2,2′-Dimethyl-1,1′-[2,2-bis(bromomethyl)propane-1,3-diyl]dibenzimidazole hemihydrate
The title compound, C21H22Br2N4·0.5H2O, contains two benzimidazole groups which may provide two potential coordination nodes for the construction of metal–organic frameworks. The mean planes of the two imidazole groups are almost perpendicular, with a dihedral angle of 83....
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-03-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812007751 |
| _version_ | 1828137712016687104 |
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| author | Yong-Sheng Yan Ling Liu Shen-Tang Wang Xing Wang Chun-Bo Liu |
| author_facet | Yong-Sheng Yan Ling Liu Shen-Tang Wang Xing Wang Chun-Bo Liu |
| author_sort | Yong-Sheng Yan |
| collection | DOAJ |
| description | The title compound, C21H22Br2N4·0.5H2O, contains two benzimidazole groups which may provide two potential coordination nodes for the construction of metal–organic frameworks. The mean planes of the two imidazole groups are almost perpendicular, with a dihedral angle of 83.05 (2)°, and adjacent molecules are linked into a one-dimensional chain by π–π stacking interactions between imidazole groups of different molecules [centroid-to-centroid distances of 3.834 (2) and 3.522 (2) Å]. |
| first_indexed | 2024-04-11T18:23:07Z |
| format | Article |
| id | doaj.art-5dc86f24b66f4510a2f2bc735e1b889c |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T18:23:07Z |
| publishDate | 2012-03-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-5dc86f24b66f4510a2f2bc735e1b889c2022-12-22T04:09:42ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-03-01683o856o85610.1107/S16005368120077512,2′-Dimethyl-1,1′-[2,2-bis(bromomethyl)propane-1,3-diyl]dibenzimidazole hemihydrateYong-Sheng YanLing LiuShen-Tang WangXing WangChun-Bo LiuThe title compound, C21H22Br2N4·0.5H2O, contains two benzimidazole groups which may provide two potential coordination nodes for the construction of metal–organic frameworks. The mean planes of the two imidazole groups are almost perpendicular, with a dihedral angle of 83.05 (2)°, and adjacent molecules are linked into a one-dimensional chain by π–π stacking interactions between imidazole groups of different molecules [centroid-to-centroid distances of 3.834 (2) and 3.522 (2) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536812007751 |
| spellingShingle | Yong-Sheng Yan Ling Liu Shen-Tang Wang Xing Wang Chun-Bo Liu 2,2′-Dimethyl-1,1′-[2,2-bis(bromomethyl)propane-1,3-diyl]dibenzimidazole hemihydrate Acta Crystallographica Section E |
| title | 2,2′-Dimethyl-1,1′-[2,2-bis(bromomethyl)propane-1,3-diyl]dibenzimidazole hemihydrate |
| title_full | 2,2′-Dimethyl-1,1′-[2,2-bis(bromomethyl)propane-1,3-diyl]dibenzimidazole hemihydrate |
| title_fullStr | 2,2′-Dimethyl-1,1′-[2,2-bis(bromomethyl)propane-1,3-diyl]dibenzimidazole hemihydrate |
| title_full_unstemmed | 2,2′-Dimethyl-1,1′-[2,2-bis(bromomethyl)propane-1,3-diyl]dibenzimidazole hemihydrate |
| title_short | 2,2′-Dimethyl-1,1′-[2,2-bis(bromomethyl)propane-1,3-diyl]dibenzimidazole hemihydrate |
| title_sort | 2 2 amp 8242 dimethyl 1 1 amp 8242 2 2 bis bromomethyl propane 1 3 diyl dibenzimidazole hemihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812007751 |
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