Supported Ionic Liquid Catalysts for the Oxidation of S- and N-Containing Compounds—The Effect of Bronsted Sites and Heteropolyacid Concentration
In this article, a series of effective catalysts based on betaine and sulfuric or phosphomolybdic acids was obtained. These compositions were characterized by various physicochemical methods and tested in the oxidation of sulfur- and nitrogenous-containing compounds by H<sub>2</sub>O<...
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| Format: | Article |
| Language: | English |
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MDPI AG
2023-03-01
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| Series: | Catalysts |
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| Online Access: | https://www.mdpi.com/2073-4344/13/4/664 |
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| author | Vladislav Gorbunov Aleksey Buryak Kirill Oskolok Andrey G. Popov Irina Tarkhanova |
| author_facet | Vladislav Gorbunov Aleksey Buryak Kirill Oskolok Andrey G. Popov Irina Tarkhanova |
| author_sort | Vladislav Gorbunov |
| collection | DOAJ |
| description | In this article, a series of effective catalysts based on betaine and sulfuric or phosphomolybdic acids was obtained. These compositions were characterized by various physicochemical methods and tested in the oxidation of sulfur- and nitrogenous-containing compounds by H<sub>2</sub>O<sub>2</sub>. An increase in the amount of heteropolyacid (HPA) leads to a non-linear change in acidity, and the degree of removal of sulfur-containing compounds correlates with the concentration of Bronsted acid sites on the surface. On the contrary, the degree of pyridine removal is determined primarily by the content of heteropolyacids in the catalyst. |
| first_indexed | 2024-03-11T05:08:59Z |
| format | Article |
| id | doaj.art-5e9e5084f99146dd96acf20b645a5249 |
| institution | Directory Open Access Journal |
| issn | 2073-4344 |
| language | English |
| last_indexed | 2024-03-11T05:08:59Z |
| publishDate | 2023-03-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Catalysts |
| spelling | doaj.art-5e9e5084f99146dd96acf20b645a52492023-11-17T18:40:50ZengMDPI AGCatalysts2073-43442023-03-0113466410.3390/catal13040664Supported Ionic Liquid Catalysts for the Oxidation of S- and N-Containing Compounds—The Effect of Bronsted Sites and Heteropolyacid ConcentrationVladislav Gorbunov0Aleksey Buryak1Kirill Oskolok2Andrey G. Popov3Irina Tarkhanova4Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, RussiaA.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 31-4 Leninsky Prospect, 119071 Moscow, RussiaDepartment of Chemistry, Lomonosov Moscow State University, 119991 Moscow, RussiaDepartment of Chemistry, Lomonosov Moscow State University, 119991 Moscow, RussiaDepartment of Chemistry, Lomonosov Moscow State University, 119991 Moscow, RussiaIn this article, a series of effective catalysts based on betaine and sulfuric or phosphomolybdic acids was obtained. These compositions were characterized by various physicochemical methods and tested in the oxidation of sulfur- and nitrogenous-containing compounds by H<sub>2</sub>O<sub>2</sub>. An increase in the amount of heteropolyacid (HPA) leads to a non-linear change in acidity, and the degree of removal of sulfur-containing compounds correlates with the concentration of Bronsted acid sites on the surface. On the contrary, the degree of pyridine removal is determined primarily by the content of heteropolyacids in the catalyst.https://www.mdpi.com/2073-4344/13/4/664desulfurizationdenitrogenationionic liquidspolyoxometalates |
| spellingShingle | Vladislav Gorbunov Aleksey Buryak Kirill Oskolok Andrey G. Popov Irina Tarkhanova Supported Ionic Liquid Catalysts for the Oxidation of S- and N-Containing Compounds—The Effect of Bronsted Sites and Heteropolyacid Concentration Catalysts desulfurization denitrogenation ionic liquids polyoxometalates |
| title | Supported Ionic Liquid Catalysts for the Oxidation of S- and N-Containing Compounds—The Effect of Bronsted Sites and Heteropolyacid Concentration |
| title_full | Supported Ionic Liquid Catalysts for the Oxidation of S- and N-Containing Compounds—The Effect of Bronsted Sites and Heteropolyacid Concentration |
| title_fullStr | Supported Ionic Liquid Catalysts for the Oxidation of S- and N-Containing Compounds—The Effect of Bronsted Sites and Heteropolyacid Concentration |
| title_full_unstemmed | Supported Ionic Liquid Catalysts for the Oxidation of S- and N-Containing Compounds—The Effect of Bronsted Sites and Heteropolyacid Concentration |
| title_short | Supported Ionic Liquid Catalysts for the Oxidation of S- and N-Containing Compounds—The Effect of Bronsted Sites and Heteropolyacid Concentration |
| title_sort | supported ionic liquid catalysts for the oxidation of s and n containing compounds the effect of bronsted sites and heteropolyacid concentration |
| topic | desulfurization denitrogenation ionic liquids polyoxometalates |
| url | https://www.mdpi.com/2073-4344/13/4/664 |
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