Electropolymerisation Technologies for Next-Generation Lithium–Sulphur Batteries

Lithium–sulphur batteries (LiSBs) have garnered significant attention as the next-generation energy storage device because of their high theoretical energy density, low cost, and environmental friendliness. However, the undesirable “shuttle effect” by lithium polysulphides (LPSs) severely inhibits t...

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Main Authors: Soochan Kim, Youngkwan Lee
Format: Article
Language:English
Published: MDPI AG 2023-07-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/15/15/3231
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author Soochan Kim
Youngkwan Lee
author_facet Soochan Kim
Youngkwan Lee
author_sort Soochan Kim
collection DOAJ
description Lithium–sulphur batteries (LiSBs) have garnered significant attention as the next-generation energy storage device because of their high theoretical energy density, low cost, and environmental friendliness. However, the undesirable “shuttle effect” by lithium polysulphides (LPSs) severely inhibits their practical application. To alleviate the shuttle effect, conductive polymers have been used to fabricate LiSBs owing to their improved electrically conducting pathways, flexible mechanical properties, and high affinity to LPSs, which allow the shuttle effect to be controlled. In this study, the applications of various conductive polymers prepared via the simple yet sophisticated electropolymerisation (EP) technology are systematically investigated based on the main components of LiSBs (cathodes, anodes, separators, and electrolytes). Finally, the potential application of EP technology in next-generation batteries is comprehensively discussed.
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spelling doaj.art-5e263c208c8f4145a0f26acb52d06d412023-11-18T23:28:21ZengMDPI AGPolymers2073-43602023-07-011515323110.3390/polym15153231Electropolymerisation Technologies for Next-Generation Lithium–Sulphur BatteriesSoochan Kim0Youngkwan Lee1Department of Engineering, University of Cambridge, Cambridge CB3 0FS, UKSchool of Chemical Engineering, Sungkyunkwan University, Suwon 16419, Republic of KoreaLithium–sulphur batteries (LiSBs) have garnered significant attention as the next-generation energy storage device because of their high theoretical energy density, low cost, and environmental friendliness. However, the undesirable “shuttle effect” by lithium polysulphides (LPSs) severely inhibits their practical application. To alleviate the shuttle effect, conductive polymers have been used to fabricate LiSBs owing to their improved electrically conducting pathways, flexible mechanical properties, and high affinity to LPSs, which allow the shuttle effect to be controlled. In this study, the applications of various conductive polymers prepared via the simple yet sophisticated electropolymerisation (EP) technology are systematically investigated based on the main components of LiSBs (cathodes, anodes, separators, and electrolytes). Finally, the potential application of EP technology in next-generation batteries is comprehensively discussed.https://www.mdpi.com/2073-4360/15/15/3231electropolymerisationconductive polymerbattery componentslithium–sulphur batteries
spellingShingle Soochan Kim
Youngkwan Lee
Electropolymerisation Technologies for Next-Generation Lithium–Sulphur Batteries
Polymers
electropolymerisation
conductive polymer
battery components
lithium–sulphur batteries
title Electropolymerisation Technologies for Next-Generation Lithium–Sulphur Batteries
title_full Electropolymerisation Technologies for Next-Generation Lithium–Sulphur Batteries
title_fullStr Electropolymerisation Technologies for Next-Generation Lithium–Sulphur Batteries
title_full_unstemmed Electropolymerisation Technologies for Next-Generation Lithium–Sulphur Batteries
title_short Electropolymerisation Technologies for Next-Generation Lithium–Sulphur Batteries
title_sort electropolymerisation technologies for next generation lithium sulphur batteries
topic electropolymerisation
conductive polymer
battery components
lithium–sulphur batteries
url https://www.mdpi.com/2073-4360/15/15/3231
work_keys_str_mv AT soochankim electropolymerisationtechnologiesfornextgenerationlithiumsulphurbatteries
AT youngkwanlee electropolymerisationtechnologiesfornextgenerationlithiumsulphurbatteries