Hierarchically Nanostructured Transition Metal Oxides for Lithium‐Ion Batteries

Abstract Lithium‐ion batteries (LIBs) have been widely used in the field of portable electric devices because of their high energy density and long cycling life. To further improve the performance of LIBs, it is of great importance to develop new electrode materials. Various transition metal oxides...

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Main Authors: Mingbo Zheng, Hao Tang, Lulu Li, Qin Hu, Li Zhang, Huaiguo Xue, Huan Pang
Format: Article
Language:English
Published: Wiley 2018-03-01
Series:Advanced Science
Subjects:
Online Access:https://doi.org/10.1002/advs.201700592
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author Mingbo Zheng
Hao Tang
Lulu Li
Qin Hu
Li Zhang
Huaiguo Xue
Huan Pang
author_facet Mingbo Zheng
Hao Tang
Lulu Li
Qin Hu
Li Zhang
Huaiguo Xue
Huan Pang
author_sort Mingbo Zheng
collection DOAJ
description Abstract Lithium‐ion batteries (LIBs) have been widely used in the field of portable electric devices because of their high energy density and long cycling life. To further improve the performance of LIBs, it is of great importance to develop new electrode materials. Various transition metal oxides (TMOs) have been extensively investigated as electrode materials for LIBs. According to the reaction mechanism, there are mainly two kinds of TMOs, one is based on conversion reaction and the other is based on intercalation/deintercalation reaction. Recently, hierarchically nanostructured TMOs have become a hot research area in the field of LIBs. Hierarchical architecture can provide numerous accessible electroactive sites for redox reactions, shorten the diffusion distance of Li‐ion during the reaction, and accommodate volume expansion during cycling. With rapid research progress in this field, a timely account of this advanced technology is highly necessary. Here, the research progress on the synthesis methods, morphological characteristics, and electrochemical performances of hierarchically nanostructured TMOs for LIBs is summarized and discussed. Some relevant prospects are also proposed.
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spelling doaj.art-5e9a8e7c72b44240997176778004b9d12022-12-21T22:46:36ZengWileyAdvanced Science2198-38442018-03-0153n/an/a10.1002/advs.201700592Hierarchically Nanostructured Transition Metal Oxides for Lithium‐Ion BatteriesMingbo Zheng0Hao Tang1Lulu Li2Qin Hu3Li Zhang4Huaiguo Xue5Huan Pang6School of Chemistry and Chemical Engineering Institute for Innovative Materials and Energy Yangzhou University Yangzhou 225002 Jiangsu P. R. ChinaSchool of Chemistry and Chemical Engineering Institute for Innovative Materials and Energy Yangzhou University Yangzhou 225002 Jiangsu P. R. ChinaSchool of Chemistry and Chemical Engineering Institute for Innovative Materials and Energy Yangzhou University Yangzhou 225002 Jiangsu P. R. ChinaSchool of Chemistry and Chemical Engineering Institute for Innovative Materials and Energy Yangzhou University Yangzhou 225002 Jiangsu P. R. ChinaSchool of Chemistry and Chemical Engineering Institute for Innovative Materials and Energy Yangzhou University Yangzhou 225002 Jiangsu P. R. ChinaSchool of Chemistry and Chemical Engineering Institute for Innovative Materials and Energy Yangzhou University Yangzhou 225002 Jiangsu P. R. ChinaSchool of Chemistry and Chemical Engineering Institute for Innovative Materials and Energy Yangzhou University Yangzhou 225002 Jiangsu P. R. ChinaAbstract Lithium‐ion batteries (LIBs) have been widely used in the field of portable electric devices because of their high energy density and long cycling life. To further improve the performance of LIBs, it is of great importance to develop new electrode materials. Various transition metal oxides (TMOs) have been extensively investigated as electrode materials for LIBs. According to the reaction mechanism, there are mainly two kinds of TMOs, one is based on conversion reaction and the other is based on intercalation/deintercalation reaction. Recently, hierarchically nanostructured TMOs have become a hot research area in the field of LIBs. Hierarchical architecture can provide numerous accessible electroactive sites for redox reactions, shorten the diffusion distance of Li‐ion during the reaction, and accommodate volume expansion during cycling. With rapid research progress in this field, a timely account of this advanced technology is highly necessary. Here, the research progress on the synthesis methods, morphological characteristics, and electrochemical performances of hierarchically nanostructured TMOs for LIBs is summarized and discussed. Some relevant prospects are also proposed.https://doi.org/10.1002/advs.201700592hierarchical nanostructureslithium‐ion batteriestransition metal oxides
spellingShingle Mingbo Zheng
Hao Tang
Lulu Li
Qin Hu
Li Zhang
Huaiguo Xue
Huan Pang
Hierarchically Nanostructured Transition Metal Oxides for Lithium‐Ion Batteries
Advanced Science
hierarchical nanostructures
lithium‐ion batteries
transition metal oxides
title Hierarchically Nanostructured Transition Metal Oxides for Lithium‐Ion Batteries
title_full Hierarchically Nanostructured Transition Metal Oxides for Lithium‐Ion Batteries
title_fullStr Hierarchically Nanostructured Transition Metal Oxides for Lithium‐Ion Batteries
title_full_unstemmed Hierarchically Nanostructured Transition Metal Oxides for Lithium‐Ion Batteries
title_short Hierarchically Nanostructured Transition Metal Oxides for Lithium‐Ion Batteries
title_sort hierarchically nanostructured transition metal oxides for lithium ion batteries
topic hierarchical nanostructures
lithium‐ion batteries
transition metal oxides
url https://doi.org/10.1002/advs.201700592
work_keys_str_mv AT mingbozheng hierarchicallynanostructuredtransitionmetaloxidesforlithiumionbatteries
AT haotang hierarchicallynanostructuredtransitionmetaloxidesforlithiumionbatteries
AT lululi hierarchicallynanostructuredtransitionmetaloxidesforlithiumionbatteries
AT qinhu hierarchicallynanostructuredtransitionmetaloxidesforlithiumionbatteries
AT lizhang hierarchicallynanostructuredtransitionmetaloxidesforlithiumionbatteries
AT huaiguoxue hierarchicallynanostructuredtransitionmetaloxidesforlithiumionbatteries
AT huanpang hierarchicallynanostructuredtransitionmetaloxidesforlithiumionbatteries