Grown and Characterization of ZnO Aligned Nanorod Arrays for Sensor Applications

ZnO nanorods are promising materials for many applications, in particular for UV detectors. In the present paper, the properties of high crystal quality individual ZnO nanorods and nanorod arrays grown by the self-catalytic CVD method have been investigated to assess their possible applicationsfor U...

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Main Authors: Arkady N. Redkin, Eugene E. Yakimov, Maria V. Evstafieva, Eugene B. Yakimov
Format: Article
Language:English
Published: MDPI AG 2021-06-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/14/13/3750
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author Arkady N. Redkin
Eugene E. Yakimov
Maria V. Evstafieva
Eugene B. Yakimov
author_facet Arkady N. Redkin
Eugene E. Yakimov
Maria V. Evstafieva
Eugene B. Yakimov
author_sort Arkady N. Redkin
collection DOAJ
description ZnO nanorods are promising materials for many applications, in particular for UV detectors. In the present paper, the properties of high crystal quality individual ZnO nanorods and nanorod arrays grown by the self-catalytic CVD method have been investigated to assess their possible applicationsfor UV photodetectors. X-ray diffraction, Raman spectroscopy and cathodoluminescence investigations demonstrate the high quality of nanorods. The nanorod resistivity and carrier concentration in dark is estimated. The transient photocurrent response of both as grown and annealed at 550 °C nanorod array under UV illumination pulses is studied. It is shown that annealing increases the sensitivity and decreases the responsivity that is explained by oxygen out-diffusion and the formation of near surface layer enriched with oxygen vacancies. Oxygen vacancy formation due to annealing is confirmed by an increase of green emission band intensity.
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spelling doaj.art-5e58c2c847914904bcfe7a6d8155713a2023-11-22T01:16:43ZengMDPI AGEnergies1996-10732021-06-011413375010.3390/en14133750Grown and Characterization of ZnO Aligned Nanorod Arrays for Sensor ApplicationsArkady N. Redkin0Eugene E. Yakimov1Maria V. Evstafieva2Eugene B. Yakimov3Institute of Microelectronics Technology RAS, 6 Academician Ossipyan str., 142432 Chernogolovka, RussiaInstitute of Microelectronics Technology RAS, 6 Academician Ossipyan str., 142432 Chernogolovka, RussiaInstitute of Microelectronics Technology RAS, 6 Academician Ossipyan str., 142432 Chernogolovka, RussiaInstitute of Microelectronics Technology RAS, 6 Academician Ossipyan str., 142432 Chernogolovka, RussiaZnO nanorods are promising materials for many applications, in particular for UV detectors. In the present paper, the properties of high crystal quality individual ZnO nanorods and nanorod arrays grown by the self-catalytic CVD method have been investigated to assess their possible applicationsfor UV photodetectors. X-ray diffraction, Raman spectroscopy and cathodoluminescence investigations demonstrate the high quality of nanorods. The nanorod resistivity and carrier concentration in dark is estimated. The transient photocurrent response of both as grown and annealed at 550 °C nanorod array under UV illumination pulses is studied. It is shown that annealing increases the sensitivity and decreases the responsivity that is explained by oxygen out-diffusion and the formation of near surface layer enriched with oxygen vacancies. Oxygen vacancy formation due to annealing is confirmed by an increase of green emission band intensity.https://www.mdpi.com/1996-1073/14/13/3750ZnO nanorodself-catalytic CVD methodphotoresponsecathodoluminescence
spellingShingle Arkady N. Redkin
Eugene E. Yakimov
Maria V. Evstafieva
Eugene B. Yakimov
Grown and Characterization of ZnO Aligned Nanorod Arrays for Sensor Applications
Energies
ZnO nanorod
self-catalytic CVD method
photoresponse
cathodoluminescence
title Grown and Characterization of ZnO Aligned Nanorod Arrays for Sensor Applications
title_full Grown and Characterization of ZnO Aligned Nanorod Arrays for Sensor Applications
title_fullStr Grown and Characterization of ZnO Aligned Nanorod Arrays for Sensor Applications
title_full_unstemmed Grown and Characterization of ZnO Aligned Nanorod Arrays for Sensor Applications
title_short Grown and Characterization of ZnO Aligned Nanorod Arrays for Sensor Applications
title_sort grown and characterization of zno aligned nanorod arrays for sensor applications
topic ZnO nanorod
self-catalytic CVD method
photoresponse
cathodoluminescence
url https://www.mdpi.com/1996-1073/14/13/3750
work_keys_str_mv AT arkadynredkin grownandcharacterizationofznoalignednanorodarraysforsensorapplications
AT eugeneeyakimov grownandcharacterizationofznoalignednanorodarraysforsensorapplications
AT mariavevstafieva grownandcharacterizationofznoalignednanorodarraysforsensorapplications
AT eugenebyakimov grownandcharacterizationofznoalignednanorodarraysforsensorapplications