Structural Motifs in Aryl Organogermanium Ge-O Derivatives for Material Design
The aim of this work was to understand the main structural features and ways of formation of Ge-O bonds in organogermanium compounds under the conditions of Ar<sub>n</sub>GeHal<sub>4-n</sub> (Hal = halide) hydrolysis. The structural types of these compounds were considered, p...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2023-09-01
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| Series: | International Journal of Molecular Sciences |
| Subjects: | |
| Online Access: | https://www.mdpi.com/1422-0067/24/17/13575 |
| Summary: | The aim of this work was to understand the main structural features and ways of formation of Ge-O bonds in organogermanium compounds under the conditions of Ar<sub>n</sub>GeHal<sub>4-n</sub> (Hal = halide) hydrolysis. The structural types of these compounds were considered, providing 11 blocks (<b>A</b>–<b>K</b>). The molecular structures of the novel compounds [(<i>p</i>-FC<sub>6</sub>H<sub>4</sub>)<sub>3</sub>Ge]<sub>2</sub>O (<b>1</b>), [(<i>p</i>-F<sub>3</sub>CC<sub>6</sub>H<sub>4</sub>)<sub>3</sub>Ge]<sub>2</sub>O (<b>2</b>), and <i>cyclo</i>-[(<i>p</i>-F<sub>3</sub>CC<sub>6</sub>H<sub>4</sub>)<sub>2</sub>GeO]<sub>4</sub> (<b>3</b>) were studied through XRD (X-ray diffraction) analysis. The molecular structure of [(<i>p</i>-F<sub>3</sub>CC<sub>6</sub>H<sub>4</sub>)<sub>3</sub>GeO]<sub>4</sub>Ge (<b>4</b>), representing a novel structural type, was also investigated. The data presented in this study will be important in the design of materials with useful properties based on group 14 element derivatives with element–oxygen bonding. |
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| ISSN: | 1661-6596 1422-0067 |