Synthesis and Characterisation of Azo-Based Dichlorotriazine Reactive Dye with Halochromic Behaviour

Halochromism or pH sensitivity has tremendous potential for applications in various textile fields, such as protective clothing, wound dressings, etc. Reactive dye is mostly used to colour cotton or other regenerated cellulose fibres due to its better fastness and wide range of hue, from vivid to d...

Full description

Bibliographic Details
Main Authors: Mustafijur Rahman, Mohammad Abbas Uddin, Md. Moynul Hassan Shibly, Nusrat Binta Hossain, Mohammad Forhad Hossain, Muriel Rigout
Format: Article
Language:English
Published: University of Ljubljana Press (Založba Univerze v Ljubljani) 2021-11-01
Series:Tekstilec
Subjects:
Online Access:https://journals.uni-lj.si/tekstilec/article/view/12022
_version_ 1797771966470422528
author Mustafijur Rahman
Mohammad Abbas Uddin
Md. Moynul Hassan Shibly
Nusrat Binta Hossain
Mohammad Forhad Hossain
Muriel Rigout
author_facet Mustafijur Rahman
Mohammad Abbas Uddin
Md. Moynul Hassan Shibly
Nusrat Binta Hossain
Mohammad Forhad Hossain
Muriel Rigout
author_sort Mustafijur Rahman
collection DOAJ
description Halochromism or pH sensitivity has tremendous potential for applications in various textile fields, such as protective clothing, wound dressings, etc. Reactive dye is mostly used to colour cotton or other regenerated cellulose fibres due to its better fastness and wide range of hue, from vivid to dull shades. In this research work, an azo-based dichlorotriazine reactive dye was synthesised from H-acid (4-amino-5-hydroxy-2,7-naphthalenedisulfonic acid) and 4-nitroaniline, which incorporates a halochromic behaviour. The change of colour of this dye was evaluated both in the the solution stage and coloured fabric stage in various pH solutions. A visible change of colour with the alteration of pH was observed after dyeing textile fabric with the synthesised dye. However, a significant difference was observed in a few cases with regard to the change of colour with the alteration of pH in the solution stage and coloured fabric stage. The dyed fabric also displayed very good to excellent wash fastness properties. Generally, the reactive dye synthesised in this research demonstrated an obvious change of colour with the alteration of the pH level.
first_indexed 2024-03-12T21:45:14Z
format Article
id doaj.art-5eb33dd3a4904e1d941ace86fa131d59
institution Directory Open Access Journal
issn 0351-3386
2350-3696
language English
last_indexed 2024-03-12T21:45:14Z
publishDate 2021-11-01
publisher University of Ljubljana Press (Založba Univerze v Ljubljani)
record_format Article
series Tekstilec
spelling doaj.art-5eb33dd3a4904e1d941ace86fa131d592023-07-26T12:40:12ZengUniversity of Ljubljana Press (Založba Univerze v Ljubljani)Tekstilec0351-33862350-36962021-11-0164310.14502/Tekstilec2021.64.247-25918409Synthesis and Characterisation of Azo-Based Dichlorotriazine Reactive Dye with Halochromic BehaviourMustafijur Rahman0Mohammad Abbas Uddin1Md. Moynul Hassan Shibly2Nusrat Binta Hossain3Mohammad Forhad Hossain4Muriel Rigout5Department of Dyes and Chemicals Engineering, Bangladesh University of Textiles, Dhaka, BangladeshDepartment of Dyes and Chemicals Engineering, Bangladesh University of Textiles, Dhaka, BangladeshDepartment of Textile Engineering, Primeasia University, Dhaka, Bangladesh Puls Trading Far East Limited, H&M Bangladesh Liaison Office, Dhaka, Bangladesh Department of Dyes and Chemicals Engineering, Bangladesh University of Textiles, Dhaka, BangladeshSchool of Design, University of Leeds, Leeds, LS2 9JT, UK Halochromism or pH sensitivity has tremendous potential for applications in various textile fields, such as protective clothing, wound dressings, etc. Reactive dye is mostly used to colour cotton or other regenerated cellulose fibres due to its better fastness and wide range of hue, from vivid to dull shades. In this research work, an azo-based dichlorotriazine reactive dye was synthesised from H-acid (4-amino-5-hydroxy-2,7-naphthalenedisulfonic acid) and 4-nitroaniline, which incorporates a halochromic behaviour. The change of colour of this dye was evaluated both in the the solution stage and coloured fabric stage in various pH solutions. A visible change of colour with the alteration of pH was observed after dyeing textile fabric with the synthesised dye. However, a significant difference was observed in a few cases with regard to the change of colour with the alteration of pH in the solution stage and coloured fabric stage. The dyed fabric also displayed very good to excellent wash fastness properties. Generally, the reactive dye synthesised in this research demonstrated an obvious change of colour with the alteration of the pH level. https://journals.uni-lj.si/tekstilec/article/view/12022chromismH-acid4-nitroanilinesynthesishalochromicdichlorotriazine
spellingShingle Mustafijur Rahman
Mohammad Abbas Uddin
Md. Moynul Hassan Shibly
Nusrat Binta Hossain
Mohammad Forhad Hossain
Muriel Rigout
Synthesis and Characterisation of Azo-Based Dichlorotriazine Reactive Dye with Halochromic Behaviour
Tekstilec
chromism
H-acid
4-nitroaniline
synthesis
halochromic
dichlorotriazine
title Synthesis and Characterisation of Azo-Based Dichlorotriazine Reactive Dye with Halochromic Behaviour
title_full Synthesis and Characterisation of Azo-Based Dichlorotriazine Reactive Dye with Halochromic Behaviour
title_fullStr Synthesis and Characterisation of Azo-Based Dichlorotriazine Reactive Dye with Halochromic Behaviour
title_full_unstemmed Synthesis and Characterisation of Azo-Based Dichlorotriazine Reactive Dye with Halochromic Behaviour
title_short Synthesis and Characterisation of Azo-Based Dichlorotriazine Reactive Dye with Halochromic Behaviour
title_sort synthesis and characterisation of azo based dichlorotriazine reactive dye with halochromic behaviour
topic chromism
H-acid
4-nitroaniline
synthesis
halochromic
dichlorotriazine
url https://journals.uni-lj.si/tekstilec/article/view/12022
work_keys_str_mv AT mustafijurrahman synthesisandcharacterisationofazobaseddichlorotriazinereactivedyewithhalochromicbehaviour
AT mohammadabbasuddin synthesisandcharacterisationofazobaseddichlorotriazinereactivedyewithhalochromicbehaviour
AT mdmoynulhassanshibly synthesisandcharacterisationofazobaseddichlorotriazinereactivedyewithhalochromicbehaviour
AT nusratbintahossain synthesisandcharacterisationofazobaseddichlorotriazinereactivedyewithhalochromicbehaviour
AT mohammadforhadhossain synthesisandcharacterisationofazobaseddichlorotriazinereactivedyewithhalochromicbehaviour
AT murielrigout synthesisandcharacterisationofazobaseddichlorotriazinereactivedyewithhalochromicbehaviour