Glycerol electro‐reforming in alkaline electrolysis cells for the simultaneous production of value‐added chemicals and pure hydrogen – Mini‐review

Abstract Glycerol is a cheap, non‐toxic, and renewable by‐product of the rapid expansion of biodiesel and soap producers around the world. Glycerol electroforming is a method of oxidizing glycerol into valuable chemicals of interest to the pharmaceutical, cosmetics, polymer, and food industries. One...

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Main Authors: Nazym Tuleushova, Yaovi Holade, David Cornu, Sophie Tingry
Format: Article
Language:English
Published: Wiley-VCH 2023-04-01
Series:Electrochemical Science Advances
Subjects:
Online Access:https://doi.org/10.1002/elsa.202100174
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author Nazym Tuleushova
Yaovi Holade
David Cornu
Sophie Tingry
author_facet Nazym Tuleushova
Yaovi Holade
David Cornu
Sophie Tingry
author_sort Nazym Tuleushova
collection DOAJ
description Abstract Glycerol is a cheap, non‐toxic, and renewable by‐product of the rapid expansion of biodiesel and soap producers around the world. Glycerol electroforming is a method of oxidizing glycerol into valuable chemicals of interest to the pharmaceutical, cosmetics, polymer, and food industries. One of the technologies that have been studied over the past decades is to couple glycerol oxidation with the production of pure hydrogen in an electrolysis cell (so‐called electrolyzer), which has shown the advantage of consuming a much lower theoretical amount of electricity than conventional water electrolysis. The efficiency of this device is influenced by the nature, structure, and composition of the electrode material. This mini‐review concerns the understanding of glycerol electro‐oxidation, a brief state of the art of nanomaterials currently used to prepare electrode materials, and some results concerning the performance of electrolyzers in alkaline conditions that combine the efficient production of value‐added chemicals and hydrogen.
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spelling doaj.art-5ee8c36ef35040bdbb4e1a5d444bbcdf2023-04-24T05:33:52ZengWiley-VCHElectrochemical Science Advances2698-59772023-04-0132n/an/a10.1002/elsa.202100174Glycerol electro‐reforming in alkaline electrolysis cells for the simultaneous production of value‐added chemicals and pure hydrogen – Mini‐reviewNazym Tuleushova0Yaovi Holade1David Cornu2Sophie Tingry3Institut Européen des Membranes (IEM‐UMR 5635), Ecole Nationale Supurieure de Chimie de Montpellie, National Centre for Scientific Research Univ Montpellier Montpellier FranceInstitut Européen des Membranes (IEM‐UMR 5635), Ecole Nationale Supurieure de Chimie de Montpellie, National Centre for Scientific Research Univ Montpellier Montpellier FranceInstitut Européen des Membranes (IEM‐UMR 5635), Ecole Nationale Supurieure de Chimie de Montpellie, National Centre for Scientific Research Univ Montpellier Montpellier FranceInstitut Européen des Membranes (IEM‐UMR 5635), Ecole Nationale Supurieure de Chimie de Montpellie, National Centre for Scientific Research Univ Montpellier Montpellier FranceAbstract Glycerol is a cheap, non‐toxic, and renewable by‐product of the rapid expansion of biodiesel and soap producers around the world. Glycerol electroforming is a method of oxidizing glycerol into valuable chemicals of interest to the pharmaceutical, cosmetics, polymer, and food industries. One of the technologies that have been studied over the past decades is to couple glycerol oxidation with the production of pure hydrogen in an electrolysis cell (so‐called electrolyzer), which has shown the advantage of consuming a much lower theoretical amount of electricity than conventional water electrolysis. The efficiency of this device is influenced by the nature, structure, and composition of the electrode material. This mini‐review concerns the understanding of glycerol electro‐oxidation, a brief state of the art of nanomaterials currently used to prepare electrode materials, and some results concerning the performance of electrolyzers in alkaline conditions that combine the efficient production of value‐added chemicals and hydrogen.https://doi.org/10.1002/elsa.202100174alkaline electrolyzerselectrocatalysisglycerol electro‐oxidationhydrogen productionnanomaterials
spellingShingle Nazym Tuleushova
Yaovi Holade
David Cornu
Sophie Tingry
Glycerol electro‐reforming in alkaline electrolysis cells for the simultaneous production of value‐added chemicals and pure hydrogen – Mini‐review
Electrochemical Science Advances
alkaline electrolyzers
electrocatalysis
glycerol electro‐oxidation
hydrogen production
nanomaterials
title Glycerol electro‐reforming in alkaline electrolysis cells for the simultaneous production of value‐added chemicals and pure hydrogen – Mini‐review
title_full Glycerol electro‐reforming in alkaline electrolysis cells for the simultaneous production of value‐added chemicals and pure hydrogen – Mini‐review
title_fullStr Glycerol electro‐reforming in alkaline electrolysis cells for the simultaneous production of value‐added chemicals and pure hydrogen – Mini‐review
title_full_unstemmed Glycerol electro‐reforming in alkaline electrolysis cells for the simultaneous production of value‐added chemicals and pure hydrogen – Mini‐review
title_short Glycerol electro‐reforming in alkaline electrolysis cells for the simultaneous production of value‐added chemicals and pure hydrogen – Mini‐review
title_sort glycerol electro reforming in alkaline electrolysis cells for the simultaneous production of value added chemicals and pure hydrogen mini review
topic alkaline electrolyzers
electrocatalysis
glycerol electro‐oxidation
hydrogen production
nanomaterials
url https://doi.org/10.1002/elsa.202100174
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AT davidcornu glycerolelectroreforminginalkalineelectrolysiscellsforthesimultaneousproductionofvalueaddedchemicalsandpurehydrogenminireview
AT sophietingry glycerolelectroreforminginalkalineelectrolysiscellsforthesimultaneousproductionofvalueaddedchemicalsandpurehydrogenminireview