A model of chronoamperometry of a two electrons electro-deposition reaction with the adsorption of intermediate
A single step chronoamperometry of reversible reactions complicated by the intermediate adsorption and the product deposition on inert electrodes is compared theoretically with an initial state of a simple two electrons electro-deposition. If the intermediate is highly unstable, these two mechanism...
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| Format: | Article |
| Language: | English |
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International Association of Physical Chemists (IAPC)
2023-10-01
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| Series: | Journal of Electrochemical Science and Engineering |
| Subjects: | |
| Online Access: | https://pub.iapchem.org/ojs/index.php/JESE/article/view/2026 |
| _version_ | 1797629802635591680 |
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| author | Milivoj Lovrić |
| author_facet | Milivoj Lovrić |
| author_sort | Milivoj Lovrić |
| collection | DOAJ |
| description |
A single step chronoamperometry of reversible reactions complicated by the intermediate adsorption and the product deposition on inert electrodes is compared theoretically with an initial state of a simple two electrons electro-deposition. If the intermediate is highly unstable, these two mechanisms are similar, but the mechanism with successive electron transfers is needed to explain the responses appearing generally. The stability of intermediate depends on standard potentials of two steps and on the strength of adsorption. Two limiting cases are analysed and the difference between them is described.
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| first_indexed | 2024-03-11T10:58:11Z |
| format | Article |
| id | doaj.art-5ebc8867661d411d8ed48bb2fdca0492 |
| institution | Directory Open Access Journal |
| issn | 1847-9286 |
| language | English |
| last_indexed | 2024-03-11T10:58:11Z |
| publishDate | 2023-10-01 |
| publisher | International Association of Physical Chemists (IAPC) |
| record_format | Article |
| series | Journal of Electrochemical Science and Engineering |
| spelling | doaj.art-5ebc8867661d411d8ed48bb2fdca04922023-11-13T00:55:09ZengInternational Association of Physical Chemists (IAPC)Journal of Electrochemical Science and Engineering1847-92862023-10-0110.5599/jese.2026A model of chronoamperometry of a two electrons electro-deposition reaction with the adsorption of intermediateMilivoj Lovrić0Independent scientist, Zagreb, Croatia A single step chronoamperometry of reversible reactions complicated by the intermediate adsorption and the product deposition on inert electrodes is compared theoretically with an initial state of a simple two electrons electro-deposition. If the intermediate is highly unstable, these two mechanisms are similar, but the mechanism with successive electron transfers is needed to explain the responses appearing generally. The stability of intermediate depends on standard potentials of two steps and on the strength of adsorption. Two limiting cases are analysed and the difference between them is described. https://pub.iapchem.org/ojs/index.php/JESE/article/view/2026Two steps electrode mechanismsadsorption of intermediatelogarithmic analysissimultaneous electrons transfertheory of electro-deposition reactions |
| spellingShingle | Milivoj Lovrić A model of chronoamperometry of a two electrons electro-deposition reaction with the adsorption of intermediate Journal of Electrochemical Science and Engineering Two steps electrode mechanisms adsorption of intermediate logarithmic analysis simultaneous electrons transfer theory of electro-deposition reactions |
| title | A model of chronoamperometry of a two electrons electro-deposition reaction with the adsorption of intermediate |
| title_full | A model of chronoamperometry of a two electrons electro-deposition reaction with the adsorption of intermediate |
| title_fullStr | A model of chronoamperometry of a two electrons electro-deposition reaction with the adsorption of intermediate |
| title_full_unstemmed | A model of chronoamperometry of a two electrons electro-deposition reaction with the adsorption of intermediate |
| title_short | A model of chronoamperometry of a two electrons electro-deposition reaction with the adsorption of intermediate |
| title_sort | model of chronoamperometry of a two electrons electro deposition reaction with the adsorption of intermediate |
| topic | Two steps electrode mechanisms adsorption of intermediate logarithmic analysis simultaneous electrons transfer theory of electro-deposition reactions |
| url | https://pub.iapchem.org/ojs/index.php/JESE/article/view/2026 |
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