Effects of the Structure of TiO2 Nanotube Arrays on Its Catalytic Activity for Microbial Fuel Cell

Abstract To enhance the microbial fuel cell (MFC) for wastewater treatment and chemical oxygen demand degradation, TiO2 nanotubes arrays (TNA) are successfully synthesized on Ti foil substrate by the anodization process in HF and NH4F solution, respectively (hereafter, denoted as TNA‐HF and TNA‐NF)....

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Main Authors: Tao Guo, Changzheng Wang, Ping Xu, Cuimin Feng, Shuai Si, Yajun Zhang, Qiang Wang, Mengtong Shi, Fengnan Yang, Jingxiao Wang, Yang Zhang
Format: Article
Language:English
Published: Wiley 2019-05-01
Series:Global Challenges
Subjects:
Online Access:https://doi.org/10.1002/gch2.201800084
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author Tao Guo
Changzheng Wang
Ping Xu
Cuimin Feng
Shuai Si
Yajun Zhang
Qiang Wang
Mengtong Shi
Fengnan Yang
Jingxiao Wang
Yang Zhang
author_facet Tao Guo
Changzheng Wang
Ping Xu
Cuimin Feng
Shuai Si
Yajun Zhang
Qiang Wang
Mengtong Shi
Fengnan Yang
Jingxiao Wang
Yang Zhang
author_sort Tao Guo
collection DOAJ
description Abstract To enhance the microbial fuel cell (MFC) for wastewater treatment and chemical oxygen demand degradation, TiO2 nanotubes arrays (TNA) are successfully synthesized on Ti foil substrate by the anodization process in HF and NH4F solution, respectively (hereafter, denoted as TNA‐HF and TNA‐NF). The differences between the two kinds of TNA are revealed based on their morphologies and spectroscopic characterizations. It should be highlighted that 3D TNA‐NF with an appropriate dimension can make a positive contribution to the high photocatalytic activity. In comparison with the TNA‐HF, the 3D TNA‐NF sample exhibits a significant enhancement in current generation as the MFC anode. In particular, the TNA‐NF performs nearly 1.23 times higher than the TNA‐HF, and near twofold higher than the carbon felt. It is found that the two kinds of TiO2‐based anodes have different conductivities and corrosion potentials, which are responsible for the difference in their current generation performances. Based on the experimental results, excellent stability, reliability, and low cost, TNA‐NF can be considered a promising and scalable MFC bioanode material.
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spelling doaj.art-5ecaa273177b4b3ebd197048921bd12e2023-08-14T09:40:38ZengWileyGlobal Challenges2056-66462019-05-0135n/an/a10.1002/gch2.201800084Effects of the Structure of TiO2 Nanotube Arrays on Its Catalytic Activity for Microbial Fuel CellTao Guo0Changzheng Wang1Ping Xu2Cuimin Feng3Shuai Si4Yajun Zhang5Qiang Wang6Mengtong Shi7Fengnan Yang8Jingxiao Wang9Yang Zhang10Key Laboratory of Urban Stormwater System and Water Environment Ministry of Education Beijing University of Civil Engineering and Architecture Beijing 100044 P. R. ChinaKey Laboratory of Urban Stormwater System and Water Environment Ministry of Education Beijing University of Civil Engineering and Architecture Beijing 100044 P. R. ChinaKey Laboratory of Urban Stormwater System and Water Environment Ministry of Education Beijing University of Civil Engineering and Architecture Beijing 100044 P. R. ChinaKey Laboratory of Urban Stormwater System and Water Environment Ministry of Education Beijing University of Civil Engineering and Architecture Beijing 100044 P. R. ChinaKey Laboratory of Urban Stormwater System and Water Environment Ministry of Education Beijing University of Civil Engineering and Architecture Beijing 100044 P. R. ChinaKey Laboratory of Urban Stormwater System and Water Environment Ministry of Education Beijing University of Civil Engineering and Architecture Beijing 100044 P. R. ChinaLaboratory for Micro‐sized Functional Materials College of Elementary Education Capital Normal University Beijing 100048 P. R. ChinaKey Laboratory of Urban Stormwater System and Water Environment Ministry of Education Beijing University of Civil Engineering and Architecture Beijing 100044 P. R. ChinaKey Laboratory of Urban Stormwater System and Water Environment Ministry of Education Beijing University of Civil Engineering and Architecture Beijing 100044 P. R. ChinaKey Laboratory of Urban Stormwater System and Water Environment Ministry of Education Beijing University of Civil Engineering and Architecture Beijing 100044 P. R. ChinaBeijing Institute of Nanoenergy and Nanosystems Chinese Academy of Sciences Beijing 100083 P. R. ChinaAbstract To enhance the microbial fuel cell (MFC) for wastewater treatment and chemical oxygen demand degradation, TiO2 nanotubes arrays (TNA) are successfully synthesized on Ti foil substrate by the anodization process in HF and NH4F solution, respectively (hereafter, denoted as TNA‐HF and TNA‐NF). The differences between the two kinds of TNA are revealed based on their morphologies and spectroscopic characterizations. It should be highlighted that 3D TNA‐NF with an appropriate dimension can make a positive contribution to the high photocatalytic activity. In comparison with the TNA‐HF, the 3D TNA‐NF sample exhibits a significant enhancement in current generation as the MFC anode. In particular, the TNA‐NF performs nearly 1.23 times higher than the TNA‐HF, and near twofold higher than the carbon felt. It is found that the two kinds of TiO2‐based anodes have different conductivities and corrosion potentials, which are responsible for the difference in their current generation performances. Based on the experimental results, excellent stability, reliability, and low cost, TNA‐NF can be considered a promising and scalable MFC bioanode material.https://doi.org/10.1002/gch2.201800084CODmicrobial fuel cellsphotocatalyticpower generationTiO2 nanotube arrays
spellingShingle Tao Guo
Changzheng Wang
Ping Xu
Cuimin Feng
Shuai Si
Yajun Zhang
Qiang Wang
Mengtong Shi
Fengnan Yang
Jingxiao Wang
Yang Zhang
Effects of the Structure of TiO2 Nanotube Arrays on Its Catalytic Activity for Microbial Fuel Cell
Global Challenges
COD
microbial fuel cells
photocatalytic
power generation
TiO2 nanotube arrays
title Effects of the Structure of TiO2 Nanotube Arrays on Its Catalytic Activity for Microbial Fuel Cell
title_full Effects of the Structure of TiO2 Nanotube Arrays on Its Catalytic Activity for Microbial Fuel Cell
title_fullStr Effects of the Structure of TiO2 Nanotube Arrays on Its Catalytic Activity for Microbial Fuel Cell
title_full_unstemmed Effects of the Structure of TiO2 Nanotube Arrays on Its Catalytic Activity for Microbial Fuel Cell
title_short Effects of the Structure of TiO2 Nanotube Arrays on Its Catalytic Activity for Microbial Fuel Cell
title_sort effects of the structure of tio2 nanotube arrays on its catalytic activity for microbial fuel cell
topic COD
microbial fuel cells
photocatalytic
power generation
TiO2 nanotube arrays
url https://doi.org/10.1002/gch2.201800084
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