Effect of gamma (γ-) radiation on the opto-structural and morphological properties of green synthesized BaO nanoparticles using Moringa Oleifera leaves
In this current assessment, BaO synthesized from Moringa Oleifera leaves were irradiated using 0–75 kGy gamma radiation and investigated its physical impacts. The x-ray diffraction (XRD) data demonstrated the synthesis of tetragonal BaO, and no phase deviation was observed after irradiation. As dose...
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Elsevier
2024-02-01
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author | Md Rabiul Islam Sapan Kumar Sen Arup Kumar M.S. Islam Md. Serajum Manir Zannath Ara M.D. Hossain M.K. Alam |
author_facet | Md Rabiul Islam Sapan Kumar Sen Arup Kumar M.S. Islam Md. Serajum Manir Zannath Ara M.D. Hossain M.K. Alam |
author_sort | Md Rabiul Islam |
collection | DOAJ |
description | In this current assessment, BaO synthesized from Moringa Oleifera leaves were irradiated using 0–75 kGy gamma radiation and investigated its physical impacts. The x-ray diffraction (XRD) data demonstrated the synthesis of tetragonal BaO, and no phase deviation was observed after irradiation. As doses are increased, the overall crystallite size were decreased due to an increase in defects and disorders. The tetragonal BaO was evident in Fourier transform infrared (FTIR) spectra prior to and following irradiation, while peak intensities and wavenumbers varied considerably. The as-prepared BaO showed a spherical shape morphology, and Field emission scanning electron microscopy (FESEM) indicated no vital deviations in it after irradiation. As irradiation shifts from 0 to 75 kGy, optical bandgap was increased from 4.55 to 4.93 eV, evaluated using Kubelka-Munk (K-M) equation from UV–vis–NIR spectrophotometer. Opto-electronic and photonic devices have challenges in extreme radiation conditions, such as space and nuclear environments. So, these assessments suggested that BaO can withstand high levels of gamma photon and could be a good option for photonic and optoelectronic instruments in an extreme gamma-ray exposed conditions. |
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spelling | doaj.art-5def1d7f0f4147369c67d721e4bb916d2024-03-09T09:28:02ZengElsevierHeliyon2405-84402024-02-01104e26350Effect of gamma (γ-) radiation on the opto-structural and morphological properties of green synthesized BaO nanoparticles using Moringa Oleifera leavesMd Rabiul Islam0Sapan Kumar Sen1Arup Kumar2M.S. Islam3Md. Serajum Manir4Zannath Ara5M.D. Hossain6M.K. Alam7Institute of Radiation and Polymer Technology, Atomic Energy Research Establishment, Bangladesh Atomic Energy Commission, Dhaka, 1349, Bangladesh; Corresponding author.Institute of Electronics, Atomic Energy Research Establishment, Bangladesh Atomic Energy Commission, Dhaka, 1349, BangladeshMaterials Science Division, Atomic Energy Center, Dhaka, Bangladesh Atomic Energy Commission, Dhaka, 1000, BangladeshDepartment of Nanomaterials and Ceramic Engineering, Bangladesh University of Engineering and Technology, Dhaka, 1000, BangladeshInstitute of Radiation and Polymer Technology, Atomic Energy Research Establishment, Bangladesh Atomic Energy Commission, Dhaka, 1349, BangladeshDepartment of Chemistry, University of Dhaka, Dhaka, 1000, Bangladesh; Ministry of Labour and Employment, Government of the People's Republic of Bangladesh, Dhaka, 1000, BangladeshDepartment of Physics, Sher-E-Bangla Nagar Adarsha Mohila College, Dhaka, 1207, BangladeshDepartment of Physics, Bangladesh University of Engineering and Technology, Dhaka, 1000, BangladeshIn this current assessment, BaO synthesized from Moringa Oleifera leaves were irradiated using 0–75 kGy gamma radiation and investigated its physical impacts. The x-ray diffraction (XRD) data demonstrated the synthesis of tetragonal BaO, and no phase deviation was observed after irradiation. As doses are increased, the overall crystallite size were decreased due to an increase in defects and disorders. The tetragonal BaO was evident in Fourier transform infrared (FTIR) spectra prior to and following irradiation, while peak intensities and wavenumbers varied considerably. The as-prepared BaO showed a spherical shape morphology, and Field emission scanning electron microscopy (FESEM) indicated no vital deviations in it after irradiation. As irradiation shifts from 0 to 75 kGy, optical bandgap was increased from 4.55 to 4.93 eV, evaluated using Kubelka-Munk (K-M) equation from UV–vis–NIR spectrophotometer. Opto-electronic and photonic devices have challenges in extreme radiation conditions, such as space and nuclear environments. So, these assessments suggested that BaO can withstand high levels of gamma photon and could be a good option for photonic and optoelectronic instruments in an extreme gamma-ray exposed conditions.http://www.sciencedirect.com/science/article/pii/S2405844024023818BaOGreen synthesisGamma irradiationMoringa OleiferWilliamson-Hall method |
spellingShingle | Md Rabiul Islam Sapan Kumar Sen Arup Kumar M.S. Islam Md. Serajum Manir Zannath Ara M.D. Hossain M.K. Alam Effect of gamma (γ-) radiation on the opto-structural and morphological properties of green synthesized BaO nanoparticles using Moringa Oleifera leaves Heliyon BaO Green synthesis Gamma irradiation Moringa Oleifer Williamson-Hall method |
title | Effect of gamma (γ-) radiation on the opto-structural and morphological properties of green synthesized BaO nanoparticles using Moringa Oleifera leaves |
title_full | Effect of gamma (γ-) radiation on the opto-structural and morphological properties of green synthesized BaO nanoparticles using Moringa Oleifera leaves |
title_fullStr | Effect of gamma (γ-) radiation on the opto-structural and morphological properties of green synthesized BaO nanoparticles using Moringa Oleifera leaves |
title_full_unstemmed | Effect of gamma (γ-) radiation on the opto-structural and morphological properties of green synthesized BaO nanoparticles using Moringa Oleifera leaves |
title_short | Effect of gamma (γ-) radiation on the opto-structural and morphological properties of green synthesized BaO nanoparticles using Moringa Oleifera leaves |
title_sort | effect of gamma γ radiation on the opto structural and morphological properties of green synthesized bao nanoparticles using moringa oleifera leaves |
topic | BaO Green synthesis Gamma irradiation Moringa Oleifer Williamson-Hall method |
url | http://www.sciencedirect.com/science/article/pii/S2405844024023818 |
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