Morphology Transition of ZnO Nanorod Arrays Synthesized by a Two-Step Aqueous Solution Method

ZnO nanorod arrays (ZNAs) with vertically-aligned orientation were obtained by a two-step aqueous solution method. The morphology of the ZnO nanorods was regulated by changing the precursor concentration and the growth time of each step. ZnO nanorods with distinct structures, including flat top, con...

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Main Authors: Guannan He, Bo Huang, Zhenxuan Lin, Weifeng Yang, Qinyu He, Lunxiong Li
Format: Article
Language:English
Published: MDPI AG 2018-03-01
Series:Crystals
Subjects:
Online Access:http://www.mdpi.com/2073-4352/8/4/152
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author Guannan He
Bo Huang
Zhenxuan Lin
Weifeng Yang
Qinyu He
Lunxiong Li
author_facet Guannan He
Bo Huang
Zhenxuan Lin
Weifeng Yang
Qinyu He
Lunxiong Li
author_sort Guannan He
collection DOAJ
description ZnO nanorod arrays (ZNAs) with vertically-aligned orientation were obtained by a two-step aqueous solution method. The morphology of the ZnO nanorods was regulated by changing the precursor concentration and the growth time of each step. ZnO nanorods with distinct structures, including flat top, cone top, syringe shape, and nail shape, were obtained. Moreover, based on the X-ray diffraction (XRD) and the transmission electron microscope (TEM) analysis, the possible growth mechanisms of different ZnO nanostructrues were proposed. The room-temperature PL spectra show that the syringe-shaped ZNAs with ultra-sharp tips have high crystalline quality. Our study provides a simple and repeatable method to regulate the morphology of the ZNAs.
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spelling doaj.art-5e73bc7004f2499aa0aa7e9b6c5a886d2022-12-22T04:20:07ZengMDPI AGCrystals2073-43522018-03-018415210.3390/cryst8040152cryst8040152Morphology Transition of ZnO Nanorod Arrays Synthesized by a Two-Step Aqueous Solution MethodGuannan He0Bo Huang1Zhenxuan Lin2Weifeng Yang3Qinyu He4Lunxiong Li5Guangdong Provincial Key Laboratory of Quantum Engineering and Quantum Materials, South China Normal University, Guangzhou 510006, Guangdong, ChinaDepartment of Electronic Engineering, Jinan University, Guangzhou 510632, Guangdong, ChinaGuangdong Provincial Key Laboratory of Quantum Engineering and Quantum Materials, South China Normal University, Guangzhou 510006, Guangdong, ChinaInstitute of Materials Research and Engineering, A*STAR (Agency for Science, Technology and Research), 2 Fusionopolis Way, Innovis, Singapore 138634, SingaporeGuangdong Provincial Key Laboratory of Quantum Engineering and Quantum Materials, South China Normal University, Guangzhou 510006, Guangdong, ChinaGuangdong Provincial Key Laboratory of Quantum Engineering and Quantum Materials, South China Normal University, Guangzhou 510006, Guangdong, ChinaZnO nanorod arrays (ZNAs) with vertically-aligned orientation were obtained by a two-step aqueous solution method. The morphology of the ZnO nanorods was regulated by changing the precursor concentration and the growth time of each step. ZnO nanorods with distinct structures, including flat top, cone top, syringe shape, and nail shape, were obtained. Moreover, based on the X-ray diffraction (XRD) and the transmission electron microscope (TEM) analysis, the possible growth mechanisms of different ZnO nanostructrues were proposed. The room-temperature PL spectra show that the syringe-shaped ZNAs with ultra-sharp tips have high crystalline quality. Our study provides a simple and repeatable method to regulate the morphology of the ZNAs.http://www.mdpi.com/2073-4352/8/4/152ZnO nanorod arraysaqueous solution methodgrowth mechanismPL spectra
spellingShingle Guannan He
Bo Huang
Zhenxuan Lin
Weifeng Yang
Qinyu He
Lunxiong Li
Morphology Transition of ZnO Nanorod Arrays Synthesized by a Two-Step Aqueous Solution Method
Crystals
ZnO nanorod arrays
aqueous solution method
growth mechanism
PL spectra
title Morphology Transition of ZnO Nanorod Arrays Synthesized by a Two-Step Aqueous Solution Method
title_full Morphology Transition of ZnO Nanorod Arrays Synthesized by a Two-Step Aqueous Solution Method
title_fullStr Morphology Transition of ZnO Nanorod Arrays Synthesized by a Two-Step Aqueous Solution Method
title_full_unstemmed Morphology Transition of ZnO Nanorod Arrays Synthesized by a Two-Step Aqueous Solution Method
title_short Morphology Transition of ZnO Nanorod Arrays Synthesized by a Two-Step Aqueous Solution Method
title_sort morphology transition of zno nanorod arrays synthesized by a two step aqueous solution method
topic ZnO nanorod arrays
aqueous solution method
growth mechanism
PL spectra
url http://www.mdpi.com/2073-4352/8/4/152
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AT weifengyang morphologytransitionofznonanorodarrayssynthesizedbyatwostepaqueoussolutionmethod
AT qinyuhe morphologytransitionofznonanorodarrayssynthesizedbyatwostepaqueoussolutionmethod
AT lunxiongli morphologytransitionofznonanorodarrayssynthesizedbyatwostepaqueoussolutionmethod