Solid State Process for Preparation of Nickel Oxide Nanoparticles: Characterization and Optical Study
In the present work, we report preparation of NiO nanoparticles with well-defined plate morphology by solid-state reaction of NiCl2∙6H2O and the Schiff base ligand N,N′-bis-(3-methoxysalicylidene)benzene-1,4-diamine), as a novel precursor via solid state thermal decomposition method. This method is...
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| Format: | Article |
| Language: | English |
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Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR
2016-09-01
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| Series: | Iranian Journal of Chemistry & Chemical Engineering |
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| Online Access: | http://www.ijcce.ac.ir/article_22054_0cc64699d1355e99b3470834ef002cee.pdf |
| _version_ | 1828462803657162752 |
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| author | Aliakbar Dehno Khalaji |
| author_facet | Aliakbar Dehno Khalaji |
| author_sort | Aliakbar Dehno Khalaji |
| collection | DOAJ |
| description | In the present work, we report preparation of NiO nanoparticles with well-defined plate morphology by solid-state reaction of NiCl2∙6H2O and the Schiff base ligand N,N′-bis-(3-methoxysalicylidene)benzene-1,4-diamine), as a novel precursor via solid state thermal decomposition method. This method is a simple and environmentally friendly for preparing transition metal oxides. The result of TGA analysis of the precursor showed that the proper calcinations temperature is 450 oC. The NiO product was characterized by XRD, FT-IR and UV-Vis spectroscopy, SEM and TEM. The results indicated that the obtained product is face-centered cubic of nickel oxide, plate shape with average particle size of 10-20 nm. The optical absorption band gap of the nickel oxide nanoparticles was estimated to be 2.1 eV. |
| first_indexed | 2024-12-11T02:42:30Z |
| format | Article |
| id | doaj.art-5e0df35fd5814297a66ec997f18b2cc4 |
| institution | Directory Open Access Journal |
| issn | 1021-9986 1021-9986 |
| language | English |
| last_indexed | 2024-12-11T02:42:30Z |
| publishDate | 2016-09-01 |
| publisher | Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR |
| record_format | Article |
| series | Iranian Journal of Chemistry & Chemical Engineering |
| spelling | doaj.art-5e0df35fd5814297a66ec997f18b2cc42022-12-22T01:23:31ZengIranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECRIranian Journal of Chemistry & Chemical Engineering1021-99861021-99862016-09-01353172022054Solid State Process for Preparation of Nickel Oxide Nanoparticles: Characterization and Optical StudyAliakbar Dehno Khalaji0Department of Chemistry, Faculty of Science, Golestan University, P.O. Box 155 Gorgan, I.R. IRANIn the present work, we report preparation of NiO nanoparticles with well-defined plate morphology by solid-state reaction of NiCl2∙6H2O and the Schiff base ligand N,N′-bis-(3-methoxysalicylidene)benzene-1,4-diamine), as a novel precursor via solid state thermal decomposition method. This method is a simple and environmentally friendly for preparing transition metal oxides. The result of TGA analysis of the precursor showed that the proper calcinations temperature is 450 oC. The NiO product was characterized by XRD, FT-IR and UV-Vis spectroscopy, SEM and TEM. The results indicated that the obtained product is face-centered cubic of nickel oxide, plate shape with average particle size of 10-20 nm. The optical absorption band gap of the nickel oxide nanoparticles was estimated to be 2.1 eV.http://www.ijcce.ac.ir/article_22054_0cc64699d1355e99b3470834ef002cee.pdfnickel oxidenanoparticlessolid-stateschiff basethermal decomposition |
| spellingShingle | Aliakbar Dehno Khalaji Solid State Process for Preparation of Nickel Oxide Nanoparticles: Characterization and Optical Study Iranian Journal of Chemistry & Chemical Engineering nickel oxide nanoparticles solid-state schiff base thermal decomposition |
| title | Solid State Process for Preparation of Nickel Oxide Nanoparticles: Characterization and Optical Study |
| title_full | Solid State Process for Preparation of Nickel Oxide Nanoparticles: Characterization and Optical Study |
| title_fullStr | Solid State Process for Preparation of Nickel Oxide Nanoparticles: Characterization and Optical Study |
| title_full_unstemmed | Solid State Process for Preparation of Nickel Oxide Nanoparticles: Characterization and Optical Study |
| title_short | Solid State Process for Preparation of Nickel Oxide Nanoparticles: Characterization and Optical Study |
| title_sort | solid state process for preparation of nickel oxide nanoparticles characterization and optical study |
| topic | nickel oxide nanoparticles solid-state schiff base thermal decomposition |
| url | http://www.ijcce.ac.ir/article_22054_0cc64699d1355e99b3470834ef002cee.pdf |
| work_keys_str_mv | AT aliakbardehnokhalaji solidstateprocessforpreparationofnickeloxidenanoparticlescharacterizationandopticalstudy |