Tetra-μ-acetato-bis[(1,3-benzothiazole)copper(II)](Cu—Cu)
The title compound, [Cu2(CH3CO2)4(C7H5NS)2] or [(C7H5NS)Cu]2(μ-O2CCH3)4, crystallizes with one molecule per unit cell. The coordination number of copper is six with four basal O atoms, one axial N atom and one axial Cu atom. Four acetate ligands act as bidentate linker and connect two C...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811027140 |
| _version_ | 1823959226131677184 |
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| author | Johannes Hermle Gerd Meyer |
| author_facet | Johannes Hermle Gerd Meyer |
| author_sort | Johannes Hermle |
| collection | DOAJ |
| description | The title compound, [Cu2(CH3CO2)4(C7H5NS)2] or [(C7H5NS)Cu]2(μ-O2CCH3)4, crystallizes with one molecule per unit cell. The coordination number of copper is six with four basal O atoms, one axial N atom and one axial Cu atom. Four acetate ligands act as bidentate linker and connect two Cu atoms, with a crystallographic inversion center located at the mid-point of the Cu—Cu bond. The acetate ligands form slightly distorted square planes around each metal ion, while the copper ions are displaced by 0.2089 (4) Å from these planes towards the N atoms. Thus, the Cu—Cu distance is elongated to 2.6378 (7) Å, compared with the 2.2180 (7) Å distance between the two basal planes. The angle between the basal plane and the Cu—N bond is 4.84 (6)°. |
| first_indexed | 2024-12-17T16:30:01Z |
| format | Article |
| id | doaj.art-5eacf167e8234f689833cc1a37f8299e |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-17T16:30:01Z |
| publishDate | 2011-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-5eacf167e8234f689833cc1a37f8299e2022-12-21T21:41:16ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-08-01678m1089m108910.1107/S1600536811027140Tetra-μ-acetato-bis[(1,3-benzothiazole)copper(II)](Cu—Cu)Johannes HermleGerd MeyerThe title compound, [Cu2(CH3CO2)4(C7H5NS)2] or [(C7H5NS)Cu]2(μ-O2CCH3)4, crystallizes with one molecule per unit cell. The coordination number of copper is six with four basal O atoms, one axial N atom and one axial Cu atom. Four acetate ligands act as bidentate linker and connect two Cu atoms, with a crystallographic inversion center located at the mid-point of the Cu—Cu bond. The acetate ligands form slightly distorted square planes around each metal ion, while the copper ions are displaced by 0.2089 (4) Å from these planes towards the N atoms. Thus, the Cu—Cu distance is elongated to 2.6378 (7) Å, compared with the 2.2180 (7) Å distance between the two basal planes. The angle between the basal plane and the Cu—N bond is 4.84 (6)°.http://scripts.iucr.org/cgi-bin/paper?S1600536811027140 |
| spellingShingle | Johannes Hermle Gerd Meyer Tetra-μ-acetato-bis[(1,3-benzothiazole)copper(II)](Cu—Cu) Acta Crystallographica Section E |
| title | Tetra-μ-acetato-bis[(1,3-benzothiazole)copper(II)](Cu—Cu) |
| title_full | Tetra-μ-acetato-bis[(1,3-benzothiazole)copper(II)](Cu—Cu) |
| title_fullStr | Tetra-μ-acetato-bis[(1,3-benzothiazole)copper(II)](Cu—Cu) |
| title_full_unstemmed | Tetra-μ-acetato-bis[(1,3-benzothiazole)copper(II)](Cu—Cu) |
| title_short | Tetra-μ-acetato-bis[(1,3-benzothiazole)copper(II)](Cu—Cu) |
| title_sort | tetra amp 956 acetato bis 1 3 benzothiazole copper ii cu amp 8212 cu |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811027140 |
| work_keys_str_mv | AT johanneshermle tetraamp956acetatobis13benzothiazolecopperiicuamp8212cu AT gerdmeyer tetraamp956acetatobis13benzothiazolecopperiicuamp8212cu |