Functionalized Hydroperoxide Formation from the Reaction of Methacrolein-Oxide, an Isoprene-Derived Criegee Intermediate, with Formic Acid: Experiment and Theory

Functionalized Hydroperoxide Formation from the Reaction of Methacrolein-Oxide, an Isoprene-Derived Criegee Intermediate, with Formic Acid: Experiment and Theory

Methacrolein oxide (MACR-oxide) is a four-carbon, resonance-stabilized Criegee intermediate produced from isoprene ozonolysis, yet its reactivity is not well understood. This study identifies the functionalized hydroperoxide species, 1-hydroperoxy-2-methylallyl formate (HPMAF), generated from the re...

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Bibliographic Details
Main Authors: Michael F. Vansco, Kristen Zuraski, Frank A. F. Winiberg, Kendrew Au, Nisalak Trongsiriwat, Patrick J. Walsh, David L. Osborn, Carl J. Percival, Stephen J. Klippenstein, Craig A. Taatjes, Marsha I. Lester, Rebecca L. Caravan
Format: Article
Language:English
Published: MDPI AG 2021-05-01
Series:Molecules
Subjects:
reaction intermediates
oxidation reactions
reaction pathways
kinetics
mass spectrometry
ionization
Online Access:https://www.mdpi.com/1420-3049/26/10/3058

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