Synergistic Ti-Fe Oxides on Fishbone-Derived Carbon Sulfonate: Enhanced Styrene Oxidation Catalysis
Fishbone-derived carbon sulfonate, modified through incipient wetness impregnation with titanium tetraisopropoxide and iron nitrate salts, displays catalytic activity in the oxidation of styrene with hydrogen peroxide (H2O2) as an oxidant. This was done to develop a cost-effective, non-toxic, and en...
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| Format: | Article |
| Language: | English |
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Department of Chemistry, Universitas Gadjah Mada
2023-12-01
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| Series: | Indonesian Journal of Chemistry |
| Subjects: | |
| Online Access: | https://jurnal.ugm.ac.id/ijc/article/view/80667 |
| _version_ | 1797336362768138240 |
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| author | Mukhamad Nurhadi Ratna Kusumawardani Teguh Wirawan Sin Yuan Lai Hadi Nur |
| author_facet | Mukhamad Nurhadi Ratna Kusumawardani Teguh Wirawan Sin Yuan Lai Hadi Nur |
| author_sort | Mukhamad Nurhadi |
| collection | DOAJ |
| description | Fishbone-derived carbon sulfonate, modified through incipient wetness impregnation with titanium tetraisopropoxide and iron nitrate salts, displays catalytic activity in the oxidation of styrene with hydrogen peroxide (H2O2) as an oxidant. This was done to develop a cost-effective, non-toxic, and environmentally friendly bimetallic oxide catalyst, incorporating titanium and iron oxides on mesoporous-derived carbon fishbone to enhance styrene conversion and benzaldehyde selectivity in styrene oxidation using aqueous H2O2. The catalyst, featuring a combination of titanium and iron oxides on the surface of the fishbone-derived carbon sulfonate, demonstrates higher catalytic activity than single oxide catalysts, such as titanium or iron oxides alone. Factors influencing the catalyst's performance are investigated by using FTIR, XRD, XRF, SEM, and BET surface area. The results reveal that the presence of both titanium and iron oxides on the surface of the fishbone-derived carbon sulfonate and the catalyst's surface area creates a synergistic effect, the primary factors affecting its catalytic activity in styrene oxidation using H2O2 as an oxidant. |
| first_indexed | 2024-03-08T08:53:20Z |
| format | Article |
| id | doaj.art-5e2166d8b2a046e78042670a45974fc4 |
| institution | Directory Open Access Journal |
| issn | 1411-9420 2460-1578 |
| language | English |
| last_indexed | 2024-03-08T08:53:20Z |
| publishDate | 2023-12-01 |
| publisher | Department of Chemistry, Universitas Gadjah Mada |
| record_format | Article |
| series | Indonesian Journal of Chemistry |
| spelling | doaj.art-5e2166d8b2a046e78042670a45974fc42024-02-01T07:39:03ZengDepartment of Chemistry, Universitas Gadjah MadaIndonesian Journal of Chemistry1411-94202460-15782023-12-012361514152410.22146/ijc.8066734731Synergistic Ti-Fe Oxides on Fishbone-Derived Carbon Sulfonate: Enhanced Styrene Oxidation CatalysisMukhamad Nurhadi0Ratna Kusumawardani1Teguh Wirawan2Sin Yuan Lai3Hadi Nur4Department of Chemical Education, Universitas Mulawarman, Kampus Gunung Kelua, Samarinda 75119, IndonesiaDepartment of Chemical Education, Universitas Mulawarman, Kampus Gunung Kelua, Samarinda 75119, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Mulawarman, Samarinda 75119, IndonesiaSchool of Energy and Chemical Engineering, Xiamen University Malaysia, Selangor Darul Ehsan 43900, Malaysia; Kelip-kelip! Center of Excellence for Light Enabling Technologies, Xiamen University Malaysia, Bandar Sunsuria, Sepang 43900, Malaysia; College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, ChinaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Malang, Jl. Semarang No. 5, Malang 65145, Indonesia; Center of Advanced Materials for Renewable Energy (CAMRY), Universitas Negeri Malang, Jl. Semarang No. 5, Malang 65145, IndonesiaFishbone-derived carbon sulfonate, modified through incipient wetness impregnation with titanium tetraisopropoxide and iron nitrate salts, displays catalytic activity in the oxidation of styrene with hydrogen peroxide (H2O2) as an oxidant. This was done to develop a cost-effective, non-toxic, and environmentally friendly bimetallic oxide catalyst, incorporating titanium and iron oxides on mesoporous-derived carbon fishbone to enhance styrene conversion and benzaldehyde selectivity in styrene oxidation using aqueous H2O2. The catalyst, featuring a combination of titanium and iron oxides on the surface of the fishbone-derived carbon sulfonate, demonstrates higher catalytic activity than single oxide catalysts, such as titanium or iron oxides alone. Factors influencing the catalyst's performance are investigated by using FTIR, XRD, XRF, SEM, and BET surface area. The results reveal that the presence of both titanium and iron oxides on the surface of the fishbone-derived carbon sulfonate and the catalyst's surface area creates a synergistic effect, the primary factors affecting its catalytic activity in styrene oxidation using H2O2 as an oxidant.https://jurnal.ugm.ac.id/ijc/article/view/80667ironoxidationstyrenesynergistic effecttitanium |
| spellingShingle | Mukhamad Nurhadi Ratna Kusumawardani Teguh Wirawan Sin Yuan Lai Hadi Nur Synergistic Ti-Fe Oxides on Fishbone-Derived Carbon Sulfonate: Enhanced Styrene Oxidation Catalysis Indonesian Journal of Chemistry iron oxidation styrene synergistic effect titanium |
| title | Synergistic Ti-Fe Oxides on Fishbone-Derived Carbon Sulfonate: Enhanced Styrene Oxidation Catalysis |
| title_full | Synergistic Ti-Fe Oxides on Fishbone-Derived Carbon Sulfonate: Enhanced Styrene Oxidation Catalysis |
| title_fullStr | Synergistic Ti-Fe Oxides on Fishbone-Derived Carbon Sulfonate: Enhanced Styrene Oxidation Catalysis |
| title_full_unstemmed | Synergistic Ti-Fe Oxides on Fishbone-Derived Carbon Sulfonate: Enhanced Styrene Oxidation Catalysis |
| title_short | Synergistic Ti-Fe Oxides on Fishbone-Derived Carbon Sulfonate: Enhanced Styrene Oxidation Catalysis |
| title_sort | synergistic ti fe oxides on fishbone derived carbon sulfonate enhanced styrene oxidation catalysis |
| topic | iron oxidation styrene synergistic effect titanium |
| url | https://jurnal.ugm.ac.id/ijc/article/view/80667 |
| work_keys_str_mv | AT mukhamadnurhadi synergistictifeoxidesonfishbonederivedcarbonsulfonateenhancedstyreneoxidationcatalysis AT ratnakusumawardani synergistictifeoxidesonfishbonederivedcarbonsulfonateenhancedstyreneoxidationcatalysis AT teguhwirawan synergistictifeoxidesonfishbonederivedcarbonsulfonateenhancedstyreneoxidationcatalysis AT sinyuanlai synergistictifeoxidesonfishbonederivedcarbonsulfonateenhancedstyreneoxidationcatalysis AT hadinur synergistictifeoxidesonfishbonederivedcarbonsulfonateenhancedstyreneoxidationcatalysis |