Phosphate Ion Removal from Synthetic and Real Wastewater Using MnFe2O4 Nanoparticles: A Reusable Adsorbent
The purpose of this study was to eliminate phosphate (P) from wastewater using MnFe2O4 nanoparticles. BET, TGA/DTG, FTIR, SEM, TEM, VSM, XRD and EDX/Map analyses were used to determine the MnFe2O4 surface properties. The specific surface area of the adsorbent was 196.56 m2/g and VSM analysis showed...
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Format: | Article |
Language: | English |
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Slovenian Chemical Society
2022-09-01
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Series: | Acta Chimica Slovenica |
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Online Access: | https://journals.matheo.si/index.php/ACSi/article/view/7594 |
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author | Widodo Brontowiyono Indrajit Patra Shaymaa Abed Hussein - Alimuddin Ahmed B. Mahdi Samar Emad Izzat Dhuha Mohsin Al-Dhalemi Ahmed Kareem Obaid Aldulaim Rosario Mireya Romero Parra Luis Andres Barboza Arenas Yasser Fakri Mustafa |
author_facet | Widodo Brontowiyono Indrajit Patra Shaymaa Abed Hussein - Alimuddin Ahmed B. Mahdi Samar Emad Izzat Dhuha Mohsin Al-Dhalemi Ahmed Kareem Obaid Aldulaim Rosario Mireya Romero Parra Luis Andres Barboza Arenas Yasser Fakri Mustafa |
author_sort | Widodo Brontowiyono |
collection | DOAJ |
description | The purpose of this study was to eliminate phosphate (P) from wastewater using MnFe2O4 nanoparticles. BET, TGA/DTG, FTIR, SEM, TEM, VSM, XRD and EDX/Map analyses were used to determine the MnFe2O4 surface properties. The specific surface area of the adsorbent was 196.56 m2/g and VSM analysis showed that the adsorbent has a ferromagnetic property. The maximum P sorption efficiency using MnFe2O4 (98.52%) was achieved at pH 6, temperature of 55 °C, P concentration of 10 mg/L, time of 60 min, and sorbent dosage of 2.5 g/L, which is a significant value. Also, the thermodynamic study indicated that the P sorption process is spontaneous and endothermic. Moreover, the utmost sorption capacity of P using MnFe2O4 was 39.48 mg/g. Besides, MnFe2O4 can be used for up to 6 reuse cycles with high sorption efficiency (>91%). Also, MnFe2O4 was able to remove phosphate, COD, and BOD5 from municipal wastewater with considerable removal efficiencies of 82.7%, 75.8%, and 77.3%, respectively. |
first_indexed | 2024-04-11T01:20:32Z |
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id | doaj.art-5e1f78fa995b4a369d64bc631c703c57 |
institution | Directory Open Access Journal |
issn | 1318-0207 1580-3155 |
language | English |
last_indexed | 2024-04-11T01:20:32Z |
publishDate | 2022-09-01 |
publisher | Slovenian Chemical Society |
record_format | Article |
series | Acta Chimica Slovenica |
spelling | doaj.art-5e1f78fa995b4a369d64bc631c703c572023-01-03T11:29:15ZengSlovenian Chemical SocietyActa Chimica Slovenica1318-02071580-31552022-09-0169368169310.17344/acsi.2022.75941100Phosphate Ion Removal from Synthetic and Real Wastewater Using MnFe2O4 Nanoparticles: A Reusable AdsorbentWidodo Brontowiyono0Indrajit Patra1Shaymaa Abed Hussein2- Alimuddin3Ahmed B. Mahdi4Samar Emad Izzat5Dhuha Mohsin Al-Dhalemi6Ahmed Kareem Obaid Aldulaim7Rosario Mireya Romero Parra8Luis Andres Barboza Arenas9Yasser Fakri Mustafa10Department of Environmental Engineering and Centre for Environmental Studies, Islamic University of Indonesia, Yogyakarta - 55589, IndonesiaNIT Durgapur, West Bengal, IndiaAl-Manara College For Medical Sciences, Maysan, IraqPhysical Sciences Section, School of Sciences, Maulana Azad National Urdu University, Hyderabad - 500032, Telangana, IndiaAnesthesia Techniques Department, Al-Mustaqbal University College, Babylon, IraqPharmacy department, Al-Nisour University College, Baghdad, IraqAltoosi University College, Najaf , IraqDepartment of Pharmacy, Al-Zahrawi University College, Karbala, IraqUniversidad Continental, Lima, PerúUniversidad Tecnológica del Perú, PerúDepartment of Pharmaceutical Chemistry, College of Pharmacy, University of Mosul, Mosul-41001, Iraq.The purpose of this study was to eliminate phosphate (P) from wastewater using MnFe2O4 nanoparticles. BET, TGA/DTG, FTIR, SEM, TEM, VSM, XRD and EDX/Map analyses were used to determine the MnFe2O4 surface properties. The specific surface area of the adsorbent was 196.56 m2/g and VSM analysis showed that the adsorbent has a ferromagnetic property. The maximum P sorption efficiency using MnFe2O4 (98.52%) was achieved at pH 6, temperature of 55 °C, P concentration of 10 mg/L, time of 60 min, and sorbent dosage of 2.5 g/L, which is a significant value. Also, the thermodynamic study indicated that the P sorption process is spontaneous and endothermic. Moreover, the utmost sorption capacity of P using MnFe2O4 was 39.48 mg/g. Besides, MnFe2O4 can be used for up to 6 reuse cycles with high sorption efficiency (>91%). Also, MnFe2O4 was able to remove phosphate, COD, and BOD5 from municipal wastewater with considerable removal efficiencies of 82.7%, 75.8%, and 77.3%, respectively.https://journals.matheo.si/index.php/ACSi/article/view/7594sorptionmnfe2o4 nanoparticlesphosphatewastewater |
spellingShingle | Widodo Brontowiyono Indrajit Patra Shaymaa Abed Hussein - Alimuddin Ahmed B. Mahdi Samar Emad Izzat Dhuha Mohsin Al-Dhalemi Ahmed Kareem Obaid Aldulaim Rosario Mireya Romero Parra Luis Andres Barboza Arenas Yasser Fakri Mustafa Phosphate Ion Removal from Synthetic and Real Wastewater Using MnFe2O4 Nanoparticles: A Reusable Adsorbent Acta Chimica Slovenica sorption mnfe2o4 nanoparticles phosphate wastewater |
title | Phosphate Ion Removal from Synthetic and Real Wastewater Using MnFe2O4 Nanoparticles: A Reusable Adsorbent |
title_full | Phosphate Ion Removal from Synthetic and Real Wastewater Using MnFe2O4 Nanoparticles: A Reusable Adsorbent |
title_fullStr | Phosphate Ion Removal from Synthetic and Real Wastewater Using MnFe2O4 Nanoparticles: A Reusable Adsorbent |
title_full_unstemmed | Phosphate Ion Removal from Synthetic and Real Wastewater Using MnFe2O4 Nanoparticles: A Reusable Adsorbent |
title_short | Phosphate Ion Removal from Synthetic and Real Wastewater Using MnFe2O4 Nanoparticles: A Reusable Adsorbent |
title_sort | phosphate ion removal from synthetic and real wastewater using mnfe2o4 nanoparticles a reusable adsorbent |
topic | sorption mnfe2o4 nanoparticles phosphate wastewater |
url | https://journals.matheo.si/index.php/ACSi/article/view/7594 |
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