A thermodynamically consistent Markovian master equation beyond the secular approximation

Markovian master equations provide a versatile tool for describing open quantum systems when memory effects of the environment may be neglected. As these equations are of an approximate nature, they often do not respect the laws of thermodynamics when no secular approximation is performed in their d...

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Main Authors: Patrick P Potts, Alex Arash Sand Kalaee, Andreas Wacker
Format: Article
Language:English
Published: IOP Publishing 2021-01-01
Series:New Journal of Physics
Subjects:
Online Access:https://doi.org/10.1088/1367-2630/ac3b2f
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author Patrick P Potts
Alex Arash Sand Kalaee
Andreas Wacker
author_facet Patrick P Potts
Alex Arash Sand Kalaee
Andreas Wacker
author_sort Patrick P Potts
collection DOAJ
description Markovian master equations provide a versatile tool for describing open quantum systems when memory effects of the environment may be neglected. As these equations are of an approximate nature, they often do not respect the laws of thermodynamics when no secular approximation is performed in their derivation. Here we introduce a Markovian master equation that is thermodynamically consistent and provides an accurate description whenever memory effects can be neglected. The thermodynamic consistency is obtained through a rescaled Hamiltonian for the thermodynamic bookkeeping, exploiting the fact that a Markovian description implies a limited resolution for heat. Our results enable a thermodynamically consistent description of a variety of systems where the secular approximation breaks down.
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spelling doaj.art-5e004816d31c4da1bc75014dfb546e782023-08-08T15:41:24ZengIOP PublishingNew Journal of Physics1367-26302021-01-01231212301310.1088/1367-2630/ac3b2fA thermodynamically consistent Markovian master equation beyond the secular approximationPatrick P Potts0https://orcid.org/0000-0001-6036-7291Alex Arash Sand Kalaee1https://orcid.org/0000-0003-2691-724XAndreas Wacker2https://orcid.org/0000-0003-1758-6274Physics Department and NanoLund, Lund University , Box 118, 22100 Lund, Sweden; Department of Physics, University of Basel , Klingelbergstrasse 82, 4056 Basel, SwitzerlandPhysics Department and NanoLund, Lund University , Box 118, 22100 Lund, SwedenPhysics Department and NanoLund, Lund University , Box 118, 22100 Lund, SwedenMarkovian master equations provide a versatile tool for describing open quantum systems when memory effects of the environment may be neglected. As these equations are of an approximate nature, they often do not respect the laws of thermodynamics when no secular approximation is performed in their derivation. Here we introduce a Markovian master equation that is thermodynamically consistent and provides an accurate description whenever memory effects can be neglected. The thermodynamic consistency is obtained through a rescaled Hamiltonian for the thermodynamic bookkeeping, exploiting the fact that a Markovian description implies a limited resolution for heat. Our results enable a thermodynamically consistent description of a variety of systems where the secular approximation breaks down.https://doi.org/10.1088/1367-2630/ac3b2fMarkovian master equationquantum thermodynamicsheat engine
spellingShingle Patrick P Potts
Alex Arash Sand Kalaee
Andreas Wacker
A thermodynamically consistent Markovian master equation beyond the secular approximation
New Journal of Physics
Markovian master equation
quantum thermodynamics
heat engine
title A thermodynamically consistent Markovian master equation beyond the secular approximation
title_full A thermodynamically consistent Markovian master equation beyond the secular approximation
title_fullStr A thermodynamically consistent Markovian master equation beyond the secular approximation
title_full_unstemmed A thermodynamically consistent Markovian master equation beyond the secular approximation
title_short A thermodynamically consistent Markovian master equation beyond the secular approximation
title_sort thermodynamically consistent markovian master equation beyond the secular approximation
topic Markovian master equation
quantum thermodynamics
heat engine
url https://doi.org/10.1088/1367-2630/ac3b2f
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