depending on the COD parameter. Based on the experimental results, up to 62.4%, 58.4% and 54.9% COD removals by the CFP, MFP and EFP were achieved, respectively. It was observed that adjustment of initial pH to acidic values is not required in the CFP. The optimal operational conditions were found to be [Fe2+] = 500 mg/L, [H2O2] = 1000 mg/L at pH 7.3 (original pH) in the CFP, [Fe0] = 1250 mg/L, [H2O2] = 1000 mg/L at pH 3 in the MFP, and I = 1.0 A, [H2O2] = 1500 mg/L at pH 3 in the EFP, respectively. As a result, the CFP has been determined as a more efficient alternative treatment method.http://www.sciencedirect.com/science/article/pii/S1878535212003061CODElectro-FentonFenton processPaper industryWhite liquorZero valent iron
spellingShingle Mehmet Faik Sevimli
Elif Deliktaş
Serkan Şahinkaya
Dünyamin Güçlü
A comparative study for treatment of white liquor by different applications of Fenton process
Arabian Journal of Chemistry
COD
Electro-Fenton
Fenton process
Paper industry
White liquor
Zero valent iron
title A comparative study for treatment of white liquor by different applications of Fenton process
title_full A comparative study for treatment of white liquor by different applications of Fenton process
title_fullStr A comparative study for treatment of white liquor by different applications of Fenton process
title_full_unstemmed A comparative study for treatment of white liquor by different applications of Fenton process
title_short A comparative study for treatment of white liquor by different applications of Fenton process
title_sort comparative study for treatment of white liquor by different applications of fenton process
topic COD
Electro-Fenton
Fenton process
Paper industry
White liquor
Zero valent iron
url http://www.sciencedirect.com/science/article/pii/S1878535212003061
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