Poly[[tetraaquabis(1H-imidazole-κN3)bis[2-(oxaloamino)benzoato(3–)]dicopper(II)barium(II)] dihydrate]
In the title coordination polymer, {[BaCu2(C9H4NO5)2(C3H4N2)2(H2O)4]·2H2O}n, the Ba2+ cation is decacoordinate, ligated by four aqua ligands and four [Cu(C9H4O5N)(C3H4N2)] `complex ligands'. The CuII-containing complex-ligands are bridged by the Ba2+ cations, resulting in a one-dimensi...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808000597 |
| _version_ | 1818491501461635072 |
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| author | Peng Zhang Kaihui Li Chongzhen Mei |
| author_facet | Peng Zhang Kaihui Li Chongzhen Mei |
| author_sort | Peng Zhang |
| collection | DOAJ |
| description | In the title coordination polymer, {[BaCu2(C9H4NO5)2(C3H4N2)2(H2O)4]·2H2O}n, the Ba2+ cation is decacoordinate, ligated by four aqua ligands and four [Cu(C9H4O5N)(C3H4N2)] `complex ligands'. The CuII-containing complex-ligands are bridged by the Ba2+ cations, resulting in a one-dimensional polymeric chain structure. The crystal structure is maintained via N—H...O and O—H...O hydrogen bonds. There is one disordered solvent water molecule in the asymmetric unit, with occupancies of 0.44 (2) and 0.56 (2). |
| first_indexed | 2024-12-10T17:31:39Z |
| format | Article |
| id | doaj.art-5e98cdd65e8b48fb81220312eee2420d |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T17:31:39Z |
| publishDate | 2008-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-5e98cdd65e8b48fb81220312eee2420d2022-12-22T01:39:39ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-02-01642m356m35610.1107/S1600536808000597Poly[[tetraaquabis(1H-imidazole-κN3)bis[2-(oxaloamino)benzoato(3–)]dicopper(II)barium(II)] dihydrate]Peng ZhangKaihui LiChongzhen MeiIn the title coordination polymer, {[BaCu2(C9H4NO5)2(C3H4N2)2(H2O)4]·2H2O}n, the Ba2+ cation is decacoordinate, ligated by four aqua ligands and four [Cu(C9H4O5N)(C3H4N2)] `complex ligands'. The CuII-containing complex-ligands are bridged by the Ba2+ cations, resulting in a one-dimensional polymeric chain structure. The crystal structure is maintained via N—H...O and O—H...O hydrogen bonds. There is one disordered solvent water molecule in the asymmetric unit, with occupancies of 0.44 (2) and 0.56 (2).http://scripts.iucr.org/cgi-bin/paper?S1600536808000597 |
| spellingShingle | Peng Zhang Kaihui Li Chongzhen Mei Poly[[tetraaquabis(1H-imidazole-κN3)bis[2-(oxaloamino)benzoato(3–)]dicopper(II)barium(II)] dihydrate] Acta Crystallographica Section E |
| title | Poly[[tetraaquabis(1H-imidazole-κN3)bis[2-(oxaloamino)benzoato(3–)]dicopper(II)barium(II)] dihydrate] |
| title_full | Poly[[tetraaquabis(1H-imidazole-κN3)bis[2-(oxaloamino)benzoato(3–)]dicopper(II)barium(II)] dihydrate] |
| title_fullStr | Poly[[tetraaquabis(1H-imidazole-κN3)bis[2-(oxaloamino)benzoato(3–)]dicopper(II)barium(II)] dihydrate] |
| title_full_unstemmed | Poly[[tetraaquabis(1H-imidazole-κN3)bis[2-(oxaloamino)benzoato(3–)]dicopper(II)barium(II)] dihydrate] |
| title_short | Poly[[tetraaquabis(1H-imidazole-κN3)bis[2-(oxaloamino)benzoato(3–)]dicopper(II)barium(II)] dihydrate] |
| title_sort | poly tetraaquabis 1h imidazole 954 n3 bis 2 oxaloamino benzoato 3 8211 dicopper ii barium ii dihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808000597 |
| work_keys_str_mv | AT pengzhang polytetraaquabis1himidazole954n3bis2oxaloaminobenzoato38211dicopperiibariumiidihydrate AT kaihuili polytetraaquabis1himidazole954n3bis2oxaloaminobenzoato38211dicopperiibariumiidihydrate AT chongzhenmei polytetraaquabis1himidazole954n3bis2oxaloaminobenzoato38211dicopperiibariumiidihydrate |