Analysis of agglomeration behaviors of aluminized composite propellants

To improve the performance of aluminized propellants, it is important to study the mechanism of agglomeration and approve the methods of inhibiting agglomeration. In this study, organic fluoride was added to the propellants and the dynamic combustion process of the propellants was obtained through v...

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Main Author: Mengying Liu
Format: Article
Language:English
Published: Elsevier 2023-04-01
Series:Case Studies in Thermal Engineering
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2214157X23001582
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author Mengying Liu
author_facet Mengying Liu
author_sort Mengying Liu
collection DOAJ
description To improve the performance of aluminized propellants, it is important to study the mechanism of agglomeration and approve the methods of inhibiting agglomeration. In this study, organic fluoride was added to the propellants and the dynamic combustion process of the propellants was obtained through visual combustion test system. At the same time, an algorithm which can detect the size of particles out of focus more accurately is also proposed. Then, the agglomeration behaviors, as well as the size distribution of initial condensed products and final condensed products, during the combustion of propellants are discussed. The influence of organic fluoride additive on the evolution of condensed products and the distribution of their sizes were also analyzed. The results show that the condensed products had a coral structure, and underwent the stages of exposure, accumulation, splicing, separation, and combustion to evolve into oxidation cap structures. When organic fluoride is added, special flocculent products were formed instead of coral-like products and the AlF3 was found in the condensed products. Besides, detailed behaviors of condensed products have been found in the gas. The products with an oxidation cap still subsequently interacted with one another in the gas, including through re-fusion and re-separation. The distribution of the initial products was relatively concentrated and stable while that of the final products exhibited a prominent trend of increasing first, then decreasing, and gradually stabilizing. Besides, with the addition of organic fluoride, the main combustion products were converted α - Al2O3 and θ - Al2O3 to γ - Al2O3 and δ - Al2O3, indicating that the addition of organic fluoride significantly improved the performance of the aluminized propellants in terms of suppressing the size of the condensed products.
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spelling doaj.art-5e18444c23f54d039ff400487b9349ce2023-03-21T04:16:32ZengElsevierCase Studies in Thermal Engineering2214-157X2023-04-0144102852Analysis of agglomeration behaviors of aluminized composite propellantsMengying Liu0Nanjing University of Aeronautics and Astronautics, Nanjing, 210016, ChinaTo improve the performance of aluminized propellants, it is important to study the mechanism of agglomeration and approve the methods of inhibiting agglomeration. In this study, organic fluoride was added to the propellants and the dynamic combustion process of the propellants was obtained through visual combustion test system. At the same time, an algorithm which can detect the size of particles out of focus more accurately is also proposed. Then, the agglomeration behaviors, as well as the size distribution of initial condensed products and final condensed products, during the combustion of propellants are discussed. The influence of organic fluoride additive on the evolution of condensed products and the distribution of their sizes were also analyzed. The results show that the condensed products had a coral structure, and underwent the stages of exposure, accumulation, splicing, separation, and combustion to evolve into oxidation cap structures. When organic fluoride is added, special flocculent products were formed instead of coral-like products and the AlF3 was found in the condensed products. Besides, detailed behaviors of condensed products have been found in the gas. The products with an oxidation cap still subsequently interacted with one another in the gas, including through re-fusion and re-separation. The distribution of the initial products was relatively concentrated and stable while that of the final products exhibited a prominent trend of increasing first, then decreasing, and gradually stabilizing. Besides, with the addition of organic fluoride, the main combustion products were converted α - Al2O3 and θ - Al2O3 to γ - Al2O3 and δ - Al2O3, indicating that the addition of organic fluoride significantly improved the performance of the aluminized propellants in terms of suppressing the size of the condensed products.http://www.sciencedirect.com/science/article/pii/S2214157X23001582Aluminized propellantCombustionAgglomerationOrganic fluoride additiveSize distribution
spellingShingle Mengying Liu
Analysis of agglomeration behaviors of aluminized composite propellants
Case Studies in Thermal Engineering
Aluminized propellant
Combustion
Agglomeration
Organic fluoride additive
Size distribution
title Analysis of agglomeration behaviors of aluminized composite propellants
title_full Analysis of agglomeration behaviors of aluminized composite propellants
title_fullStr Analysis of agglomeration behaviors of aluminized composite propellants
title_full_unstemmed Analysis of agglomeration behaviors of aluminized composite propellants
title_short Analysis of agglomeration behaviors of aluminized composite propellants
title_sort analysis of agglomeration behaviors of aluminized composite propellants
topic Aluminized propellant
Combustion
Agglomeration
Organic fluoride additive
Size distribution
url http://www.sciencedirect.com/science/article/pii/S2214157X23001582
work_keys_str_mv AT mengyingliu analysisofagglomerationbehaviorsofaluminizedcompositepropellants