Numerical Analysis of the Horvath–Kawazoe Equation — The Adsorption of Nitrogen, Argon, Benzene, Carbon Tetrachloride and Sulphur Hexafluoride
A previously proposed numerical procedure based on the Horvath–Kawazoe (HK) model for estimating the MPSD (micropore size distribution) from a single nitrogen adsorption isotherm was developed. The results of the calculation of MSPD for two synthetic carbons obtained from numerical studies using the...
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| Format: | Article |
| Language: | English |
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SAGE Publications
2002-04-01
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| Series: | Adsorption Science & Technology |
| Online Access: | https://doi.org/10.1260/026361702760254478 |
| _version_ | 1797283660138807296 |
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| author | Piotr Kowalczyk Artur P. Terzyk Piotr A. Gauden Gerhard Rychlicki |
| author_facet | Piotr Kowalczyk Artur P. Terzyk Piotr A. Gauden Gerhard Rychlicki |
| author_sort | Piotr Kowalczyk |
| collection | DOAJ |
| description | A previously proposed numerical procedure based on the Horvath–Kawazoe (HK) model for estimating the MPSD (micropore size distribution) from a single nitrogen adsorption isotherm was developed. The results of the calculation of MSPD for two synthetic carbons obtained from numerical studies using the modified procedure are presented and discussed. These allowed the evaluation of the distribution from a single adsorption isotherm of nitrogen, argon, benzene, carbon tetrachloride and sulphur hexafluoride. In addition, the nitrogen and argon adsorption potential distributions were calculated for the same carbons applying the HK and condensation approximation (CA) methods. Agreement between these two independent approaches was observed. Differences between the MSPD obtained from HK and from the Dubinin micropore filling model (using the CONTIN package) were observed and discussed. It was shown that the structural parameter of the Dubinin–Astakov equation had no significant influence on the MSPD curves obtained. |
| first_indexed | 2024-03-07T17:34:05Z |
| format | Article |
| id | doaj.art-5ef2b16d690c4b99a1e668b77bbbe3eb |
| institution | Directory Open Access Journal |
| issn | 0263-6174 2048-4038 |
| language | English |
| last_indexed | 2024-03-07T17:34:05Z |
| publishDate | 2002-04-01 |
| publisher | SAGE Publications |
| record_format | Article |
| series | Adsorption Science & Technology |
| spelling | doaj.art-5ef2b16d690c4b99a1e668b77bbbe3eb2024-03-02T17:13:16ZengSAGE PublicationsAdsorption Science & Technology0263-61742048-40382002-04-012010.1260/026361702760254478Numerical Analysis of the Horvath–Kawazoe Equation — The Adsorption of Nitrogen, Argon, Benzene, Carbon Tetrachloride and Sulphur HexafluoridePiotr Kowalczyk0Artur P. Terzyk1Piotr A. Gauden2Gerhard Rychlicki3 Department of Respiratory Protection, Military Institute of Chemistry and Radiometry, Gen. Chruściel Avenue 105, 00-910 Warsaw, Poland Physicochemistry of Carbon Materials Research Group, Department of Chemistry, Nicolaus Copernicus University, Gagarin St. 7, 87-100 Toruń, Poland Physicochemistry of Carbon Materials Research Group, Department of Chemistry, Nicolaus Copernicus University, Gagarin St. 7, 87-100 Toruń, Poland Physicochemistry of Carbon Materials Research Group, Department of Chemistry, Nicolaus Copernicus University, Gagarin St. 7, 87-100 Toruń, PolandA previously proposed numerical procedure based on the Horvath–Kawazoe (HK) model for estimating the MPSD (micropore size distribution) from a single nitrogen adsorption isotherm was developed. The results of the calculation of MSPD for two synthetic carbons obtained from numerical studies using the modified procedure are presented and discussed. These allowed the evaluation of the distribution from a single adsorption isotherm of nitrogen, argon, benzene, carbon tetrachloride and sulphur hexafluoride. In addition, the nitrogen and argon adsorption potential distributions were calculated for the same carbons applying the HK and condensation approximation (CA) methods. Agreement between these two independent approaches was observed. Differences between the MSPD obtained from HK and from the Dubinin micropore filling model (using the CONTIN package) were observed and discussed. It was shown that the structural parameter of the Dubinin–Astakov equation had no significant influence on the MSPD curves obtained.https://doi.org/10.1260/026361702760254478 |
| spellingShingle | Piotr Kowalczyk Artur P. Terzyk Piotr A. Gauden Gerhard Rychlicki Numerical Analysis of the Horvath–Kawazoe Equation — The Adsorption of Nitrogen, Argon, Benzene, Carbon Tetrachloride and Sulphur Hexafluoride Adsorption Science & Technology |
| title | Numerical Analysis of the Horvath–Kawazoe Equation — The Adsorption of Nitrogen, Argon, Benzene, Carbon Tetrachloride and Sulphur Hexafluoride |
| title_full | Numerical Analysis of the Horvath–Kawazoe Equation — The Adsorption of Nitrogen, Argon, Benzene, Carbon Tetrachloride and Sulphur Hexafluoride |
| title_fullStr | Numerical Analysis of the Horvath–Kawazoe Equation — The Adsorption of Nitrogen, Argon, Benzene, Carbon Tetrachloride and Sulphur Hexafluoride |
| title_full_unstemmed | Numerical Analysis of the Horvath–Kawazoe Equation — The Adsorption of Nitrogen, Argon, Benzene, Carbon Tetrachloride and Sulphur Hexafluoride |
| title_short | Numerical Analysis of the Horvath–Kawazoe Equation — The Adsorption of Nitrogen, Argon, Benzene, Carbon Tetrachloride and Sulphur Hexafluoride |
| title_sort | numerical analysis of the horvath kawazoe equation the adsorption of nitrogen argon benzene carbon tetrachloride and sulphur hexafluoride |
| url | https://doi.org/10.1260/026361702760254478 |
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