Preparation and Characterization of Cu (II), Mn(II) and Zn(II)complexes with new sulfamethoxazole Compounds
Acetophenone sulfamethoxazole and 3-Nitrobenzophenone sulfamethoxazole were prepared from the reaction of sulfamethoxazole with two ketones. The prepared ligands were identified by (C.H.N) analysis and UV-VIS, FT-IR spectroscopic techniques. Metal complexes of the two ligands were prepared in an a...
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| Format: | Article |
| Language: | Arabic |
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College of Science for Women, University of Baghdad
2017-09-01
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| Series: | Baghdad Science Journal |
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| Online Access: | http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/2396 |
| _version_ | 1828274439775584256 |
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| author | Baghdad Science Journal |
| author_facet | Baghdad Science Journal |
| author_sort | Baghdad Science Journal |
| collection | DOAJ |
| description | Acetophenone sulfamethoxazole and 3-Nitrobenzophenone sulfamethoxazole were prepared from the reaction of sulfamethoxazole with two ketones. The prepared ligands were identified by (C.H.N) analysis and UV-VIS, FT-IR spectroscopic techniques. Metal complexes of the two ligands were prepared in an aqueous alcohol with Zn (II), Mn (II) and Cu (II) ions with a molar ratio1:1. The proposed general formula for the resulting complexes was [ML.CL2.H2O]H2O .The complexes were characterized by (C.H.N) technique , spectroscopic methods ,conductivity, atomic absorption ,magnetic susceptibility measurements and melting point. According to the results obtained, the suggested geometry is to be octahedral for all the complexes. |
| first_indexed | 2024-04-13T06:35:29Z |
| format | Article |
| id | doaj.art-5d64a52b34ad425dae97ee15ac83042a |
| institution | Directory Open Access Journal |
| issn | 2078-8665 2411-7986 |
| language | Arabic |
| last_indexed | 2024-04-13T06:35:29Z |
| publishDate | 2017-09-01 |
| publisher | College of Science for Women, University of Baghdad |
| record_format | Article |
| series | Baghdad Science Journal |
| spelling | doaj.art-5d64a52b34ad425dae97ee15ac83042a2022-12-22T02:57:56ZaraCollege of Science for Women, University of BaghdadBaghdad Science Journal2078-86652411-79862017-09-0114310.21123/bsj.14.3.575-581Preparation and Characterization of Cu (II), Mn(II) and Zn(II)complexes with new sulfamethoxazole CompoundsBaghdad Science JournalAcetophenone sulfamethoxazole and 3-Nitrobenzophenone sulfamethoxazole were prepared from the reaction of sulfamethoxazole with two ketones. The prepared ligands were identified by (C.H.N) analysis and UV-VIS, FT-IR spectroscopic techniques. Metal complexes of the two ligands were prepared in an aqueous alcohol with Zn (II), Mn (II) and Cu (II) ions with a molar ratio1:1. The proposed general formula for the resulting complexes was [ML.CL2.H2O]H2O .The complexes were characterized by (C.H.N) technique , spectroscopic methods ,conductivity, atomic absorption ,magnetic susceptibility measurements and melting point. According to the results obtained, the suggested geometry is to be octahedral for all the complexes.http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/2396Sulfamethoxazole, Schiff base complexes, Metal complexes, Antibacterial. |
| spellingShingle | Baghdad Science Journal Preparation and Characterization of Cu (II), Mn(II) and Zn(II)complexes with new sulfamethoxazole Compounds Baghdad Science Journal Sulfamethoxazole, Schiff base complexes, Metal complexes, Antibacterial. |
| title | Preparation and Characterization of Cu (II), Mn(II) and Zn(II)complexes with new sulfamethoxazole Compounds |
| title_full | Preparation and Characterization of Cu (II), Mn(II) and Zn(II)complexes with new sulfamethoxazole Compounds |
| title_fullStr | Preparation and Characterization of Cu (II), Mn(II) and Zn(II)complexes with new sulfamethoxazole Compounds |
| title_full_unstemmed | Preparation and Characterization of Cu (II), Mn(II) and Zn(II)complexes with new sulfamethoxazole Compounds |
| title_short | Preparation and Characterization of Cu (II), Mn(II) and Zn(II)complexes with new sulfamethoxazole Compounds |
| title_sort | preparation and characterization of cu ii mn ii and zn ii complexes with new sulfamethoxazole compounds |
| topic | Sulfamethoxazole, Schiff base complexes, Metal complexes, Antibacterial. |
| url | http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/2396 |
| work_keys_str_mv | AT baghdadsciencejournal preparationandcharacterizationofcuiimniiandzniicomplexeswithnewsulfamethoxazolecompounds |