Source and Transformation of MgO-Based Inclusions in Si-Mn-Killed Steel with Lime-Silicate Slag

The origin, evolution, and formation mechanism of MgO-based inclusions in Si-Mn-killed steel were studied in industrial trials with systematical samplings of the refining ladle, casting tundish, and as-cast bloom. In the present study, there were large numbers of MgO-based non-metallic inclusions, w...

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Main Authors: Jiaqi Zhao, Jianhua Chu, Xin Liu, Min Wang, Xiaofeng Cai, Han Ma, Yanping Bao
Format: Article
Language:English
Published: MDPI AG 2022-08-01
Series:Metals
Subjects:
Online Access:https://www.mdpi.com/2075-4701/12/8/1323
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author Jiaqi Zhao
Jianhua Chu
Xin Liu
Min Wang
Xiaofeng Cai
Han Ma
Yanping Bao
author_facet Jiaqi Zhao
Jianhua Chu
Xin Liu
Min Wang
Xiaofeng Cai
Han Ma
Yanping Bao
author_sort Jiaqi Zhao
collection DOAJ
description The origin, evolution, and formation mechanism of MgO-based inclusions in Si-Mn-killed steel were studied in industrial trials with systematical samplings of the refining ladle, casting tundish, and as-cast bloom. In the present study, there were large numbers of MgO-based non-metallic inclusions, which started to form in the LF final process, and the MgO content in the lime-silicate slag increases from LF to VD process. The reason for the formation of MgO-based inclusions in refining process was analyzed using FactSage8.1 software. It was found that MgO-based inclusions were caused by the violent reaction between the slag and steel and the serious erosion of MgO-C refractory. The MgO solubility decreased in the lime-silicate slag and precipitated the periclase phase with basicity increasing. The solubility of MgO increased with an increase in the temperature. Measures were taken to optimize the refining process based on the above result. By increasing the slag basicity and increasing the content of MgO in the slag, erosion of the MgO-C refractory was reduced and the number of MgO-based non-metallic inclusions decreased from 0.2 to 0.04 per square millimeter.
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spelling doaj.art-5f1b53f697da49ee94df1e009d9724ba2023-12-01T23:59:40ZengMDPI AGMetals2075-47012022-08-01128132310.3390/met12081323Source and Transformation of MgO-Based Inclusions in Si-Mn-Killed Steel with Lime-Silicate SlagJiaqi Zhao0Jianhua Chu1Xin Liu2Min Wang3Xiaofeng Cai4Han Ma5Yanping Bao6State Key Lab of Advanced Metallurgy, University of Science & Technology Beijing, Beijing 100083, ChinaSchool of Metallurgical Engineering, Anhui University of Technology, Maanshan 243002, ChinaState Key Lab of Advanced Metallurgy, University of Science & Technology Beijing, Beijing 100083, ChinaState Key Lab of Advanced Metallurgy, University of Science & Technology Beijing, Beijing 100083, ChinaInstitute of Research of Iron & Steel, Zhangjiagang 215600, ChinaInstitute of Research of Iron & Steel, Zhangjiagang 215600, ChinaState Key Lab of Advanced Metallurgy, University of Science & Technology Beijing, Beijing 100083, ChinaThe origin, evolution, and formation mechanism of MgO-based inclusions in Si-Mn-killed steel were studied in industrial trials with systematical samplings of the refining ladle, casting tundish, and as-cast bloom. In the present study, there were large numbers of MgO-based non-metallic inclusions, which started to form in the LF final process, and the MgO content in the lime-silicate slag increases from LF to VD process. The reason for the formation of MgO-based inclusions in refining process was analyzed using FactSage8.1 software. It was found that MgO-based inclusions were caused by the violent reaction between the slag and steel and the serious erosion of MgO-C refractory. The MgO solubility decreased in the lime-silicate slag and precipitated the periclase phase with basicity increasing. The solubility of MgO increased with an increase in the temperature. Measures were taken to optimize the refining process based on the above result. By increasing the slag basicity and increasing the content of MgO in the slag, erosion of the MgO-C refractory was reduced and the number of MgO-based non-metallic inclusions decreased from 0.2 to 0.04 per square millimeter.https://www.mdpi.com/2075-4701/12/8/1323MgO saturationindustrial trialnon-metallic inclusionsthermodynamic calculation
spellingShingle Jiaqi Zhao
Jianhua Chu
Xin Liu
Min Wang
Xiaofeng Cai
Han Ma
Yanping Bao
Source and Transformation of MgO-Based Inclusions in Si-Mn-Killed Steel with Lime-Silicate Slag
Metals
MgO saturation
industrial trial
non-metallic inclusions
thermodynamic calculation
title Source and Transformation of MgO-Based Inclusions in Si-Mn-Killed Steel with Lime-Silicate Slag
title_full Source and Transformation of MgO-Based Inclusions in Si-Mn-Killed Steel with Lime-Silicate Slag
title_fullStr Source and Transformation of MgO-Based Inclusions in Si-Mn-Killed Steel with Lime-Silicate Slag
title_full_unstemmed Source and Transformation of MgO-Based Inclusions in Si-Mn-Killed Steel with Lime-Silicate Slag
title_short Source and Transformation of MgO-Based Inclusions in Si-Mn-Killed Steel with Lime-Silicate Slag
title_sort source and transformation of mgo based inclusions in si mn killed steel with lime silicate slag
topic MgO saturation
industrial trial
non-metallic inclusions
thermodynamic calculation
url https://www.mdpi.com/2075-4701/12/8/1323
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