Improved thermal conductivity of poly(dimethylsiloxane) composites filled with well-aligned hybrid filler network of boron nitride and graphene oxide
Polymer composites have attracted considerable attention due to their easy processability, low cost, and various applications. However, intrinsic poor thermal, electrical properties of polymer always have been the bottlenecks of multifunctional technical development. In this study, fabrication of lo...
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| Format: | Article |
| Language: | English |
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Elsevier
2021-12-01
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| Series: | Polymer Testing |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S0142941821003469 |
| _version_ | 1819005750894133248 |
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| author | Wondu Lee Jooheon Kim |
| author_facet | Wondu Lee Jooheon Kim |
| author_sort | Wondu Lee |
| collection | DOAJ |
| description | Polymer composites have attracted considerable attention due to their easy processability, low cost, and various applications. However, intrinsic poor thermal, electrical properties of polymer always have been the bottlenecks of multifunctional technical development. In this study, fabrication of low dielectric loss and highly thermal conductive composites was investigated through hybridization of silane-treated reduced graphene oxide (rGO) and boron nitride (BN), sintering of silver nanoparticles (AgNPs) on the surface of two-dimensional fillers, and infiltration of poly(dimethylsiloxane) (PDMS). The well-ordered filler structure was achieved by aligned BN on the rGO surface. The aligned PDMS/BNA-SrGOA composites, which form heat transfer paths along the filler orientation of two-dimensional BN and GO, exhibited high thermal conductivities of 10.91 and 1.27 W/mK according to in-plane and through-plane direction in a 1:2 ratio of BN and rGO. In addition, the dielectric loss was decreased by interaction with BN compared to that with only the rGO composites. Finally, the treatment of a silane coupling agent on the rGO surface reduced the interface resistivity between the filler and matrix, which reinforced the thermal, electrical, mechanical properties. |
| first_indexed | 2024-12-20T23:57:46Z |
| format | Article |
| id | doaj.art-5f2216d140074c0ca64a5a29b172faf4 |
| institution | Directory Open Access Journal |
| issn | 0142-9418 |
| language | English |
| last_indexed | 2024-12-20T23:57:46Z |
| publishDate | 2021-12-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Polymer Testing |
| spelling | doaj.art-5f2216d140074c0ca64a5a29b172faf42022-12-21T19:22:41ZengElsevierPolymer Testing0142-94182021-12-01104107402Improved thermal conductivity of poly(dimethylsiloxane) composites filled with well-aligned hybrid filler network of boron nitride and graphene oxideWondu Lee0Jooheon Kim1School of Chemical Engineering and Materials Science, Chung-Ang University, Seoul, 156-756, Republic of KoreaSchool of Chemical Engineering and Materials Science, Chung-Ang University, Seoul, 156-756, Republic of Korea; Department of Advanced Materials Engineering, Chung-Ang University, Anseong-si, Gyeonggi-do, 17546, Republic of Korea; Graduate School of Intelligent Energy and Industry, Chung-Ang University, Seoul, 156-756, Republic of Korea; Corresponding author. School of Chemical Engineering and Materials Science, Chung-Ang University, Seoul, 156-756, Republic of Korea.Polymer composites have attracted considerable attention due to their easy processability, low cost, and various applications. However, intrinsic poor thermal, electrical properties of polymer always have been the bottlenecks of multifunctional technical development. In this study, fabrication of low dielectric loss and highly thermal conductive composites was investigated through hybridization of silane-treated reduced graphene oxide (rGO) and boron nitride (BN), sintering of silver nanoparticles (AgNPs) on the surface of two-dimensional fillers, and infiltration of poly(dimethylsiloxane) (PDMS). The well-ordered filler structure was achieved by aligned BN on the rGO surface. The aligned PDMS/BNA-SrGOA composites, which form heat transfer paths along the filler orientation of two-dimensional BN and GO, exhibited high thermal conductivities of 10.91 and 1.27 W/mK according to in-plane and through-plane direction in a 1:2 ratio of BN and rGO. In addition, the dielectric loss was decreased by interaction with BN compared to that with only the rGO composites. Finally, the treatment of a silane coupling agent on the rGO surface reduced the interface resistivity between the filler and matrix, which reinforced the thermal, electrical, mechanical properties.http://www.sciencedirect.com/science/article/pii/S0142941821003469Polymer-matrix composites (PMCs)3D networkSilane treatmentThermal conductivity |
| spellingShingle | Wondu Lee Jooheon Kim Improved thermal conductivity of poly(dimethylsiloxane) composites filled with well-aligned hybrid filler network of boron nitride and graphene oxide Polymer Testing Polymer-matrix composites (PMCs) 3D network Silane treatment Thermal conductivity |
| title | Improved thermal conductivity of poly(dimethylsiloxane) composites filled with well-aligned hybrid filler network of boron nitride and graphene oxide |
| title_full | Improved thermal conductivity of poly(dimethylsiloxane) composites filled with well-aligned hybrid filler network of boron nitride and graphene oxide |
| title_fullStr | Improved thermal conductivity of poly(dimethylsiloxane) composites filled with well-aligned hybrid filler network of boron nitride and graphene oxide |
| title_full_unstemmed | Improved thermal conductivity of poly(dimethylsiloxane) composites filled with well-aligned hybrid filler network of boron nitride and graphene oxide |
| title_short | Improved thermal conductivity of poly(dimethylsiloxane) composites filled with well-aligned hybrid filler network of boron nitride and graphene oxide |
| title_sort | improved thermal conductivity of poly dimethylsiloxane composites filled with well aligned hybrid filler network of boron nitride and graphene oxide |
| topic | Polymer-matrix composites (PMCs) 3D network Silane treatment Thermal conductivity |
| url | http://www.sciencedirect.com/science/article/pii/S0142941821003469 |
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