Phosphate Ion Removal from Synthetic and Real Wastewater Using MnFe2O4 Nanoparticles: A Reusable Adsorbent

The purpose of this study was to eliminate phosphate (P) from wastewater using MnFe2O4 nanoparticles. BET, TGA/DTG, FTIR, SEM, TEM, VSM, XRD and EDX/Map analyses were used to determine the MnFe2O4 surface properties. The specific surface area of the adsorbent was 196.56 m2/g and VSM analysis showed...

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Main Authors: Widodo Brontowiyono, Indrajit Patra, Shaymaa Abed Hussein, - Alimuddin, Ahmed B. Mahdi, Samar Emad Izzat, Dhuha Mohsin Al-Dhalemi, Ahmed Kareem Obaid Aldulaim, Rosario Mireya Romero Parra, Luis Andres Barboza Arenas, Yasser Fakri Mustafa
Format: Article
Language:English
Published: Slovenian Chemical Society 2022-09-01
Series:Acta Chimica Slovenica
Subjects:
Online Access:https://journals.matheo.si/index.php/ACSi/article/view/7594
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author Widodo Brontowiyono
Indrajit Patra
Shaymaa Abed Hussein
- Alimuddin
Ahmed B. Mahdi
Samar Emad Izzat
Dhuha Mohsin Al-Dhalemi
Ahmed Kareem Obaid Aldulaim
Rosario Mireya Romero Parra
Luis Andres Barboza Arenas
Yasser Fakri Mustafa
author_facet Widodo Brontowiyono
Indrajit Patra
Shaymaa Abed Hussein
- Alimuddin
Ahmed B. Mahdi
Samar Emad Izzat
Dhuha Mohsin Al-Dhalemi
Ahmed Kareem Obaid Aldulaim
Rosario Mireya Romero Parra
Luis Andres Barboza Arenas
Yasser Fakri Mustafa
author_sort Widodo Brontowiyono
collection DOAJ
description The purpose of this study was to eliminate phosphate (P) from wastewater using MnFe2O4 nanoparticles. BET, TGA/DTG, FTIR, SEM, TEM, VSM, XRD and EDX/Map analyses were used to determine the MnFe2O4 surface properties. The specific surface area of the adsorbent was 196.56 m2/g and VSM analysis showed that the adsorbent has a ferromagnetic property. The maximum P sorption efficiency using MnFe2O4 (98.52%) was achieved at pH 6, temperature of 55 °C, P concentration of 10 mg/L, time of 60 min, and sorbent dosage of 2.5 g/L, which is a significant value. Also, the thermodynamic study indicated that the P sorption process is spontaneous and endothermic. Moreover, the utmost sorption capacity of P using MnFe2O4 was 39.48 mg/g. Besides, MnFe2O4 can be used for up to 6 reuse cycles with high sorption efficiency (>91%). Also, MnFe2O4 was able to remove phosphate, COD, and BOD5 from municipal wastewater with considerable removal efficiencies of 82.7%, 75.8%, and 77.3%, respectively.
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spelling doaj.art-5e1f78fa995b4a369d64bc631c703c572023-01-03T11:29:15ZengSlovenian Chemical SocietyActa Chimica Slovenica1318-02071580-31552022-09-0169368169310.17344/acsi.2022.75941100Phosphate Ion Removal from Synthetic and Real Wastewater Using MnFe2O4 Nanoparticles: A Reusable AdsorbentWidodo Brontowiyono0Indrajit Patra1Shaymaa Abed Hussein2- Alimuddin3Ahmed B. Mahdi4Samar Emad Izzat5Dhuha Mohsin Al-Dhalemi6Ahmed Kareem Obaid Aldulaim7Rosario Mireya Romero Parra8Luis Andres Barboza Arenas9Yasser Fakri Mustafa10Department of Environmental Engineering and Centre for Environmental Studies, Islamic University of Indonesia, Yogyakarta - 55589, IndonesiaNIT Durgapur, West Bengal, IndiaAl-Manara College For Medical Sciences, Maysan, IraqPhysical Sciences Section, School of Sciences, Maulana Azad National Urdu University, Hyderabad - 500032, Telangana, IndiaAnesthesia Techniques Department, Al-Mustaqbal University College, Babylon, IraqPharmacy department, Al-Nisour University College, Baghdad, IraqAltoosi University College, Najaf , IraqDepartment of Pharmacy, Al-Zahrawi University College, Karbala, IraqUniversidad Continental, Lima, PerúUniversidad Tecnológica del Perú, PerúDepartment of Pharmaceutical Chemistry, College of Pharmacy, University of Mosul, Mosul-41001, Iraq.The purpose of this study was to eliminate phosphate (P) from wastewater using MnFe2O4 nanoparticles. BET, TGA/DTG, FTIR, SEM, TEM, VSM, XRD and EDX/Map analyses were used to determine the MnFe2O4 surface properties. The specific surface area of the adsorbent was 196.56 m2/g and VSM analysis showed that the adsorbent has a ferromagnetic property. The maximum P sorption efficiency using MnFe2O4 (98.52%) was achieved at pH 6, temperature of 55 °C, P concentration of 10 mg/L, time of 60 min, and sorbent dosage of 2.5 g/L, which is a significant value. Also, the thermodynamic study indicated that the P sorption process is spontaneous and endothermic. Moreover, the utmost sorption capacity of P using MnFe2O4 was 39.48 mg/g. Besides, MnFe2O4 can be used for up to 6 reuse cycles with high sorption efficiency (>91%). Also, MnFe2O4 was able to remove phosphate, COD, and BOD5 from municipal wastewater with considerable removal efficiencies of 82.7%, 75.8%, and 77.3%, respectively.https://journals.matheo.si/index.php/ACSi/article/view/7594sorptionmnfe2o4 nanoparticlesphosphatewastewater
spellingShingle Widodo Brontowiyono
Indrajit Patra
Shaymaa Abed Hussein
- Alimuddin
Ahmed B. Mahdi
Samar Emad Izzat
Dhuha Mohsin Al-Dhalemi
Ahmed Kareem Obaid Aldulaim
Rosario Mireya Romero Parra
Luis Andres Barboza Arenas
Yasser Fakri Mustafa
Phosphate Ion Removal from Synthetic and Real Wastewater Using MnFe2O4 Nanoparticles: A Reusable Adsorbent
Acta Chimica Slovenica
sorption
mnfe2o4 nanoparticles
phosphate
wastewater
title Phosphate Ion Removal from Synthetic and Real Wastewater Using MnFe2O4 Nanoparticles: A Reusable Adsorbent
title_full Phosphate Ion Removal from Synthetic and Real Wastewater Using MnFe2O4 Nanoparticles: A Reusable Adsorbent
title_fullStr Phosphate Ion Removal from Synthetic and Real Wastewater Using MnFe2O4 Nanoparticles: A Reusable Adsorbent
title_full_unstemmed Phosphate Ion Removal from Synthetic and Real Wastewater Using MnFe2O4 Nanoparticles: A Reusable Adsorbent
title_short Phosphate Ion Removal from Synthetic and Real Wastewater Using MnFe2O4 Nanoparticles: A Reusable Adsorbent
title_sort phosphate ion removal from synthetic and real wastewater using mnfe2o4 nanoparticles a reusable adsorbent
topic sorption
mnfe2o4 nanoparticles
phosphate
wastewater
url https://journals.matheo.si/index.php/ACSi/article/view/7594
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