Hydrogenation of Biomass-Derived Levulinic Acid to Gamma- Valerolactone Using Polymer-Based Metal-Containing Catalysts
Nowadays the development of effective catalytic systems of selective hydrogenation of levulinic acid (LA) to gamma-valerolactone (GVL) is of high importance. However, there is a lack of data concerning the use of polymer-based catalyst in this process. The possibility to use of Ru-containing catalys...
| Main Authors: | , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
AIDIC Servizi S.r.l.
2017-10-01
|
| Series: | Chemical Engineering Transactions |
| Online Access: | https://www.cetjournal.it/index.php/cet/article/view/200 |
| _version_ | 1811189844042317824 |
|---|---|
| author | L.Z. Nikoshvili I.I. Protsenko D.A. Abusuek A.O. Zaykovskaya A.V. Bykov V. Matveeva E. Sulman |
| author_facet | L.Z. Nikoshvili I.I. Protsenko D.A. Abusuek A.O. Zaykovskaya A.V. Bykov V. Matveeva E. Sulman |
| author_sort | L.Z. Nikoshvili |
| collection | DOAJ |
| description | Nowadays the development of effective catalytic systems of selective hydrogenation of levulinic acid (LA) to gamma-valerolactone (GVL) is of high importance. However, there is a lack of data concerning the use of polymer-based catalyst in this process. The possibility to use of Ru-containing catalysts on the basis of hypercrosslinked polystyrene (HPS) in hydrogenation of LA to GVL is discussed. Catalyst 5%-Ru/HPS is shown to be highly active and selective in hydrogenation of LA in aqueous medium (yield of GVL more than 99%) at mild reaction conditions (90 °C, 2 MPa of hydrogen partial pressure) and the absence of co-catalysts. |
| first_indexed | 2024-04-11T14:40:32Z |
| format | Article |
| id | doaj.art-5ebbcb05891e432082cf0e9a882bc36e |
| institution | Directory Open Access Journal |
| issn | 2283-9216 |
| language | English |
| last_indexed | 2024-04-11T14:40:32Z |
| publishDate | 2017-10-01 |
| publisher | AIDIC Servizi S.r.l. |
| record_format | Article |
| series | Chemical Engineering Transactions |
| spelling | doaj.art-5ebbcb05891e432082cf0e9a882bc36e2022-12-22T04:17:57ZengAIDIC Servizi S.r.l.Chemical Engineering Transactions2283-92162017-10-016110.3303/CET1761147Hydrogenation of Biomass-Derived Levulinic Acid to Gamma- Valerolactone Using Polymer-Based Metal-Containing CatalystsL.Z. NikoshviliI.I. ProtsenkoD.A. AbusuekA.O. ZaykovskayaA.V. BykovV. MatveevaE. SulmanNowadays the development of effective catalytic systems of selective hydrogenation of levulinic acid (LA) to gamma-valerolactone (GVL) is of high importance. However, there is a lack of data concerning the use of polymer-based catalyst in this process. The possibility to use of Ru-containing catalysts on the basis of hypercrosslinked polystyrene (HPS) in hydrogenation of LA to GVL is discussed. Catalyst 5%-Ru/HPS is shown to be highly active and selective in hydrogenation of LA in aqueous medium (yield of GVL more than 99%) at mild reaction conditions (90 °C, 2 MPa of hydrogen partial pressure) and the absence of co-catalysts.https://www.cetjournal.it/index.php/cet/article/view/200 |
| spellingShingle | L.Z. Nikoshvili I.I. Protsenko D.A. Abusuek A.O. Zaykovskaya A.V. Bykov V. Matveeva E. Sulman Hydrogenation of Biomass-Derived Levulinic Acid to Gamma- Valerolactone Using Polymer-Based Metal-Containing Catalysts Chemical Engineering Transactions |
| title | Hydrogenation of Biomass-Derived Levulinic Acid to Gamma- Valerolactone Using Polymer-Based Metal-Containing Catalysts |
| title_full | Hydrogenation of Biomass-Derived Levulinic Acid to Gamma- Valerolactone Using Polymer-Based Metal-Containing Catalysts |
| title_fullStr | Hydrogenation of Biomass-Derived Levulinic Acid to Gamma- Valerolactone Using Polymer-Based Metal-Containing Catalysts |
| title_full_unstemmed | Hydrogenation of Biomass-Derived Levulinic Acid to Gamma- Valerolactone Using Polymer-Based Metal-Containing Catalysts |
| title_short | Hydrogenation of Biomass-Derived Levulinic Acid to Gamma- Valerolactone Using Polymer-Based Metal-Containing Catalysts |
| title_sort | hydrogenation of biomass derived levulinic acid to gamma valerolactone using polymer based metal containing catalysts |
| url | https://www.cetjournal.it/index.php/cet/article/view/200 |
| work_keys_str_mv | AT lznikoshvili hydrogenationofbiomassderivedlevulinicacidtogammavalerolactoneusingpolymerbasedmetalcontainingcatalysts AT iiprotsenko hydrogenationofbiomassderivedlevulinicacidtogammavalerolactoneusingpolymerbasedmetalcontainingcatalysts AT daabusuek hydrogenationofbiomassderivedlevulinicacidtogammavalerolactoneusingpolymerbasedmetalcontainingcatalysts AT aozaykovskaya hydrogenationofbiomassderivedlevulinicacidtogammavalerolactoneusingpolymerbasedmetalcontainingcatalysts AT avbykov hydrogenationofbiomassderivedlevulinicacidtogammavalerolactoneusingpolymerbasedmetalcontainingcatalysts AT vmatveeva hydrogenationofbiomassderivedlevulinicacidtogammavalerolactoneusingpolymerbasedmetalcontainingcatalysts AT esulman hydrogenationofbiomassderivedlevulinicacidtogammavalerolactoneusingpolymerbasedmetalcontainingcatalysts |