Metrology in Gas Analysis at the Federal Office of Metrology METAS

Gas analysis as a metrological discipline has a history of about 25 years in Switzerland. Starting with the requirement of reliable reference gas mixtures for legal applications the Swiss Federal Office of Metrology (METAS) had to increasingly find also calibration solutions for the ambien...

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Main Author: Bernhard Niederhauser
Format: Article
Language:deu
Published: Swiss Chemical Society 2009-10-01
Series:CHIMIA
Subjects:
Online Access:https://www.chimia.ch/chimia/article/view/4731
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author Bernhard Niederhauser
author_facet Bernhard Niederhauser
author_sort Bernhard Niederhauser
collection DOAJ
description Gas analysis as a metrological discipline has a history of about 25 years in Switzerland. Starting with the requirement of reliable reference gas mixtures for legal applications the Swiss Federal Office of Metrology (METAS) had to increasingly find also calibration solutions for the ambient air level. Thereby the metrological principles of traceability, uncertainty evaluation and verification as well as the use of unambiguous terminology for quantities and units were in the focus of the activities. Using three examples different ways of implementing these principles are explained. For the emission range, traceability is mainly achieved by gravimetrically prepared certified gas mixtures in pressurised cylinders using high purity gases and a highly reproducible comparison method. The reactivity and limited stability of the important analytes in the ambient range ask for dynamic methods to secure traceability to the international system of units (SI). The dynamic methods requiring additionally high accuracy gas flow measurement techniques and trace gas analysis will be the focus for further developments at METAS.
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spelling doaj.art-5e62e9cf99ca4e7caf76c78ca984dac72022-12-21T17:24:44ZdeuSwiss Chemical SocietyCHIMIA0009-42932673-24242009-10-01631010.2533/chimia.2009.650Metrology in Gas Analysis at the Federal Office of Metrology METASBernhard Niederhauser Gas analysis as a metrological discipline has a history of about 25 years in Switzerland. Starting with the requirement of reliable reference gas mixtures for legal applications the Swiss Federal Office of Metrology (METAS) had to increasingly find also calibration solutions for the ambient air level. Thereby the metrological principles of traceability, uncertainty evaluation and verification as well as the use of unambiguous terminology for quantities and units were in the focus of the activities. Using three examples different ways of implementing these principles are explained. For the emission range, traceability is mainly achieved by gravimetrically prepared certified gas mixtures in pressurised cylinders using high purity gases and a highly reproducible comparison method. The reactivity and limited stability of the important analytes in the ambient range ask for dynamic methods to secure traceability to the international system of units (SI). The dynamic methods requiring additionally high accuracy gas flow measurement techniques and trace gas analysis will be the focus for further developments at METAS. https://www.chimia.ch/chimia/article/view/4731Gas analysisMeasurement uncertaintyReference gas mixturesTraceabilityVerification
spellingShingle Bernhard Niederhauser
Metrology in Gas Analysis at the Federal Office of Metrology METAS
CHIMIA
Gas analysis
Measurement uncertainty
Reference gas mixtures
Traceability
Verification
title Metrology in Gas Analysis at the Federal Office of Metrology METAS
title_full Metrology in Gas Analysis at the Federal Office of Metrology METAS
title_fullStr Metrology in Gas Analysis at the Federal Office of Metrology METAS
title_full_unstemmed Metrology in Gas Analysis at the Federal Office of Metrology METAS
title_short Metrology in Gas Analysis at the Federal Office of Metrology METAS
title_sort metrology in gas analysis at the federal office of metrology metas
topic Gas analysis
Measurement uncertainty
Reference gas mixtures
Traceability
Verification
url https://www.chimia.ch/chimia/article/view/4731
work_keys_str_mv AT bernhardniederhauser metrologyingasanalysisatthefederalofficeofmetrologymetas