Spin-orbit coupling effects in O(2) activation by cofactor-independent 2,4-dioxygenase

Spin-orbit coupling effects in O(2) activation by cofactor-independent 2,4-dioxygenase

The O2 (dioxygen) is paramagnetic molecule with two non-paired electron spins and triplet ground state (S = 1) while majority of organic molecules are diamagnetic species; they have all electron spins paired and the singlet ground state with the total spin S = 0. Oxygenases catalyze a concerted inse...

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Bibliographic Details
Main Authors:	B. F. Minaev, R. R. Valiev
Format:	Article
Language:	English
Published:	National Academy of Sciences of Ukraine, Palladin Institute of Biochemistry 2019-02-01
Series:	The Ukrainian Biochemical Journal
Subjects:	2-methyl-3-hydroxy-4(1H)-quinolone 4-dioxygenase bacterial 1-H-3-hydroxy-4-oxoquinaldine 2 cofactor-independent oxygenases dioxygen radical pair spin-orbit coupling superoxide anion
Online Access:	http://ukrbiochemjournal.org/wp-content/uploads/2019/01/Minaev_1_19.pdf

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