Enhancement of the resistance to hydrogen embrittlement by tailoring grain boundary characteristics in a low carbon high strength steel

In this work, the feasibility of using “grain boundary engineering” to reduce the susceptibility to hydrogen embrittlement in a low carbon low alloy steel was examined. By adding Cu element, the fraction of random grain boundary (RGB) exhibited the highest value in the steel with 1%Cu, while the fra...

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Main Authors: Xiaohui Xi, Zhikun Liu, Zhenbo Qin, Tong Wu, Jinliang Wang, Ning Xu, Liqing Chen
Format: Article
Language:English
Published: Elsevier 2023-11-01
Series:Journal of Materials Research and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2238785423029320
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author Xiaohui Xi
Zhikun Liu
Zhenbo Qin
Tong Wu
Jinliang Wang
Ning Xu
Liqing Chen
author_facet Xiaohui Xi
Zhikun Liu
Zhenbo Qin
Tong Wu
Jinliang Wang
Ning Xu
Liqing Chen
author_sort Xiaohui Xi
collection DOAJ
description In this work, the feasibility of using “grain boundary engineering” to reduce the susceptibility to hydrogen embrittlement in a low carbon low alloy steel was examined. By adding Cu element, the fraction of random grain boundary (RGB) exhibited the highest value in the steel with 1%Cu, while the fraction of special grain boundary (SGB) showed a monotonical decline. The slow strain rate tensile (SSRT) test revealed that the elongation loss presented an increase with Cu addition increasing from 1 % to 3 %. This can be explained in terms of hydrogen diffusion, hydrogen trap and crack propagation. The steel with 1%Cu had a higher fraction of high angle grain boundary (HAGB), which contributed to a higher density of hydrogen traps and a lower hydrogen diffusion rate. Moreover, the steel with 1%Cu had the highest fraction of SGB (∑3, ∑5, ∑7 and ∑≥9), which was beneficial to the resistance to crack propagation. Under the combined effect of RGB and SGB, a higher resistance to hydrogen embrittlement was achieved in the steel with 1%Cu.
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spelling doaj.art-5f0d2a0ddd674eeaa71a836536e1de9d2024-02-21T05:28:11ZengElsevierJournal of Materials Research and Technology2238-78542023-11-012771197127Enhancement of the resistance to hydrogen embrittlement by tailoring grain boundary characteristics in a low carbon high strength steelXiaohui Xi0Zhikun Liu1Zhenbo Qin2Tong Wu3Jinliang Wang4Ning Xu5Liqing Chen6School of Mechanical Engineering, Guangdong Ocean University, Zhanjiang, 524088, China; Zhanjiang Key Laboratory of Corrosion and Protection of Ocean Engineering Equipment, Zhanjiang, 524088, ChinaSchool of Mechanical Engineering, Guangdong Ocean University, Zhanjiang, 524088, China; Zhanjiang Key Laboratory of Corrosion and Protection of Ocean Engineering Equipment, Zhanjiang, 524088, ChinaSchool of Materials Science and Engineering, Tianjin University, Tianjin, 300072, ChinaSchool of Mechanical Engineering, Guangdong Ocean University, Zhanjiang, 524088, China; Zhanjiang Key Laboratory of Corrosion and Protection of Ocean Engineering Equipment, Zhanjiang, 524088, ChinaSchool of Mechanical Engineering, Guangdong Ocean University, Zhanjiang, 524088, China; Zhanjiang Key Laboratory of Corrosion and Protection of Ocean Engineering Equipment, Zhanjiang, 524088, ChinaState Key Laboratory of Rolling and Automation, Northeastern University, Shenyang, 110819, China; Corresponding author.State Key Laboratory of Rolling and Automation, Northeastern University, Shenyang, 110819, ChinaIn this work, the feasibility of using “grain boundary engineering” to reduce the susceptibility to hydrogen embrittlement in a low carbon low alloy steel was examined. By adding Cu element, the fraction of random grain boundary (RGB) exhibited the highest value in the steel with 1%Cu, while the fraction of special grain boundary (SGB) showed a monotonical decline. The slow strain rate tensile (SSRT) test revealed that the elongation loss presented an increase with Cu addition increasing from 1 % to 3 %. This can be explained in terms of hydrogen diffusion, hydrogen trap and crack propagation. The steel with 1%Cu had a higher fraction of high angle grain boundary (HAGB), which contributed to a higher density of hydrogen traps and a lower hydrogen diffusion rate. Moreover, the steel with 1%Cu had the highest fraction of SGB (∑3, ∑5, ∑7 and ∑≥9), which was beneficial to the resistance to crack propagation. Under the combined effect of RGB and SGB, a higher resistance to hydrogen embrittlement was achieved in the steel with 1%Cu.http://www.sciencedirect.com/science/article/pii/S2238785423029320Low carbon high strength steelHydrogen embrittlementGrain boundary characteristicsCrack propagation
spellingShingle Xiaohui Xi
Zhikun Liu
Zhenbo Qin
Tong Wu
Jinliang Wang
Ning Xu
Liqing Chen
Enhancement of the resistance to hydrogen embrittlement by tailoring grain boundary characteristics in a low carbon high strength steel
Journal of Materials Research and Technology
Low carbon high strength steel
Hydrogen embrittlement
Grain boundary characteristics
Crack propagation
title Enhancement of the resistance to hydrogen embrittlement by tailoring grain boundary characteristics in a low carbon high strength steel
title_full Enhancement of the resistance to hydrogen embrittlement by tailoring grain boundary characteristics in a low carbon high strength steel
title_fullStr Enhancement of the resistance to hydrogen embrittlement by tailoring grain boundary characteristics in a low carbon high strength steel
title_full_unstemmed Enhancement of the resistance to hydrogen embrittlement by tailoring grain boundary characteristics in a low carbon high strength steel
title_short Enhancement of the resistance to hydrogen embrittlement by tailoring grain boundary characteristics in a low carbon high strength steel
title_sort enhancement of the resistance to hydrogen embrittlement by tailoring grain boundary characteristics in a low carbon high strength steel
topic Low carbon high strength steel
Hydrogen embrittlement
Grain boundary characteristics
Crack propagation
url http://www.sciencedirect.com/science/article/pii/S2238785423029320
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