A small library of C–H⋯O hydrogen bonds based on supramolecular architectures of 1,5-diketone malonates in the solid state
Structural supramolecular architectures in the solid state of 1,5-diketone malonates 1a-g are proposed to construct a small library of hydrogen bonds by C–H⋯O interactions by crystal structure analysis. A possible route of crystallization mechanism at different levels of hierarchy considers the next...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Elsevier
2023-07-01
|
| Series: | Arabian Journal of Chemistry |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S1878535223003052 |
| _version_ | 1797837093757517824 |
|---|---|
| author | Domingo Salazar-Mendoza José Luis García-Gutiérrez Federico Jiménez-Cruz |
| author_facet | Domingo Salazar-Mendoza José Luis García-Gutiérrez Federico Jiménez-Cruz |
| author_sort | Domingo Salazar-Mendoza |
| collection | DOAJ |
| description | Structural supramolecular architectures in the solid state of 1,5-diketone malonates 1a-g are proposed to construct a small library of hydrogen bonds by C–H⋯O interactions by crystal structure analysis. A possible route of crystallization mechanism at different levels of hierarchy considers the next strategic steps: a) Intramolecular interactions provide a kite-like molecular conformation. b) Intermolecular interactions provide molecular recognition between the structural unit, synthon, and macrocycles. c) The supramolecular architectures obtained from the conjunction of the multiple functions performed by the C–H⋯O interactions. X-ray studies and Hirshfeld Surface Analysis are described. |
| first_indexed | 2024-04-09T15:20:21Z |
| format | Article |
| id | doaj.art-5e27e21577ed4210a217ad7c01442448 |
| institution | Directory Open Access Journal |
| issn | 1878-5352 |
| language | English |
| last_indexed | 2024-04-09T15:20:21Z |
| publishDate | 2023-07-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Arabian Journal of Chemistry |
| spelling | doaj.art-5e27e21577ed4210a217ad7c014424482023-04-29T14:49:21ZengElsevierArabian Journal of Chemistry1878-53522023-07-01167104843A small library of C–H⋯O hydrogen bonds based on supramolecular architectures of 1,5-diketone malonates in the solid stateDomingo Salazar-Mendoza0José Luis García-Gutiérrez1Federico Jiménez-Cruz2Universidad Tecnológica de la Mixteca, Carretera a Acatlima 2.5 km, 69000, Huajuapan de León, Oaxaca, México; Corresponding authors.Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas 152, Col. San Bartolo Atepehuacan, G. A. Madero, México City 07730, MéxicoInstituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas 152, Col. San Bartolo Atepehuacan, G. A. Madero, México City 07730, México; Corresponding authors.Structural supramolecular architectures in the solid state of 1,5-diketone malonates 1a-g are proposed to construct a small library of hydrogen bonds by C–H⋯O interactions by crystal structure analysis. A possible route of crystallization mechanism at different levels of hierarchy considers the next strategic steps: a) Intramolecular interactions provide a kite-like molecular conformation. b) Intermolecular interactions provide molecular recognition between the structural unit, synthon, and macrocycles. c) The supramolecular architectures obtained from the conjunction of the multiple functions performed by the C–H⋯O interactions. X-ray studies and Hirshfeld Surface Analysis are described.http://www.sciencedirect.com/science/article/pii/S18785352230030521, 5-diketone malonatesSupramolecular architecturesSynthonsIntermolecular hydrogen bondingIntramolecular hydrogen bondingHirshfeld surface analysis |
| spellingShingle | Domingo Salazar-Mendoza José Luis García-Gutiérrez Federico Jiménez-Cruz A small library of C–H⋯O hydrogen bonds based on supramolecular architectures of 1,5-diketone malonates in the solid state Arabian Journal of Chemistry 1, 5-diketone malonates Supramolecular architectures Synthons Intermolecular hydrogen bonding Intramolecular hydrogen bonding Hirshfeld surface analysis |
| title | A small library of C–H⋯O hydrogen bonds based on supramolecular architectures of 1,5-diketone malonates in the solid state |
| title_full | A small library of C–H⋯O hydrogen bonds based on supramolecular architectures of 1,5-diketone malonates in the solid state |
| title_fullStr | A small library of C–H⋯O hydrogen bonds based on supramolecular architectures of 1,5-diketone malonates in the solid state |
| title_full_unstemmed | A small library of C–H⋯O hydrogen bonds based on supramolecular architectures of 1,5-diketone malonates in the solid state |
| title_short | A small library of C–H⋯O hydrogen bonds based on supramolecular architectures of 1,5-diketone malonates in the solid state |
| title_sort | small library of c h⋯o hydrogen bonds based on supramolecular architectures of 1 5 diketone malonates in the solid state |
| topic | 1, 5-diketone malonates Supramolecular architectures Synthons Intermolecular hydrogen bonding Intramolecular hydrogen bonding Hirshfeld surface analysis |
| url | http://www.sciencedirect.com/science/article/pii/S1878535223003052 |
| work_keys_str_mv | AT domingosalazarmendoza asmalllibraryofchohydrogenbondsbasedonsupramoleculararchitecturesof15diketonemalonatesinthesolidstate AT joseluisgarciagutierrez asmalllibraryofchohydrogenbondsbasedonsupramoleculararchitecturesof15diketonemalonatesinthesolidstate AT federicojimenezcruz asmalllibraryofchohydrogenbondsbasedonsupramoleculararchitecturesof15diketonemalonatesinthesolidstate AT domingosalazarmendoza smalllibraryofchohydrogenbondsbasedonsupramoleculararchitecturesof15diketonemalonatesinthesolidstate AT joseluisgarciagutierrez smalllibraryofchohydrogenbondsbasedonsupramoleculararchitecturesof15diketonemalonatesinthesolidstate AT federicojimenezcruz smalllibraryofchohydrogenbondsbasedonsupramoleculararchitecturesof15diketonemalonatesinthesolidstate |